Preparation of layered K-Fe-Zn-Ti catalyst and its performance in the hydrogenation of carbon dioxide to light olefins

WU Da-kai; WANG Xu; GAO Xin-hua; MA Qing-xiang; ZHANG Jian-li; FAN Su-bing; ZHAO Tian-sheng

Volume 47 Issue 8

Aug. 2019

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Article Navigation > Journal of Fuel Chemistry and Technology > 2019 > 47(8): 949-956

WU Da-kai, WANG Xu, GAO Xin-hua, MA Qing-xiang, ZHANG Jian-li, FAN Su-bing, ZHAO Tian-sheng. Preparation of layered K-Fe-Zn-Ti catalyst and its performance in the hydrogenation of carbon dioxide to light olefins[J]. Journal of Fuel Chemistry and Technology, 2019, 47(8): 949-956.

Citation:

WU Da-kai, WANG Xu, GAO Xin-hua, MA Qing-xiang, ZHANG Jian-li, FAN Su-bing, ZHAO Tian-sheng. Preparation of layered K-Fe-Zn-Ti catalyst and its performance in the hydrogenation of carbon dioxide to light olefins[J]. Journal of Fuel Chemistry and Technology, 2019, 47(8): 949-956.

Citation:

WU Da-kai, WANG Xu, GAO Xin-hua, MA Qing-xiang, ZHANG Jian-li, FAN Su-bing, ZHAO Tian-sheng. Preparation of layered K-Fe-Zn-Ti catalyst and its performance in the hydrogenation of carbon dioxide to light olefins[J]. Journal of Fuel Chemistry and Technology, 2019, 47(8): 949-956.

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Preparation of layered K-Fe-Zn-Ti catalyst and its performance in the hydrogenation of carbon dioxide to light olefins

State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, Ningxia University, Yinchuan 750021

Funds:

the National Natural Science Foundation of China 21666030

the Natural Science Foundation of Ningxia 2018AAC02002

the Key R & D Project of Ningxia 2018BEE03010

More Information

Corresponding author: GAO Xin-hua, E-mail: gxh@nxu.edu.cn; ZHANG Jian-li, Tel: 0951-2062323, Fax: 0951-2062323, E-mail: zhangjl@nxu.edu.cn
Received Date: 2019-03-22
Rev Recd Date: 2019-05-09

Available Online: 2021-01-23

Publish Date: 2019-08-10

Abstract

Abstract

A series of layered K-Fe-Zn-Ti catalysts with different Zn/Fe molar ratios were prepared by high-temperature solid state reaction and characterized by SEM, TEM, XRD, H₂-TPR, CO₂-TPD, XPS, N₂ sorption and TG measurements; the performance of K-Fe-Zn-Ti catalysts in the hydrogenation of CO₂ to light olefins was investigated. The results indicate that the K-Fe-Zn-Ti catalysts have the typical layered structure with K_2.3Fe_2.3Ti_5.7O₁₆ as the main phase. ZnFe₂O₄ appears on the Zn promoted K-Fe-Zn-Ti catalysts, which may reduce the crystallinity, enhance the surface basicity, and promote the adsorption of CO₂. The K-Fe-Zn-Ti catalysts exhibit high selectivity to olefins in CO₂ hydrogenation; the ratio of olefins to paraffins in the products (O/P) is higher than 6.5. The addition of Zn can enhance the formation of C₅⁺ hydrocarbons and especially C₄⁺ linear alpha-olefins (LAOs); the content of LAOs in C₄⁺ hydrocarbons over Zn promoted K-Fe-Zn-Ti reaches 75.2%, in comparison with the value of 54.6% over the Zn-free K-Fe-Ti catalyst. In particular, the 0.8K-1.8Fe-0.6Zn-1.3Ti catalyst displays the highest O/P value (7.8), although the effect of Zn content in the Zn-promoted K-Fe-Zn-Ti catalysts on the yield of heavy hydrocarbons and selectivity to alpha-olefins is less significant. Moreover, the K-Fe-Zn-Ti catalysts display high stability in CO₂ hydrogenation and the LMO structure remains almost intact after a long term reaction test of 100 h.
- layered K-Fe-Zn-Ti catalyst,
- CO₂ hydrogenation,
- light olefins,
- linear α-olefins

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References(30)

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