Synthesis of hierarchical Mo/H-IM-5 catalysts by using mesoporous material as the silica source and its application in methane non-oxidative aromatization

LIU Heng; KAN Qiu-bin

Volume 44 Issue 11

Nov. 2016

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Article Navigation > Journal of Fuel Chemistry and Technology > 2016 > 44(11): 1380-1387

LIU Heng, KAN Qiu-bin. Synthesis of hierarchical Mo/H-IM-5 catalysts by using mesoporous material as the silica source and its application in methane non-oxidative aromatization[J]. Journal of Fuel Chemistry and Technology, 2016, 44(11): 1380-1387.

Citation:

LIU Heng, KAN Qiu-bin. Synthesis of hierarchical Mo/H-IM-5 catalysts by using mesoporous material as the silica source and its application in methane non-oxidative aromatization[J]. Journal of Fuel Chemistry and Technology, 2016, 44(11): 1380-1387.

Citation:

LIU Heng, KAN Qiu-bin. Synthesis of hierarchical Mo/H-IM-5 catalysts by using mesoporous material as the silica source and its application in methane non-oxidative aromatization[J]. Journal of Fuel Chemistry and Technology, 2016, 44(11): 1380-1387.

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Synthesis of hierarchical Mo/H-IM-5 catalysts by using mesoporous material as the silica source and its application in methane non-oxidative aromatization

LIU Heng^{1
,
,},
KAN Qiu-bin²

1.
Research Center for Nanotechnology, Changchun University of Science and Technology, Changchun 130022, China
2.
College of Chemistry, Jilin University, Changchun 130023, China

Funds:

Youth Fund of Changchun University of Science and Technology XJJLG-2015-12

Received Date: 2016-06-24
Rev Recd Date: 2016-08-08

Available Online: 2021-01-23

Publish Date: 2016-11-10

Abstract

Abstract

A novel hierarchical porous IM-5 (IM-5-K) was synthesized by using mesoporous silica KIT-6 as the silica sources. The physical properties and acidities of the samples were characterized by XRD, SEM, TEM, BET and NH₃-TPD. Moreover, Mo-modified catalyst, Mo-IM-5-K was prepared for non-oxidative aromatization of methane. Compared with Mo-IM-5-C, the Mo-IM-5-K catalyst showed higher conversion of methane and yields of aromatics. In addition, Mo-IM-5-K exhibited better stability than Mo-IM-5-C. Different activities and stabilities of the catalysts may be due to their different structure properties and acidities. The existence of secondary mesoporous systems may influence the location and state of the active Mo species, simultaneously lead to easier access to the active sites for reactants and better diffusion of aromatic products, thus improvs the activities of the catalysts.
- IM-5,
- mesoporous,
- molybdenum,
- methane dehydroaromatiztion

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References(25)

