Volume 48 Issue 12
Dec.  2020
Turn off MathJax
Article Contents
LI Wen-ju, GONG Ben-gen, ZHANG Jun-ying. Study on the mineral transformation and heavy metal distribution during high-silicon coal combustion[J]. Journal of Fuel Chemistry and Technology, 2020, 48(12): 1488-1497.
Citation: LI Wen-ju, GONG Ben-gen, ZHANG Jun-ying. Study on the mineral transformation and heavy metal distribution during high-silicon coal combustion[J]. Journal of Fuel Chemistry and Technology, 2020, 48(12): 1488-1497.

Study on the mineral transformation and heavy metal distribution during high-silicon coal combustion

Funds:

the National Key Research and Development Program of China 2017YFB0603101

National Natural Science Foundation of China 41672148

Soft Science Project of Henan Science and Technology Department 202400410295

Key Scientific Research Projects of Colleges and Universities in Henan Province 20B610007

More Information
  • Corresponding author: ZHANG Jun-ying, Tel:18971412881, E-mail:jyzhang@hust.edu.cn
  • Received Date: 2020-09-09
  • Rev Recd Date: 2020-10-13
  • Available Online: 2021-01-23
  • Publish Date: 2020-12-10
  • The high-silicon coal in Xuanwei area of Yunnan is selected to study the transformation behavior of minerals and the distribution and enrichment of heavy metals during the combustion process. The minerals in high-silicon coal are mainly composed of quartz, kaolinite, pyrite and anatase. The mullite in fly ash may come from the transformation of quartz and kaolinite in coal; the quartz in fly ash mainly comes from the original quartz component in coal or is formed by the conversion of SiO2-Al2O3 system. Analyzing the enrichment characteristics of several heavy metals in high-silicon coal and its fly ash, it can be found that Cr, Cu, and As are enriched in the high-silicon coal, and Mo is the heavy metal enriched in the electric fields of the ESP, while Se contents in high-silicon coal and fly ash in China are both lower than the world average level. The contents of radioactive elements of Th and U in the fine-particle high-silicon fly ash are higher than the average of world coal ash, and the enrichment factors in the fly ash in the four electric fields of the ESP are 1.51 and 1.59, respectively.
  • loading
  • [1]
    LU S Y, ZHANG H M, SOJINU S O, LIU G H, ZHANG J Q, NI H G. Trace elements contamination and human health risk assessment in drinking water from Shenzhen, China[J]. Environ Monit Assess, 2015, 187(1): 4220.
    [2]
    MEHARG A A, RAHMAN M M. Arsenic contamination of Bangladesh paddy field soils: Implications for rice contribution to arsenic consumption[J]. Environ Sci Technol, 2003, 37(2): 229-234.
    [3]
    YANG P T, HASHIMOTO Y, WU W J, HUANG J H, CHIANG P N, WANG S L. Effects of long-term paddy rice cultivation on soil arsenic speciation[J]. J Environ Manage, 2020, 254: 109768.
    [4]
    CLARKE L B, SLOSS L L. Trace Elements Emissions from Coal Combustion and Gasification[M]. London: IEA Coal Research, 1992, 111.
    [5]
    YAO Z T, JI X S, SARKER P K, TANG J H, GE L Q, XIA M S, XI Y Q. A comprehensive review on the applications of coal fly ash[J]. EarthA-Sci Rev, 2015, 141: 105-121.
    [6]
    刘桂建, 彭子成, 杨萍玥, 王桂梁, 宋超.煤中微量元素在燃烧过程中的变化[J].燃料化学学报, 2001, 29(2): 119-123.

    LIU Gui-jian, PENG Zi-cheng, YANG Ping-yue, WANG Gui-liang, SONG Chao. Changes of trace elemetns in coal during combustion[J]. J Fuel Chem Technol, 2001, 29(2): 119-123.
    [7]
    FINKELMAN R B, OREM W, CASTRANOVA V, TATU C A, BELKIN H B, ZHENG B, LERCH H E, MAHARAJ S V, BATES A L. Health impacts of coal and coal use: Possible solutions[J]. Int J Coal Geol, 2002, 50(1/4): 425-443.
    [8]
    SAIKIA B K, WARD C R, OLIVEIRA M L S, HOWER J C, LEAO F D, JOHNSTON M N, O'BRYAN A, SHARMA A, BARUAH B P, SILVA L F O. Geochemistry and nano-mineralogy of feed coals, mine overburden, and coal-derived fly ashes from Assam (North-east India): A multi-faceted analytical approach[J]. Int J Coal Geol, 2015, 137: 19-37.
    [9]
    JONES K B, RUPPERT L F, SWANSON S M. Leaching of elements from bottom ash, economizer fly ash, and fly ash from two coal-fired power plants[J]. Int J Coal Geol, 2012, 94: 337-348.
    [10]
    DUTTA B K, KHANRA S, MALLICK D. Leaching of elements from coal fly ash: Assessment of its potential for use in filling abandoned coal mines[J]. Fuel, 2009, 88(7): 1314-1323.
    [11]
    AKAR G, POLAT M, GALECKI G, IPEKOGLU U. Leaching behavior of selected trace elements in coal fly ash samples from Yenikoy coal-fired power plants[J]. Fuel Process Technol, 2012, 104: 50-56.
    [12]
    JEGADEESAN G, AL-ABED, S R, PINTO P. Influence of trace metal distribution on its leachability from coal fly ash[J]. Fuel, 2008, 87(10/11): 1887-1893.
    [13]
    董静兰, 耿晓, 高正阳, 刘彦丰.飞灰中的缺陷位SiO2对痕量元素As的吸附机理[J].燃料化学学报, 2018, 46(11): 1401-1408.

