Volume 43 Issue 06
Jun.  2015
Turn off MathJax
Article Contents
ZHUANG Chao, NING Jian-mei, LI Yi, YANG Li-xia, LIU Dao-sheng, ZHANG Lei, GUI Jian-zhou. Preparation and characterization of porous composite calcium aluminum oxide and their application in dechlorination of reformate[J]. Journal of Fuel Chemistry and Technology, 2015, 43(06): 740-746.
Citation: ZHUANG Chao, NING Jian-mei, LI Yi, YANG Li-xia, LIU Dao-sheng, ZHANG Lei, GUI Jian-zhou. Preparation and characterization of porous composite calcium aluminum oxide and their application in dechlorination of reformate[J]. Journal of Fuel Chemistry and Technology, 2015, 43(06): 740-746.

Preparation and characterization of porous composite calcium aluminum oxide and their application in dechlorination of reformate

  • Received Date: 2014-12-23
  • Rev Recd Date: 2015-02-23
  • Publish Date: 2015-06-30
  • A series of CaO-Al2O3 composites with different CaO contents were prepared by co-precipitation from low-price Ca and Al precursors, and characterized by XRD, TG-DTG, N2 adsorption, SEM and etc. Their performance removing HCl from reformate was evaluated by dynamic absorption method. Due to its large surface area, uniform particle size and high porosity, CAO-1 showed the best dechlorination performance. When the initial content of chlorine in reformate is less than 15 ng/μL, the dechlorination capacity can reach to 18% at a LHSV of 3 h-1 at 55 ℃.
  • loading
  • 张秋平. 催化重整过程中的脱氯工艺技术[J]. 炼油技术与工程, 2012, 42(3): 25-28. (ZHANG Qiu-ping. Apllication of dechlorination process in catalytic reforming[J]. Pet Refin Eng, 2012, 42(3): 25-28.)
    兰创宏, 孙乾义, 张勇, 张成藩, 秦小刚, 司海娟. 重整生成油液相脱氯技术的设计与应用[J]. 石油化工设备, 2013, 42(1): 72-74. (LAN Chuang-hong, SUN Qian-yi, ZHANG Yong, ZHANG Cheng-fan, QIN Xiao-gang, SI Hai-juan. Design and application of reformate liquid chloride adsorption technology[J]. Petro Chem Equip, 2013, 42(1): 72-74.)
    李凤生. 重整装置脱戊烷塔分离精度下降和空冷器腐蚀的原因及对策[J]. 石油炼制与化工, 2004, 35(7): 65-67. (LI Feng-sheng. Analysis and countermeasures for poor separation of reformer depentanizer and corosion of air cooler[J]. Pet Process Petrochem, 2004, 35(7): 65-67.)
    王智. 脱氯剂的工业应用[J]. 石油炼制与化工, 1998, 29(1): 19-24. (WANG Zhi. Commercial application of a dechlorination agent[J]. Pet Process Petrochem, 1998, 29(1): 19-24.)
    李生运, 杜彩霞. 催化重整系列脱氯剂的研究与应用[J]. 石油炼制与化工, 2006, 37(2): 24-29. (LI Sheng-yun, DU Cai-xia. Development and application of dechlorination absorbent for catalytic reforming[J]. Pet Process Petrochem, 2006, 37(2): 24-29.)
    豆斌林, 高晋生, 鲁军, 沙兴中. 高温煤气净化—高效脱氯剂的研究[J]. 燃料化学学报, 2000, 28(3): 206-209. (DOU Bin-lin, GAO Jin-sheng, LU Jun, SHA Xing-zhong. Study on sorbents for chloride removal from high-temperature gas[J]. J Fuel Chem Technol, 2000, 28(3): 206-209.)
    王晓东, 孙伟淼, 于晓斌. 复合的多功能脱氯剂:中国, 1539921A[P]. 2004-10-27. (WANG Xiao-dong, SUN Wei-miao, YU Xiao-bin. Composite multifunctional dechlorination agent: CN, 1539921A[P]. 2004-10-27.)
    罗平, 李怀新, 李耀会, 吕小碗, 李小定. 液相脱氯技术现状与研究进展[J]. 化工时刊, 2007, 21(9): 72-75. (LUO Ping, LI Huai-xin, LI Yao-hui, LV Xiao-wan, LI Xiao-ding. Current situation and research progress of dechloriation technology in liquid-phase[J]. Chem Ind Times, 2007, 21(9): 72-75.)