References

[1]	MA S, GUO X, ZHAO L, SCOTTC S, BAO X. Recent progress in methane dehydroaromatization:From laboratory curiosities to promising technology[J]. J Energy Chem, 2013, 22(1):1-20. doi: 10.1016/S2095-4956(13)60001-7
[2]	LUNSFORD J H. Catalytic conversion of methane to more useful chemicals and fuels:A challenge for the 21st century[J]. Catal Today, 2000, 63(2/4):165-174. https://www.researchgate.net/publication/222301582_Catalytic_conversion_of_methane_to_more_useful_chemicals_and_fuels_A_challenge_for_the_21st_century
[3]	XU C, GUAN J, WU S, JIA M, WU T, KAN Q. Catalytic performance of zeolite ITQ-13 with 9-and 10-member rings for methane dehydroaromation[J]. React Kinet Mech Catal, 2010, 99(1):193-199. https://www.researchgate.net/publication/245465093_Catalytic_performance_of_zeolite_ITQ-13_with_9-_and_10-member_rings_for_methane_dehydroaromation
[4]	LIU H, HU J, LI Z, WU S, LIU L, GUAN J, KAN Q. Synthesis of zeolite IM-5 under rotating and static conditions and the catalytic performance of Mo/H-IM-5 catalyst in methane non-oxidative aromatization[J]. Kinet Catal, 2013, 54(4):443-450. doi: 10.1134/S0023158413040083
[5]	胥月兵, 陆江银, 王吉德, 张战国. Mo基分子筛催化剂及甲烷无氧芳构化[J].化学进展, 2011, 23(1):90-106. http://www.cnki.com.cn/Article/CJFDTOTAL-HXJZ201101011.htm XU Yue-bing, LU Jiang-yin, WANG Ji-de, ZHANG Zhan-guo. Mo-based zeolite catalysts and oxygen-free methane aromatization[J]. Prog Chem, 2011, 23(1):90-106. http://www.cnki.com.cn/Article/CJFDTOTAL-HXJZ201101011.htm
[6]	WANG D, KAN Q, XU N, WU P, WU T. Study on methane aromatization over MoO₃/HMCM-49 catalyst[J]. Catal Today, 2004, 93:75-80.
[7]	LIU H, YANG S, WU S, SHANG F, YU X, XU C, GUAN J, KAN Q. Synthesis of Mo/TNU-9(TNU-9 Taejon National University No. 9) catalyst and its catalytic performance in methane non-oxidative aromatization[J]. Energy, 2011, 36:1582-1589. doi: 10.1016/j.energy.2010.12.073
[8]	LIU H, YANG S, HU J, SHANG F, LI Z, XU C, GUAN J, KAN Q. A comparison study of mesoporous Mo/H-ZSM-5 and conventional Mo/H-ZSM-5 catalysts in methane non-oxidative aromatization[J]. Fuel Process Technol, 2012, 96:195-202. doi: 10.1016/j.fuproc.2011.12.034
[9]	WU P, KAN Q, WANG X, WANG D, XING H, YANG P, WU T. Acidity and catalytic properties for methane conversion of Mo/HZSM-5 catalyst modified by reacting with organometallic complex[J]. Appl Catal A:Gen, 2005, 282(1/2):39-44. https://www.researchgate.net/publication/229323763_Acidity_and_catalytic_properties_for_methane_conversion_of_MoHZSM-5_catalyst_modified_by_reacting_with_organometallic_complex?_sg=SwMsmLyYdTDIJtGEy9ultYp-tQUp8zkQBg5V61-6Ch_S-ohmKFe1EY6Jx-bC9RR8l-1sCW9R2gJkffnjL1i6Zg
[10]	杨建华, 于素霞, 胡慧晔, 初乃波, 鲁金明, 殷德宏, 王金渠.无第二模板剂法合成多级结构ZSM-5分子筛微球及其在甲烷无氧芳构化反应中的应用[J].催化学报, 2011, 32(2):362-367. http://www.cnki.com.cn/Article/CJFDTOTAL-CHUA201102026.htm YANG Jian-hua, YU Su-xia, HU Hui-ye, CHU Nai-bo, LU Jin-ming, YIN De-hong, WANG Jin-qu. Synthesis of hierarchical HZSM-5 microspheres without second template and their application in methane dehydroaromatization[J]. Chin J Catal, 2011, 32(2):362-367. http://www.cnki.com.cn/Article/CJFDTOTAL-CHUA201102026.htm
[11]	王迪勇, 王金渠, 杨建华, 鲁金明, 殷德宏, 张艳.蒸气相法ZSM-5分子筛的合成及其负载的Mo催化剂在甲烷芳构化中的应用[J].催化学报, 2012, 33(8):1383-1388. http://www.cnki.com.cn/Article/CJFDTOTAL-CHUA201208023.htm WANG Di-yong, WANG Jin-qu, YANG Jian-hua, LU Jin-ming, YIN De-hong, ZHANG Yan. Synthesis of ZSM-5 zeolite by vapor-phase method and performance of its Mo-based catalyst for methane dehydroaromatization[J]. Chin J Catal, 2012, 33(8):1383-1388. http://www.cnki.com.cn/Article/CJFDTOTAL-CHUA201208023.htm
[12]	张航飞, 马记源, 尹金莲, 周蓉, 陆江银.改性Mo-Co/HZSM-5催化剂对甲烷无氧芳构化反应的影响[J].现代化工, 2015, 35(11):77-80. http://www.cnki.com.cn/Article/CJFDTOTAL-XDHG201511019.htm ZHANG Hang-fei, MA Ji-yuan, YIN Jin-lian, ZHOU Rong, LU Jiang-yin. Effect of methane dehydroaromatization over modified 6%Mo-0.7%Co/HZSM-5 catalysts in absence of oxidants[J]. Mod Chem Ind, 2015, 35(11):77-80. http://www.cnki.com.cn/Article/CJFDTOTAL-XDHG201511019.htm
