Preparation of anionic functionalized ionic liquid antioxidant[X] [C6H5COO] for biodiesel

SUI Meng; LI Fa-she; WU Xue-hua; WANG Shuang; LI Ming

Volume 47 Issue 1

Jan. 2019

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Article Navigation > Journal of Fuel Chemistry and Technology > 2019 > 47(1): 66-73

SUI Meng, LI Fa-she, WU Xue-hua, WANG Shuang, LI Ming. Preparation of anionic functionalized ionic liquid antioxidant[X] [C6H5COO] for biodiesel[J]. Journal of Fuel Chemistry and Technology, 2019, 47(1): 66-73.

Citation:

SUI Meng, LI Fa-she, WU Xue-hua, WANG Shuang, LI Ming. Preparation of anionic functionalized ionic liquid antioxidant[X] [C₆H₅COO] for biodiesel[J]. Journal of Fuel Chemistry and Technology, 2019, 47(1): 66-73.

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Preparation of anionic functionalized ionic liquid antioxidant[X] [C₆H₅COO] for biodiesel

SUI Meng^{1, 2},
LI Fa-she^{1, 2
,
,},
WU Xue-hua^{1, 3},
WANG Shuang²,
LI Ming⁴

1.
Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
2.
Engineering Research Center of Metallurgical Energy Conservation & Emission Reduction, Ministry of Education, Kunming 650093, China
3.
Kunming University of Science and Technology, Kunming 650093, China
4.
Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510000, China

Funds:

the National Natural Science Foundation of China 51766007

Natural Science Foundation of Yunnan Province 2015FB128

Natural Science Foundation of Yunnan Province 2018FB092

NSFC-Yunnan Joint Fund Project U1602272

State Key Laboratory of Clean and Applied Utilization of Complex Nonferrous Metal Resources CNMRCUTS1704

Yunnan Science and Technology Department Foundation Youth project 2016FD055

Received Date: 2018-08-06
Rev Recd Date: 2018-11-06

Available Online: 2021-01-23

Publish Date: 2019-01-10

Abstract

Abstract

Two ionic liquid antioxidants ([MI] [C₆H₅COO], [Ch] [C₆H₅COO]) were designed, and synthesized, and measured by nuclear magnetic resonance spectra and Fourier infrared spectra.The effects of two ionic liquid antioxidants on the oxidation resistance, copper corrosion and oil solubility of Jatropha biodiesel were studied.The results show that ionic liquid antioxidants can effectively improve the oxidative stability of biodiesel. When the addition amount of[MI] [C₆H₅COO] is 0.3‰, the induction period of Jatropha biodiesel increases by 238%, exceeding the national standard (6 h). However, when the addition amount of[Ch] [C₆H₅COO] is 0.3‰, the induction period of Jatropha biodiesel increases by 141%, which does not meet the national standard. The order of oil solubility from large to small is[MI] [C₆H₅COO] > [Ch] [C₆H₅COO] > GA (raw material for synthesizing ionic liquid antioxidants).Moreover, the experiments show that the synthetic properties of[MI] [C₆H₅COO] containing lipophilic cations in the two ionic liquid antioxidants are significantly better than those containing hydrophilic cations[Ch] [C₆H₅COO].
- ionic liquid,
- biodiesel,
- antioxidants,
- oil solubility,
- oxidative stability

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References(22)

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