    DONG Jing-lan, GENG Xiao, GAO Zheng-yang, LIU Yan-feng. Adsorption mechanism of trace As on the defect sites of SiO2 in fly ash[J]. J Fuel Chem Technol, 2018, 46(11): 1401-1408.
    [14]
    ZHAO S L, DUAN Y F, LIU M, WANG C P, ZHOU Q, LU J H. Effects on enrichment characteristics of trace elements in fly ash by adding halide salts into the coal during CFB combustion[J]. J Energy Inst, 2018, 91(2): 214-221.
    [15]
    LAN Q, HE X Z, COSTA D J, TIAN L W, ROTHMAN N, HU G, MUMFORD J L. Indoor coal combustion emissions, GSTM1 and GSTT1 genotypes, and lung canceer risk: A case-control study in Xun Wei, China[J]. Cancer Epidem Biomar, 2000, 9(6): 605-608.
    [16]
    DAI S F, TIAN L W, CHOU C L, ZHOU Y P, ZHANG M Q, ZHAO L, WANG J M, YANG Z, CAO H Z, REN D Y. Mineralogical and compositional characteristics of Late Permian coals from an area of high lung cancer rate in Xuan Wei, Yunnan, China: Occurrence and origin of quartz and chamosite[J]. Int J Coal Geol, 2008, 76(4): 318-327.
    [17]
    雍其润, 龚本根, 赵永椿, 张军营.高硅煤中Si-Al-Fe-Ca四元体系碳热反应研究[J].燃料化学学报, 2017, 45(11): 1296-1302.

    YONG Qi-run, GONG Ben-gen, ZHAO Yong-chun, ZHANG Jun-ying. Carbothermal reduction of Si-Al-Fe-Ca quaternary system in a high-silica coal[J]. J Fuel Chem Technol, 2017, 45(11): 1296-1302.
    [18]
    周林, 邵龙义, 刘君霞, 宋晓焱.宣威肺癌高发区室内PM10对肺泡上皮细胞凋亡的影响[J].中国环境科学, 2010, 30(7): 1004-1008.

    ZHOU Lin, SHAO Long-yi, LIU Jun-xia, SONG Xiao-yan. Affects of indoor PM10 in Xuanwei on lung cell apoptosis[J]. China Environ Sci, 2010, 30(7): 1004-1008.
    [19]
    樊景森, 邵龙义, 王静, 王建英, 李泽熙.云南宣威燃煤室内可吸入颗粒物质量浓度变化特征[J].中国环境科学, 2012, 32(8): 1379-1383.

    FAN Jing-sen, SHAO Long-yi, WANG Jing, WANG Jian-ying, LI Ze-xi. Variations in mass concentrations of indoor inhalable particulates in the coal-burning indoor air in Xuanwei County, Yunnan province[J]. China Environ Sci, 2012, 32(8): 1379-1383.
    [20]
    ZHAO Y C, ZHANG J Y, ZHENG C G. Transformation of aluminum-rich minerals during combustion of a bauxite-bearing Chinese coal[J]. Int J Coal Geol, 2012, 94: 182-190.
    [21]
    于敦喜, 徐明厚, 易帆, 黄建辉, 李庚.燃煤过程中颗粒物的形成机理研究进展[J].煤炭转化, 2004, 27(4): 7-12.

    YU Dun-xi, XU Ming-hou, YI Fan, HUANG Jian-hui, LI Geng. A review on particle formation mechanisms during coal combstion[J]. Coal Convers, 2004, 27(4): 7-12.
    [22]
    KETRIS M P, YUDOVICH Y E. Estimations of clarkes for carbonaceous biolithes: World averages for trace element contents in black shales and coals[J]. Int J Coal Geol, 2009, 78(2): 135-148.
    [23]
    MARTINEZ-TARAZONA M R, SPEARS D A. The fate of trace elements and bulk minerals in pulverized coal combustion in a power station[J]. Fuel Process Technol, 1996, 47(1): 79-92.
    [24]
    BUHRE B J P, HINKEY J T, GUPTA R P, NELSON P F, WALL T F. Fine ash formation during combustion of pulverised coal-coal property impacts[J]. Fuel, 2006, 85(2): 185-193.
    [25]
    MCLENNAN A R, BRYANT G W, STANMORE B R, WALL T F. Ash formation mechanisms during pf combustion in reducing conditions[J]. Energy Fuels, 2000, 14(1): 150-159.
    [26]
    SENIOR C L, BOOL Ⅲ L E, SRINIVASACHAR S, PEASE B R, PORLE K. Pilot scale study of trace element vaporization and condensation during combustion of a pulverized sub-bituminous coal[J]. Fuel Process Technol, 2000, 63: 149-165.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (272) PDF downloads(19) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return