[13]	GUO X, FANG G, LI G, MA H, FAN H, YU L, MA C, WU X, DENG D, WEI M, TAN D, SI R, ZHANG S, LI J, SUN L, TANG Z, PAN X, BAO X. Direct, nonoxidative conversion of methane to ethylene, aromatics, and hydrogen[J]. Science, 2014, 344(6184):616-619. doi: 10.1126/science.1253150
[14]	KLEITZ F, CHOI S H, RYOO R. Cubic Ia3d large mesoporous silica:Synthesis and replication to platinum nanowires, carbon nanorods and carbon nanotubes[J]. Chem Commun, 2003, 9(17):2136-2137.
[15]	OVEISI H, ANAND C, MANO A, AL-DEYAB S S, KALITA P, BEITOLLAHI A, VINU A. Inclusion of size controlled gallium oxide nanoparticles into highly ordered 3D mesoporous silica with tunable pore diameters and their unusual catalytic performance[J]. J Mater Chem, 2010, 20(45):10120-10129. doi: 10.1039/c0jm02006k
[16]	CORMA A, MENGUAL J, MIGUEL P J. IM-5 zeolite for steam catalytic cracking of naphtha to produce propene and ethene. An alternative to ZSM-5 zeolite[J]. Appl Catal A:Gen, 2013, 460-461(11):106-115.
[17]	LIU H, WU S, GUO Y, SHANG F, YU X, MA Y, XU C, GUAN J, KAN Q. Synthesis of Mo/IM-5 catalyst and its catalytic behavior in methane non-oxidative aromatization[J]. Fuel, 2011, 90:1515-1521. doi: 10.1016/j.fuel.2010.11.027
[18]	VENNESTRØM P N R, JANSSENS T V W, KUSTOV A, GRILL M, PUIG-MOLINA A, LUNDEGAARD L F, TIRUVALAM R R, CONCEPCIÓN P, CORMA A. Influence of lattice stability on hydrothermal deactivation of Cu-ZSM-5 and Cu-IM-5 zeolites for selective catalytic reduction of NO_x by NH₃[J]. J Catal, 2014, 309(6):477-490.
[19]	陈俊文, 张超, 王永睿, 孙敏, 慕旭宏, 舒兴田.改性IM-5分子筛在甲苯甲醇烷基化反应中的催化性能[J].石油学报(石油加工), 2013, 29(5):757-766. http://www.cnki.com.cn/Article/CJFDTOTAL-SXJG201305003.htm CHEN Jun-wen, ZHANG Chao, WANG Yong-rui, SUN Min, MU Xu-hong, SHU Xing-tian. Catalytic performance of modified IM-5 zeolite in alkylation of toluene with methanol[J]. Acta Pet Sin (Pet Process Sect), 2013, 29(5):757-766. http://www.cnki.com.cn/Article/CJFDTOTAL-SXJG201305003.htm
[20]	PARLETT C M, WILSON K, LEE A F. Hierarchical porous materials:Catalytic applications[J]. Chem Soc Rev, 2013, 42(9):3876-3893. doi: 10.1039/C2CS35378D
[21]	SACHSE A, WUTTKE C, DÍAZ U, DESOUZA M O. Mesoporous Y zeolite through ionic liquid based surfactant templating[J]. Microporous Mesoporous Mater, 2015, 217:81-86. doi: 10.1016/j.micromeso.2015.05.049
[22]	KOOHSARYAN E, ANBIA M.纳米多级孔分子筛:简短的综述[J].催化学报, 2016, 37(4):447-467. doi: 10.1016/S1872-2067(15)61038-5 KOOHSARYAN E, ANBIA M. Nanosized and hierarchical zeolites:A short review[J]. Chin J Catal, 2016, 37(4):447-467. doi: 10.1016/S1872-2067(15)61038-5
[23]	崔生航, 张君涛, 申志兵.多级孔道ZSM-5分子筛的合成及其催化应用[J].化工进展, 2015, 34(9):3311-3316. http://www.cnki.com.cn/Article/CJFDTOTAL-HGJZ201509018.htm CUI Sheng-hang, ZHANG Jun-tao, SHEN Zhi-bing. Hierarchical ZSM-5 zeolite:Synthesis and catalytic applications[J]. Chem Ind Eng Prog, 2015, 34(9):3311-3316. http://www.cnki.com.cn/Article/CJFDTOTAL-HGJZ201509018.htm
[24]	刘晓玲, 姜健准, 张明森.合成多级孔分子筛的研究进展[J].工业催化, 2016, 24(3):10-18. http://www.cnki.com.cn/Article/CJFDTOTAL-GYCH201603002.htm LIU Xiao-ling, JIANG Jian-zhun, ZHANG Ming-sen. Research advance in synthesis of hierarchical molecular sieves[J]. Ind Catal, 2016, 24(3):10-18. http://www.cnki.com.cn/Article/CJFDTOTAL-GYCH201603002.htm
[25]	LI B, LI S, LI N, CHEN H, ZHANG W, BAO X, LIN B. Structure and acidity of Mo/ZSM-5 synthesized by solid state reaction for methane dehydrogenation and aromatization[J]. Microporous Mesoporous Mater, 2006, 88(1/3):244-253. https://www.researchgate.net/publication/222531373_Structure_and_acidity_of_MoZSM-5_synthesized_by_solid_state_reaction_for_methane_dehydrogenation_and_aromatization