    郑华艳, 李茜茜, 崔丽萍, 李忠. Ca/Al固体碱催化菜籽油制备生物柴油[J]. 燃料化学学报, 2012, 40(3): 331-336. (ZHENG Hua-yan, LI Xi-qian, CUI Li-ping, LI Zhong. Synthesis of biodiesel from rapeseed oil catalyzed by Ca/Al solid base[J]. J Fuel Chem Technol, 2012, 40(3): 331-336.)
    马军, 尉继英, 朱月香, 冯华升, 蔡小海, 谢有畅. 铜锆复合氧化物的结构对其催化选择还原一氧化氮性能的影响[J]. 化学学报, 2001,59(5): 713-717. (MA Jun, WEI Ji-ying, ZHU Yue-xiang, FENG Hua-sheng, CAI Xiao-hai, XIE You-chang. The structure of CuO-ZrO2 mixed oxides and its influence on the catalytic selective reduction of NO by propene[J]. Acta Chem Sinica, 2001, 59(5): 713-717.)
    吕志, 段雪. 阴离子层状材料的可控制备[J]. 催化学报, 2008, 29(9): 839-856. (LÜ Zhi, DUAN Xue. Controllable preparation of layered anionic materials[J]. Chin J Catal, 2008, 29(9): 839-856.)
    杨锡尧, 任韶玲, 何辉, 王大庆. 新型催化剂载体材料—镁铝复合氧化物的制备及其物理化学性质[J]. 分子催化, 1996, 10(2): 88-94. (YANG Xi-yao, REN Shao-ling, HE Hui, WANG Da-qing. Preparation and physicochemical characterization of novel catalyst material Mg-Al complex oxides[J]. J Mol Catal(China), 1996, 10(2): 88-94.)
    俞树荣, 张婷, 戴虎虎, 王毅, 冯辉霞, 赵霞. 凹凸棒石复合氧化钙脱硫剂脱除SO2的试验研究[J]. 非金属矿, 2009, 32(6): 1-2, 19. (YU Shu-rong, ZHANG Ting, DAI Hu-hu, WANG Yi, FENG Hui-xia, ZHAO Xia. Study on desulfurization of SO2 by attapulgite/calcium oxide compond desulfurization agent[J]. Non-Metall Mines, 2009, 32(6): 1-2, 19.)
    罗芳苜, 刘庆艳. 钙铝类水滑石的合成及其在PVC中的应用[J]. 塑料, 2008, 38(3): 52-53, 97. (LUO Fang-mu, LIU Qing-yan. Synthesis of Ca-Al hydrotalcite-like compounds and its application in PVC[J]. Plastics, 2008, 38(3): 52-53, 97.)
    ZHANG P, QIAN G, SHI H, RUAN X, YANG J, FROST R L. Mechanism of interaction of hydrocalumites(Ca/Al-LDH)with methyl orange and acidic scarlet GR[J]. J Colloid Interface Sci, 2012, 365(1): 110-116.
    PLANK J, DAI Z, ANDRES P R. Preparation and characterization of new Ca-Al-Poly carboxylate layered double hydroxides[J]. Mater Lett, 2006, 60(29/30): 3614-3617.
    VALENTE J S, CANTU M S, CORTEZ J G H, MONTIEL R, BOKHIMI X, LOPEZ-SALINAS E. Preparation and characterization of sol-gel MgAl hydrotalcites with nanocapsular morphology[J]. J Phys Chem C, 2007, 111(42): 642-651.
    CHMIELARZ L, KUSTROWSKI P, RAFALSKA-LASOCHA A, DZIEMBAJ R. Influence of Cu, Co and Ni cations incorporated in brucite-type layers on thermal behaviour of hydrotalcites and reducibility of the derived mixed oxide systems[J]. Thermochim Acta, 2002, 395(1/2): 225-236.
    曹林, 王海林, 解强. 钙铝类水滑石衍生复合氧化物的SO2储存性能研究[J]. 环境科学, 2013, 34(9): 3627-3632. (CAO Lin, WANG Hai-lin, XIE Qiang. Reaction of SO2 over CaAl mixed oxides derived from hydrotalcites samples[J]. Environ Sci, 2013, 34(9): 3627-3632.)
    SING K S W, EVERETT D H, HAUL R A W, MOSCOU L, PIEROTTI R A, ROUQUEROL J, SIEMIENIEWSKA T. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity(recommendations 1984)[J]. Pure Appl Chem, 1985, 57(4): 603-619.
    DE BOER J H. The structure and properties of porous materials[M]. London: Butterworth, 1985.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (405) PDF downloads(396) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return