Hydrodeoxygenation of bio-oil model compounds over amorphous NiB/SiO2-Al2O3 catalyst in oil-water biphasic system

LIU Lu-juan; LIU Yong-gang; GAO Xiang; ZHANG Rui-qin; ZHAI Yun-pu

Volume 45 Issue 8

Aug. 2017

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Article Navigation > Journal of Fuel Chemistry and Technology > 2017 > 45(8): 932-938

LIU Lu-juan, LIU Yong-gang, GAO Xiang, ZHANG Rui-qin, ZHAI Yun-pu. Hydrodeoxygenation of bio-oil model compounds over amorphous NiB/SiO2-Al2O3 catalyst in oil-water biphasic system[J]. Journal of Fuel Chemistry and Technology, 2017, 45(8): 932-938.

Citation:

LIU Lu-juan, LIU Yong-gang, GAO Xiang, ZHANG Rui-qin, ZHAI Yun-pu. Hydrodeoxygenation of bio-oil model compounds over amorphous NiB/SiO₂-Al₂O₃ catalyst in oil-water biphasic system[J]. Journal of Fuel Chemistry and Technology, 2017, 45(8): 932-938.

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Hydrodeoxygenation of bio-oil model compounds over amorphous NiB/SiO₂-Al₂O₃ catalyst in oil-water biphasic system

The College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China

Funds:

The project was supported by the International cooperation project of Henan province 172102410041

National Natural Science Foundation of China 21201153

Received Date: 2017-04-01
Rev Recd Date: 2017-06-07

Available Online: 2021-01-23

Publish Date: 2017-08-10

Abstract

Abstract

An amorphous NiB/SiO₂-Al₂O₃ catalyst was prepared and characterized by XRD, TEM, N₂ sorption and XPS. The catalytic performance of the prepared catalysts was evaluated in an oil-water bi-phase system using anisole and guaiacol as model compound of bio-oil. The results showed that Ni was in the electron-rich state with the modification of B, leading to the much higher hydrogenation activity of amorphous NiB/SiO₂-Al₂O₃ catalyst than that of Ni/SiO₂-Al₂O₃ catalyst. Increasing reaction temperature or prolonging reaction time was beneficial to the conversion of guaiacol and anisole. On the basis of the experimental results, the reaction pathway of guaiacol and anisole was analyzed, which provided a reference for the mechanism of bio oil hydrogenation.
- bio-oil,
- HDO,
- NiB,
- anisole,
- guaiacol

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References(20)

