Selective oxidation of glycerol to dihydroxyacetone over layer double hydroxide intercalated with sulfonato-salen metal complexes

LUO Jing; LI Hong-guang; ZHAO Ning; WANG Feng; XIAO Fu-kui

Volume 43 Issue 06

Jun. 2015

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Article Navigation > Journal of Fuel Chemistry and Technology > 2015 > 43(06): 677-683

LUO Jing, LI Hong-guang, ZHAO Ning, WANG Feng, XIAO Fu-kui. Selective oxidation of glycerol to dihydroxyacetone over layer double hydroxide intercalated with sulfonato-salen metal complexes[J]. Journal of Fuel Chemistry and Technology, 2015, 43(06): 677-683.

Citation:

LUO Jing, LI Hong-guang, ZHAO Ning, WANG Feng, XIAO Fu-kui. Selective oxidation of glycerol to dihydroxyacetone over layer double hydroxide intercalated with sulfonato-salen metal complexes[J]. Journal of Fuel Chemistry and Technology, 2015, 43(06): 677-683.

Citation:

LUO Jing, LI Hong-guang, ZHAO Ning, WANG Feng, XIAO Fu-kui. Selective oxidation of glycerol to dihydroxyacetone over layer double hydroxide intercalated with sulfonato-salen metal complexes[J]. Journal of Fuel Chemistry and Technology, 2015, 43(06): 677-683.

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Selective oxidation of glycerol to dihydroxyacetone over layer double hydroxide intercalated with sulfonato-salen metal complexes

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 2015-01-26
Rev Recd Date: 2015-03-10
Publish Date: 2015-06-30

Abstract

Abstract

A series of sulfonato-salen metal complexes were intercalated into Mg-Al layer double hydroxide (LDH) and used for selective oxidation of glycerol to dihydroxyacetone (DHA). The X-ray diffraction, Fourier transform infrared spectroscopy and elemental analysis results of the as-prepared catalysts demonstrated that the metal ions were combined with sulfonato-salen ligands to form metal complexes that intercalated in the LDH. The Cr(III) and Cu(II) sulfonato-salen complex-intercalated LDH catalysts were favorable for activation of H₂O₂, promoting the oxidation of glycerol to DHA. It was found that the Cu(II) sulfonato-salen-intercalated LDH catalyst was also beneficial for the dehydrogenation of glycerol, resulting in a high selectivity to DHA. The glycerol conversion and DHA selectivity obtained over the Cu(II) sulfonato-salen-intercalated LDH catalyst reached 40.3% and 52.9% respectively under the optimum reaction conditions of 60 ℃, 4 h and pH value 7.
- glycerol,
- dihydroxyacetone,
- sulfonato-salen metal complexes,
- heterogeneous catalyst,
- selective oxidation

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References(26)

References

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