Effect of aqueous phase recirculation on characteristics of bio-crude oil formation during hydrothermal liquefaction of corn stalk

YIN Si-yuan; TIAN Chun-yan; LI Yan-mei; GAO Chuan-rui; ZHANG Nian-ze; CHOU Peng-tao; YI Wei-ming; LI Zhi-he

Volume 48 Issue 3

Mar. 2020

Turn off MathJax

Article Contents

Article Navigation > Journal of Fuel Chemistry and Technology > 2020 > 48(3): 275-285

YIN Si-yuan, TIAN Chun-yan, LI Yan-mei, GAO Chuan-rui, ZHANG Nian-ze, CHOU Peng-tao, YI Wei-ming, LI Zhi-he. Effect of aqueous phase recirculation on characteristics of bio-crude oil formation during hydrothermal liquefaction of corn stalk[J]. Journal of Fuel Chemistry and Technology, 2020, 48(3): 275-285.

Citation:

YIN Si-yuan, TIAN Chun-yan, LI Yan-mei, GAO Chuan-rui, ZHANG Nian-ze, CHOU Peng-tao, YI Wei-ming, LI Zhi-he. Effect of aqueous phase recirculation on characteristics of bio-crude oil formation during hydrothermal liquefaction of corn stalk[J]. Journal of Fuel Chemistry and Technology, 2020, 48(3): 275-285.

Citation:

YIN Si-yuan, TIAN Chun-yan, LI Yan-mei, GAO Chuan-rui, ZHANG Nian-ze, CHOU Peng-tao, YI Wei-ming, LI Zhi-he. Effect of aqueous phase recirculation on characteristics of bio-crude oil formation during hydrothermal liquefaction of corn stalk[J]. Journal of Fuel Chemistry and Technology, 2020, 48(3): 275-285.

PDF( 703 KB)

Effect of aqueous phase recirculation on characteristics of bio-crude oil formation during hydrothermal liquefaction of corn stalk

YIN Si-yuan^{1, 2},
TIAN Chun-yan^{1, 2},
LI Yan-mei^{1, 2},
GAO Chuan-rui^{1, 2},
ZHANG Nian-ze^{1, 2},
CHOU Peng-tao^{1, 2},
YI Wei-ming^{1, 2
,
,},
LI Zhi-he^{1, 2}

1.
College of Agricultural Engineering and Food Science, Shandong University of Technology, Zibo 255000, China
2.
Shandong Research Center of Engineering & Technology for Clean Energy, Zibo 255000, China

Funds:

The project was supported by National Natural Science Foundation of Shandong Province ZR2017BEE049

National Natural Science Foundation of China 51706126

National Natural Science Foundation of China 31872400

National Natural Science Foundation of China 51536009

SDUT & Zibo City Integration Project 2019ZBXC380

More Information

Corresponding author: YI Wei-ming, Tel: 13506440954, E-mail: yiweiming@sdut.edu.cn
Received Date: 2020-01-06
Rev Recd Date: 2020-02-11

Available Online: 2021-01-23

Publish Date: 2020-03-10

Abstract

Abstract

The corn stalk was used as the raw material and the deionized water was used as the medium to study the effect of aqueous phase recirculation on characteristics of bio-crude oil formation during hydrothermal liquefaction of corn stalk. No additional deionized water was added during the recirculation. The results show that the aqueous phase recirculation can enrich the concentration of organic acids in aqueous phase and promote the conversion of ketophenols, which can improve the yield and quality of bio-crude oil and solid products. Specifically, the aqueous phase recirculation has little effect on the pH value of the aqueous phase (3.62-3.91), but the organic acids such as acetic acid and propionic acid are continuously accumulated and the content of ketones and phenols is gradually reduced. Also, the yield of bio-crude oil is gradually increased from 20.42% to 24.31%, the quality of bio-crude oil is slightly improved, and the carbon content of the solid product is increased from 60.94% to 61.74%.
- hydrothermal liquefaction,
- corn stalk,
- aqueous phase recirculation,
- characteristics of biocrude formation,
- bio-crude oil