References

[1]	SAIDUR R, ABDLAZIZ E, DEMIRBAS A, HOSSAIN MS, MEKHILEF S. A review on biomass as a fuel for boilers[J]. Renew Sust Energ Rev, 2011, 25(5): 2262-2289. http://www.sciencedirect.com/science/article/pii/S1364032111000578
[2]	MORTENSEN PM, GRUNWALDT JD, JENSEN PA, KNUDSEN KG, JENSEN AD. A review of catalytic upgrading of bio-oil to engine fuels[J]. Appl Catal A, 2011, 407(1/2): 1-19. http://www.sciencedirect.com/science/article/pii/S0926860X11005138
[3]	ZHAO Zhen-yu, ZUO Jian, WU An-hao, ZILLANTE G. Competitiveness assessment of the biomass power generation industry in China: A five forces model study[J]. Renew energ, 2016, 89: 144-153. doi: 10.1016/j.renene.2015.12.035
[4]	CHENG Shou-yun, WEI Lin, ZHAO Xian-hui, JULSON J. Application, deactivation, and regeneration of heterogeneous catalysts in bio-oil upgrading[J]. Catal, 2016, 6: 12-18. doi: 10.3390/catal6010012
[5]	FANG Hui-huang, ZHENG Jian-wei, LUO Xiao-lin. Product tunable behavior of carbon nanotubes-supported Ni-Fe catalysts for guaiacol hydrodeoxygenation[J]. Appl Catal, A, 2016, 6(12):19-26. http://www.sciencedirect.com/science/article/pii/S0926860X16305038
[6]	HAO Chen, WU Yu-long, QI Sui-tao, YU Chen, YANG Ming. Deoxygenation of octanoic acid catalyzed by hollow spherical Ni/ZrO₂[J]. Appl Catal A, 2017, 529: 79-90. doi: 10.1016/j.apcata.2016.10.014
[7]	CROSSLEY S, FARIA J, SHEN M, RESASCO, DE. Solid nanoparticles that catalyze biofuel upgrade reactions at the water/oil interface[J]. Science, 2010, 327(5961): 68-72. doi: 10.1126/science.1180769
[8]	JIMARE MT, CAZANA F, RAMIREZ A, ROYO C, ROMEO E, FARIA J, RESASCO DE, MONZON A. Modelling of experimental vanillin hydrodeoxygenation reactions in water/oil emulsions. Effects of mass transport[J]. Catal Today, 2013, 210: 89-97. http://www.sciencedirect.com/science/article/pii/S0920586112008267
[9]	LI He-xing, ZHANG Si-yong, LUO Hong-shan. A Ce-promoted Ni-B amorphous alloy catalyst (Ni-Ce-B) for liquid-phase furfural hydrogenation to furfural alcohol[J]. Mater Lett, 2004, 58(22/23): 2741-2746.
[10]	ZHANG Qin-sheng, LI Hai-feng, GAO Ping, WANG Lai-lai. PVP‐NiB amorphous catalyst for selective hydrogenation of phenol and its derivatives[J]. Chin J Catal, 2014, 35: 1793-1799. doi: 10.1016/S1872-2067(14)60203-5
[11]	M LEWANDOWSKI. Hydrotreating activity of bulk NiB alloy in model reaction of hydrodenitrogenation of carbazole[J]. Appl Catal B, 2015, 168-169: 322-332. doi: 10.1016/j.apcatb.2014.12.043
[12]	XIU S, SHAHBAZI A. Bio-oil production and upgrading research: A review[J]. Renew Sust Energ Rev, 2012, 16(7): 4406-4414. doi: 10.1016/j.rser.2012.04.028
[13]	WILLIAMS PT, NUGRANAD N. Comparison of products from the pyrolysis and catalytic pyrolysis of rice husks[J]. Energy, 2000, 25: 493-513. doi: 10.1016/S0360-5442(00)00009-8
[14]	LI Hui, LI He-xing, DENG Jing-fa. Influence on the reduction degree of Ni-B/SiO₂ amorphous catalyst and its role in selective hydrogenation of acrylonitrile[J]. Appl Catal, A, 2000, 193(1/2): 9-15. http://www.sciencedirect.com/science/article/pii/S0926860X99004226
[15]	XIN Hui, GUO Kai, LI Dan. Production of high-grade diesel from palmitic acid over activated carbon-supported nickel phosphide catalysts[J]. Appl Catal B, 2016, 187: 375-385. doi: 10.1016/j.apcatb.2016.01.051
[16]	SHAO Jie, XIAO Xue-zhang, FAN Xiu-lin, CHEN Li-xin, ZHU Hong-yi, YU Si-qi, GONG Zhao-dong, LI-Shou-quan, GE Hong-wei, WANG Qi-dong. A low temperature mechanochemical synthesis and characterization of amorphous Ni-B ultra fine nanoparticles[J]. Mater Lett, 2013, 109: 203-206. doi: 10.1016/j.matlet.2013.07.076
[17]	LI Hui, LI He-xing, DENG Jing-fa. Glucose hydrogenation over NiB/SiO₂ amorphous alloy catalyst and the promoting effect of metal dopants[J]. Cata Today, 2002, 74: 53-63. doi: 10.1016/S0920-5861(01)00530-2
[18]	DENG Jing-Fa, LI Yong-jiang, SHENG S, XIONG Guo-xing. The study of ultrafine NiB and NiP amorphous alloy powders as catalysts[J]. J Cata, 1994, 150(2): 434-438. doi: 10.1006/jcat.1994.1362
[19]	LI He-xing, WU Yue-dong, LUO Hong-shan, WANG Ming-hui, XU Ye-ping. Liquid phase hydrogenation of acetonitrile to ethylamine over the Co-B amorphous alloy catalyst[J]. J Cata, 2003, 214(1): 15-25. doi: 10.1016/S0021-9517(02)00038-6
[20]	KAMINSKI P, ZIOLEK M. Surface and catalytic properties of Ce^-, Zr^-, Au^-, Cu^- modified SBA-15[J]. J Catal, 2014, 312: 249-262. doi: 10.1016/j.jcat.2014.02.005