Construction of synergistic and efficient iron-based catalysts for hydrogenation of CO<sub>2</sub> to higher hydrocarbons

JI Xue-wei; GE Qing-jie; SUN Jian

Volume 47 Issue 4

Apr. 2019

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Article Navigation > Journal of Fuel Chemistry and Technology > 2019 > 47(4): 438-445

JI Xue-wei, GE Qing-jie, SUN Jian. Construction of synergistic and efficient iron-based catalysts for hydrogenation of CO2 to higher hydrocarbons[J]. Journal of Fuel Chemistry and Technology, 2019, 47(4): 438-445.

Citation:

JI Xue-wei, GE Qing-jie, SUN Jian. Construction of synergistic and efficient iron-based catalysts for hydrogenation of CO₂ to higher hydrocarbons[J]. Journal of Fuel Chemistry and Technology, 2019, 47(4): 438-445.

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Construction of synergistic and efficient iron-based catalysts for hydrogenation of CO₂ to higher hydrocarbons

JI Xue-wei^{1, 2},
GE Qing-jie¹,
SUN Jian^{1
,
,}

1.
Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Funds:

National Natural Science Foundation of China 91745107

More Information

Corresponding author: SUN Jian, E-mail: sunj@dicp.ac.cn
Received Date: 2018-11-13
Rev Recd Date: 2019-02-16

Available Online: 2021-01-23

Publish Date: 2019-04-10

Abstract

Abstract

A series of fused iron (FI) catalysts promoted with biomass ash were prepared by physical mixing method and characterized by X-ray diffraction, transmission electron microscopy and Mossbauer spectroscopy. The catalytic performance of CO₂ hydrogenation to higher hydrocarbons was evaluated in a fixed bed reactor. The results show that compared with the catalyst without biomass ash (B-ash), the fused iron catalysts promoted with biomass ash have smaller particle size and narrower size distribution, and the four phases of Fe₃O₄, Fe₅C₂, Fe₃C as well as α-Fe coexist in synergy. Thus, the tandem reaction of reverse water gas shift (RWGS) and C-C coupling proceed efficiently, and the selectivity of higher hydrocarbons is significantly improved while methane formation is effectively suppressed. Among the products, C_4-18 hydrocarbons are dominant. The C_4-18 hydrocarbons' selectivity in all hydrocarbons reaches 73.9% at the conditions of 300℃, 1.0 MPa, 4800 h^-1, H₂/CO₂=3.0 as well as the additive amount of the promoter is 5% (mass ratio).
- CO₂ hydrogenation,
- high hydrocarbons,
- Fe-based catalyst,
- biomass,
- synergism

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References(30)

References

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