FullText(HTML)

References(30)

References

[1]	宋春财, 胡浩权.生物质秸秆在水中热化学液化研究[J].四川大学学报(工程科学版), 2002, 34(5):59-62. http://d.old.wanfangdata.com.cn/Periodical/scdxxb-gckx200205015 SONG Chun-cai, HU Hao-quan. Thermochemical liquefaction of biomass in high pressure water[J]. J Sichuan Univ (Eng Sci Ed), 2002, 34(5):59-62. http://d.old.wanfangdata.com.cn/Periodical/scdxxb-gckx200205015
[2]	卫洪建, 杨晴, 李佳硕, 杨海平, 陈汉平.中国农作物秸秆资源时空分布及其产率变化分析[J].可再生能源, 2019, 37(9):1265-1273. http://d.old.wanfangdata.com.cn/Periodical/ncny201909001 WEI Hong-jian, YANG Qing, LI Jia-shuo, YANG Hai-ping, CHEN Han-ping. Analysis of spatiotemporal and density changes of crop straws resources in China[J]. Renewable Energy Resour, 2019, 37(9):1265-1273. http://d.old.wanfangdata.com.cn/Periodical/ncny201909001
[3]	刘志斌, 张学勤.木质纤维素生物质催化转化为高附加值产品的研究进展[J].纤维素科学与技术, 2019, 27(3):77-82. http://d.old.wanfangdata.com.cn/Periodical/xwskxyjs201903011 LIU Zhi-bin, ZHANG Xue-qin. Progress of lignocellulose biomass catalytic conversion to high added-value products[J]. J Cellul Sci Technol, 2019, 27(3):77-82. http://d.old.wanfangdata.com.cn/Periodical/xwskxyjs201903011
[4]	姜洪涛, 李会泉, 张懿.生物质高压液化制生物原油研究进展[J].化工进展, 2006, 25(1):8-13. http://d.old.wanfangdata.com.cn/Periodical/hgjz200601002 JIANG Hong-tao, LI Hui-quan, ZHANG Yi. Progress in liquefaction of biomass to bio-crude[J]. Chem Ind Eng Prog, 2006, 25(1):8-13. http://d.old.wanfangdata.com.cn/Periodical/hgjz200601002
[5]	KLEMMER M, MADSEN R B, HOULBERG K, MØRUP A J, CHRISTENSEN P S, BECKER J, GLASIUS M, IVERSEN B B. Effect of aqueous phase recycling in continuous hydrothermal liquefaction[J]. Ind Eng Chem Res, 2016, 55(48):12317-12325. http://cn.bing.com/academic/profile?id=c2f19ac30622475e1579a776a1f0a173&encoded=0&v=paper_preview&mkt=zh-cn
[6]	曲磊, 崔翔, 杨海平, 王贤华, 张文楠, 邵敬爱, 陈汉平.微藻水热液化制取生物油的研究进展[J].化工进展, 2018, 37(8):2962-2969. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hgjz201808012 QU Lei, CUI Xiang, YANG Hai-ping, WANG Xian-hua, ZHANG Wen-nan, SHAO Jing-ai, CHEN Han-ping. Review on the preparation of bio-oil by microalgae hydrothermal liquefaction[J]. Chem Ind Eng Prog, 2018, 37(8):2962-2969. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hgjz201808012
[7]	USMAN M, CHEN H, CHEN K, REN S, CLARK J H, FAN J, LUO G, ZHANG S. Characterization and utilization of aqueous products from hydrothermal conversion of biomass for bio-oil and hydro-char production:A review[J]. Green Chem, 2019, 21(7):1553-1572. http://cn.bing.com/academic/profile?id=b0828a754e9e136121083883145ed95a&encoded=0&v=paper_preview&mkt=zh-cn
[8]	彭文才.农作物秸秆水热液化过程及机理的研究[D].上海: 华东理工大学, 2011. PENG Wen-cai. Study on the process and mechanism of hydrothermal liquefaction of crop straws[D]. Shanghai: East China University of Science and Technology, 2011.
