Volume 44 Issue 5
May  2016
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ZHUANG De-wang, WU Shi-yong, YOU Quan, HUANG Sheng, SHANG Jian-xuan, MIN Xiao-jian, ZHENG Hua-an, WU You-qing. Low rank coal mild liquefaction coupled with carbonization and its products[J]. Journal of Fuel Chemistry and Technology, 2016, 44(5): 528-533.
Citation: ZHUANG De-wang, WU Shi-yong, YOU Quan, HUANG Sheng, SHANG Jian-xuan, MIN Xiao-jian, ZHENG Hua-an, WU You-qing. Low rank coal mild liquefaction coupled with carbonization and its products[J]. Journal of Fuel Chemistry and Technology, 2016, 44(5): 528-533.

Low rank coal mild liquefaction coupled with carbonization and its products

Funds:

the National Natural Science Foundation of China 21476079

the National Natural Science Foundation of China 21476080

the Fundamental Research Funds for the Central Universities WB1414014

  • Received Date: 2015-12-31
  • Rev Recd Date: 2016-02-25
  • Available Online: 2021-01-23
  • Publish Date: 2016-05-10
  • The distribution of products was preliminarily studied based on a process of low rank coal mild liquefaction at 390-450 ℃ coupled with carbonization. The characteristics of liquid product and semi-coke were analyzed. The results showed that the organic liquid product yield is 23.44%-33.26% (daf, coal) and the semi-coke yield is 49.56%-68.72% (daf, coal). The water content of liquid product is 1.30%-2.49%. The n-hexane soluble content of organic liquid product is higher than 98.95% with no solid particles in liquid product. The carbon content of semi-coke obtained is 87.87%-93.45% (daf), some semi-cokes have the characteristics of strong caking property. There is a close correlation between caking property and asphaltene content of semi-coke.
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  • [1]
    王建国, 赵晓红.低阶煤清洁高效梯级利用关键技术与示范[J].中国科学院院刊, 2012, 27(3): 382-388. http://www.cnki.com.cn/Article/CJFDTOTAL-KYYX201203019.htm

    WANG Jian-guo, ZHAO Xiao-hong. Demonstration of key technologies for clean and efficient utilization of low-rank coal[J]. Bull Chin Acad Sci, 2012, 27(3): 382-388. http://www.cnki.com.cn/Article/CJFDTOTAL-KYYX201203019.htm
    [2]
    LIU Z, SHI S, LI Y. Coal liquefaction technologies-development in China and challenges in chemical reaction engineering[J]. Chem Eng Sci, 2010, 65(1): 12-17. doi: 10.1016/j.ces.2009.05.014
    [3]
    郝玉良, 杨建丽, 李允梅, 刘沐鑫, 杨勇.低阶煤温和液化特征分析[J].燃料化学学报, 2012, 40(10): 1153-1160. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract18037.shtml

    HAO Yu-liang, YANG Jian-li, LI Yun-mei, LIU Mu-xin, YANG Yong. Study on mild liquefaction of lower rank coal[J]. J Fuel Chem Technol, 2012, 40(10): 1153-1160. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract18037.shtml
    [4]
    RIZKIANA J, GUAN G, WIDAYATNO W B, HAO X, WANG Z, ZHANG Z, ABUDULA A. Oil production from mild pyrolysis of low-rank coal in molten salts media[J]. Appl Energy, 2015, 154: 944-950. doi: 10.1016/j.apenergy.2015.05.092
    [5]
    尚建选, 马宝岐, 张秋民, 沈和平.低阶煤分质转化多联产技术[M].北京:煤炭工业出版社, 2013.

