CO<sub>2</sub> methanation over Ni/Mg@MCM-41 prepared by <i>in-situ</i> synthesis method

WANG Xiao-liu; YANG Meng; ZHU Ling-jun; ZHU Xiao-nan; WANG Shu-rong

Volume 48 Issue 4

Apr. 2020

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Article Navigation > Journal of Fuel Chemistry and Technology > 2020 > 48(4): 456-465

WANG Xiao-liu, YANG Meng, ZHU Ling-jun, ZHU Xiao-nan, WANG Shu-rong. CO2 methanation over Ni/Mg@MCM-41 prepared by in-situ synthesis method[J]. Journal of Fuel Chemistry and Technology, 2020, 48(4): 456-465.

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WANG Xiao-liu, YANG Meng, ZHU Ling-jun, ZHU Xiao-nan, WANG Shu-rong. CO₂ methanation over Ni/Mg@MCM-41 prepared by in-situ synthesis method[J]. Journal of Fuel Chemistry and Technology, 2020, 48(4): 456-465.

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CO₂ methanation over Ni/Mg@MCM-41 prepared by in-situ synthesis method

State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China

Funds:

the National Science Fund for Distinguished Young Scholars 51725603

More Information

Corresponding author: WANG Shu-rong, Tel: 0571-87952801, E-mail: srwang@zju.edu.cn
Received Date: 2020-01-17
Rev Recd Date: 2020-03-08

Available Online: 2021-01-23

Publish Date: 2020-04-10

Abstract

Abstract

A series of xMg@MCM-41(x=0, 0.05, 0.1) functional mesoporous materials were synthesized by a novel in-situ one pot method and then were used as support for Ni based catalysts. The results of XRD and TEM show that when the amount of Mg/Si (molar ratio) is 0.05, Mg@MCM-4 with a regular and ordered mesoporous structure is synthesized where Mg is introduced into the framework of MCM-41. Introducing Mg into the framework of the support can significantly enhance the basic properties of the catalyst, thus promoting the adsorption and activation of CO₂. The catalysts prepared in the experiments all have good thermal stability and catalytic activity. Among them, Ni/0.05Mg@MCM-41 shows the best low temperature reaction activity in the CO₂ methanation reaction.
- CO₂,
- methanation,
- in-situ,
- Mg@MCM-41,
- catalytic activity

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References(35)

References

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