[9]	LI C, YANG X, ZHANG Z, ZHOU D, ZHANG L, ZHANG S, CHEN J. Hydrothermal liquefaction of desert shrub salix psammophila to high value-added chemicals and hydrochar with recycled processing water[J]. BioResources, 2013, 8(2):2981-2997. http://cn.bing.com/academic/profile?id=0e4a03939934d1fdf825432b6ad3e81e&encoded=0&v=paper_preview&mkt=zh-cn
[10]	ELLIOTT D C, BILLER P, ROSS A B, SCHMIDT A J, JONES S B. Hydrothermal liquefaction of biomass:Developments from batch to continuous process[J]. Bioresour Technol, 2015, 178:147-156. http://cn.bing.com/academic/profile?id=b48ea9f83ec46af8859961254e5d9e29&encoded=0&v=paper_preview&mkt=zh-cn
[11]	李长军.沙柳水热转化制备生物油和生物碳的研究[D].上海: 复旦大学, 2013. LI Chang-jun. Hydrothermal conversion of desert shrub salix Psammophila to bio-oil and hydrochars[D]. Shanghai: Fudan University, 2013.
[12]	ZHU Z, ROSENDAHL L, TOOR S S, YU D, CHEN G. Hydrothermal liquefaction of barley straw to bio-crude oil:Effects of reaction temperature and aqueous phase recirculation[J]. Appl Energy, 2015, 137:183-192. http://cn.bing.com/academic/profile?id=35396cf22d9cf59824bfaffaa37478af&encoded=0&v=paper_preview&mkt=zh-cn
[13]	RAMOS-TERCERO E A, BERTUCCO A, BRILMAN D W F W. Process water recycle in hydrothermal liquefaction of microalgae to enhance bio-oil yield[J]. Energy Fuels, 2015, 29(4):2422-2430. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=79daf116425f8e52d4236b453bb9f6ac
[14]	HU Y, FENG S, BASSI A, XU C C. Improvement in bio-crude yield and quality through co-liquefaction of algal biomass and sawdust in ethanol-water mixed solvent and recycling of the aqueous by-product as a reaction medium[J]. Energy Convers Manage, 2018, 171:618-625. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=d0a3734190c76a7a7aa80335a10d72e2
[15]	PANISKO E, WIETSMA T, LEMMON T, ALBRECHT K, HOWE D. Characterization of the aqueous fractions from hydrotreatment and hydrothermal liquefaction of lignocellulosic feedstocks[J]. Biomass Bioenergy, 2015, 74:162-171. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=c80cdb8256448fc53488fb7c9dff6010
[16]	GB/T 2677.10-1995.造纸原料综纤维素含量的测定[S]. GB/T 2677.10-1995. Fibrous raw material determination of holocellulose[S].
[17]	VAN SOEST P J, ROBERTSON J B, LEWIS B A. Methods for dietary fiber, neutral detergent fiber, and nonstarch polysaccharides in relation to animal nutrition[J]. J Dairy Sci, 1991, 74(10):3583-3597. http://cn.bing.com/academic/profile?id=5b448bcfd7a32018d19d2006e09e43e6&encoded=0&v=paper_preview&mkt=zh-cn
[18]	李艳美, 柏雪源, 易维明. 3种不同原料生物油主要化学成分的GC-MS分析[J].山东科学, 2016, 29(1):56-61. http://d.old.wanfangdata.com.cn/Periodical/sdkx201601010 LI Yan-mei, BAI Xue-yuan, YI Wei-ming. GC-MS analysis of main chemical components for bio-oil from three different biomass materials[J]. Shandong Sci, 2016, 29(1):56-61. http://d.old.wanfangdata.com.cn/Periodical/sdkx201601010
[19]	YIN S, TAN Z. Hydrothermal liquefaction of cellulose to bio-oil under acidic, neutral and alkaline conditions[J]. Appl Energy, 2012, 92:234-239. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=86b3783d543218b126d7d6cdd3db26ea
