Synthesis of N, P-doped C@Mo<sub>2</sub>C catalyst and its application in CO<sub>2</sub> hydrogenation

GENG Wen-hao; LIU Fei; HAN Han; XIAO Lin-fei; WU Wei

Volume 45 Issue 4

Apr. 2017

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Article Navigation > Journal of Fuel Chemistry and Technology > 2017 > 45(4): 458-467

GENG Wen-hao, LIU Fei, HAN Han, XIAO Lin-fei, WU Wei. Synthesis of N, P-doped C@Mo2C catalyst and its application in CO2 hydrogenation[J]. Journal of Fuel Chemistry and Technology, 2017, 45(4): 458-467.

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GENG Wen-hao, LIU Fei, HAN Han, XIAO Lin-fei, WU Wei. Synthesis of N, P-doped C@Mo₂C catalyst and its application in CO₂ hydrogenation[J]. Journal of Fuel Chemistry and Technology, 2017, 45(4): 458-467.

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Synthesis of N, P-doped C@Mo₂C catalyst and its application in CO₂ hydrogenation

National Center for International Joint Research on Catalytic Technology, Key Laboratory of Chemical Engineering Process & Technology for High-efficiency Conversion, College of Heilongjiang Province, School of Chemistry and Material Sciences, Heilongjiang University, Harbin 150080, China

Funds:

the Foundation for Youth Science and Technology Innovation Talents of Harbin of China RC2013LX018002

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Corresponding author: XIAO Lin-fei, E-mail:xiaolf@hlju.edu.cn; WU Wei, E-mail:wuwei@hlju.edu.cn
Received Date: 2016-11-14
Rev Recd Date: 2017-01-22

Available Online: 2021-01-23

Publish Date: 2017-04-10

Abstract

Abstract

The N, P-doped C@Mo₂C catalysts were prepared using melamine benzoate as the source of nitrogen and carbon, melamine phosphomolybdate as the source of phosphorus, nitrogen and molybdenum, respectively. The surface structures of the prepared catalysts were characterized by XRD, SEM, TEM and XPS. The effects of the ratio of benzoic acid to melamine in melamine benzoate and n(C)/n(Mo) of the precursor on the catalysts were investigated. The activity of the catalysts was evaluated by using CO₂ hydrogenation as a model reaction in a fixed-bed reactor, in which a mixed gas of CO₂/H₂ (V_H₂:V_CO₂=3:1) was used as the feed gas, and it was found that the N, P-doped C@Mo₂C showed a good catalytic performance with CO₂ conversion of 12.2% and methanol selectivity of 52.2% under the optimal reaction conditions (reaction temperature 220℃, reaction pressure 3.0 MPa, space velocity 3 600 mL/(g·h).
- N, P-doped C@Mo₂C,
- β-Mo₂C,
- CO₂ hydrogenation,
- methanol

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References(35)

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