    SHANG Jian-xuan, MA Bao-qi, ZHANG Qiu-ping, SHEN He-ping. Low Rank Coal Grading Conversion Poly-Generation Technology[M]. Beijing: China Coal Industry Publishing House, 2013.
    [6]
    HIRANO K. Outline of NEDOL coal liquefaction process development (pilot plant program)[J]. Fuel Process Technol, 2000, 62(2): 109-118. https://www.researchgate.net/publication/257210953_Outline_of_NEDOL_coal_liquefaction_process_development_pilot_plant_program
    [7]
    MIURA K, MAE K, SAKURADA K, HASHIMOTO K. Flash pyrolysis of coal following thermal pretreatment at low temperature[J]. Energy Fuels, 1992, 6: 16-21. doi: 10.1021/ef00031a003
    [8]
    朱豫飞.煤直接液化与残渣热解联合加工技术[J].煤炭学报, 2013, 38(8): 1454-1458. http://www.cnki.com.cn/Article/CJFDTOTAL-MTXB201308027.htm

    ZHU Yu-fei. Integrated process of direct coal liquefaction and its residue pyrolysis[J]. J China Coal Soc, 2013, 38(8): 1454-1458. http://www.cnki.com.cn/Article/CJFDTOTAL-MTXB201308027.htm
    [9]
    CYPRES R, LI B. Effect of pretreatment by various gases on hydropyrolysis of a Belgian coal[J]. Fuel Process Technol, 1988, 20(1/3): 337-347.
    [10]
    吴幼青, 吴诗勇, 高晋生, 李良.一种煤温和液化的工艺方法:中国, ZL201310539685.2[P]. 2014-02-05.

    WU You-qing, WU Shi-yong, GAO Jin-sheng, LI Liang. A mild coal liquefaction process: CN, 201310539685.2[P]. 2014-02-05.
    [11]
    吴春来.煤炭直接液化[M].北京:化学工业出版社, 2010.

    WU Chun-lai. Direct Coal Liquefaction[M]. Beijing: Chemistry Industry Press, 2010.
    [12]
    李刚, 凌开成.煤高温快速液化影响因素的研究[J].燃料化学学报, 2009, 37(6): 648-653. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract17506.shtml

    LI Gang, LING Kai-cheng. Influencing factors on quick coal liquefaction at high temperature[J]. J Fuel Chem Technol, 2009, 37(6): 648-653. http://rlhxxb.sxicc.ac.cn/CN/abstract/abstract17506.shtml
    [13]
    WASAKA S, IBARAGI S, HASHIMOTO T, TSUKUI Y, KATSUYAMA T, SHIDONG S. Study on coal liquefaction characteristics of Chinese coals[J]. Fuel, 2002, 81: 1551-1557. doi: 10.1016/S0016-2361(02)00087-X
    [14]
    FINSETH D H, CILLO D L, SPRECHER R F, RETCOFSKY H L, LETT R G. Changes in hydrogen utilization with temperature during direct coal liquefaction[J]. Fuel, 1985, 64(12): 1718-1722. doi: 10.1016/0016-2361(85)90399-0
    [15]
    朱银惠, 郝临山.煤化学[M]. 2版.北京:化学工业出版社, 2011.

    ZHU Yin-hui, HAO Lin-shan. Coal Chemistry[M]. 2nd ed. Beijing: Chemical Industry Press, 2011.
    [16]
    晏善成, 郑明东, 严文福.配煤技术的发展[J].山东冶金, 2006, 28(5): 31-32. http://www.cnki.com.cn/Article/CJFDTOTAL-SDYJ200605014.htm

    YAN Shan-cheng, ZHENG Ming-dong, YAN Wen-fu. The development of coal blending technology[J]. Shandong Metall, 2006, 28(5): 31-32. http://www.cnki.com.cn/Article/CJFDTOTAL-SDYJ200605014.htm
    [17]
    FLATMAN-FAIRS D P, HARRISON G. Suitability of UK bituminous and Spanish lignitous coals, and their blends for two stage liquefaction[J]. Fuel, 1999, 78(14): 1711-1717. doi: 10.1016/S0016-2361(99)00119-2
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