[20]	CHEN H, HE Z, ZHANG B, FENG H, KANDASAMY S, WANG B. Effects of the aqueous phase recycling on bio-oil yield in hydrothermal liquefaction of spirulina platensis, α-cellulose, and lignin[J]. Energy, 2019, 179:1103-1113. doi: 10.1016/j.energy.2019.04.184
[21]	高英, 陈汉平, 汪君, 石韬, 杨海平, 王贤华.生物质水热液化和炭化率物特性研究[J].燃料化学学报, 2011, 39(12):893-900. GAO Ying, CHEN Han-ping, WANG Jun, SHI Tao, YANG Hai-ping. Characterization of products from hydrothermal liquefaction and carbonation of biomass model compounds and real biomass[J]. J Fuel Chem Technol, 2011, 39(12):893-900.
[22]	ROSS A, JONES J, KUBACKI M, BRIDGEMAN T. Classification of macroalgae as fuel and its thermochemical behaviour[J]. Bioresour Technol, 2008, 99(14):6494-6504. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=43d1e873b822c0ee3ac7e10a56a2c421
[23]	HU Y, FENG S, YUAN Z, XU C C, BASSI A. Investigation of aqueous phase recycling for improving bio-crude oil yield in hydrothermal liquefaction of algae[J]. Bioresour Technol, 2017, 239:151-159. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=101406ada755eadd37460d4d045b115a
[24]	朱哲.生物质水热液化制备生物油及其性质分析的研究[D].天津: 天津大学, 2014. ZHU Zhe. Study on hydrothermal liquefaction of biomass for bio-crude production and product characterization[D]. Tianjin: Tianjin University, 2014.
[25]	胡见波, 杜泽学, 闵恩泽.生物质水热液化机理研究进展[J].石油炼制与化工, 2012, 43(4):87-92. http://d.old.wanfangdata.com.cn/Periodical/sylzyhg201204019 HU Jian-bo, DU Ze-xue, MIN En-ze. Progress in research of reaction mechanism concerning hydrothermal liquefaction of biomass[J]. Pet Process Petrochem, 2012, 43(4):87-92. http://d.old.wanfangdata.com.cn/Periodical/sylzyhg201204019
[26]	ROSS A B, BILLER P, KUBACKI M L, LI H, LEA-LANGTON A, JONES J M. Hydrothermal processing of microalgae using alkali and organic acids[J]. Fuel, 2010, 89(9):2234-2243. doi: 10.1016-j.fuel.2010.01.025/
[27]	XU D, SAVAGE P E. Characterization of biocrudes recovered with and without solvent after hydrothermal liquefaction of algae[J]. Algal Res, 2014, 6:1-7. http://cn.bing.com/academic/profile?id=5426de7490f5dab8633ee0b20c88fcd8&encoded=0&v=paper_preview&mkt=zh-cn
[28]	ZHU Z, SI B, LU J, WATSON J, ZHANG Y, LIU Z. Elemental migration and characterization of products during hydrothermal liquefaction of cornstalk[J]. Bioresour Technol, 2017, 243:9-16. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=ea11a90341a111c134be79f320c06e2c
[29]	李润东, 张扬, 李秉硕, 刘合鑫, 开兴平, 烟征, 杨天华.玉米秸秆催化液化制备生物油实验研究[J].燃料化学学报, 2016, 44(1): 69-75. LI Run-dong, ZHANG Yang, LI Bing-suo, LIU He-xin, KAI Xing-ping, YAN Zheng, YANG Tian-hua. Hydrothermal catalytic liquefaction of corn stalk for preparation of bio-oil[J]. 2016, 44(1): 69-75.
[30]	田纯焱.富营养化藻的特性与水热液化成油的研究[D].北京: 中国农业大学, 2015. TIAN Chun-yan. Characteristics of eutrophicated algae and biocrude oil production through hydrothermal liquefaction[D]. Beijing: China Agricultural University, 2015.