Separating phenols from different fractions of bio-oil by precipitation of Ba<sup>2+</sup>

YUAN Xin-hua; TANG Guo-xu; ZHANG Li-qiang; ZHU Xi-feng

Volume 47 Issue 1

Jan. 2019

Turn off MathJax

Article Contents

Article Navigation > Journal of Fuel Chemistry and Technology > 2019 > 47(1): 53-59

YUAN Xin-hua, TANG Guo-xu, ZHANG Li-qiang, ZHU Xi-feng. Separating phenols from different fractions of bio-oil by precipitation of Ba2+[J]. Journal of Fuel Chemistry and Technology, 2019, 47(1): 53-59.

Citation:

YUAN Xin-hua, TANG Guo-xu, ZHANG Li-qiang, ZHU Xi-feng. Separating phenols from different fractions of bio-oil by precipitation of Ba²⁺[J]. Journal of Fuel Chemistry and Technology, 2019, 47(1): 53-59.

Citation:

PDF( 2094 KB)

Separating phenols from different fractions of bio-oil by precipitation of Ba²⁺

School of Engineering Science, University of Science and Technology of China, Hefei 230026, China

Funds:

the National Natural Science Foundation of China 51676179

More Information

Corresponding author: ZHU Xi-feng, E-mail:xfzhu@ustc.edu.cn
Received Date: 2018-10-11
Rev Recd Date: 2018-11-19

Available Online: 2021-01-23

Publish Date: 2019-01-10

Abstract

Abstract

The phenolic substances in the bio-oil fractions collected at different temperature intervals were extracted by barium ion precipitation method at different concentrations of NaOH reagent, reaction temperatures and reaction times, and the extraction effect was analyzed by GC-MS. The results show that the effect of barium ion precipitation on guaiacols separation is more outstanding. The temperature (30-50℃), concentration of NaOH (1.0-6.0 mol/L) and reaction time (10-40 min) have great influence on the extraction rate of guaiacols. The optimum reaction parameters include the NaOH solution of 5.5 mol/L, the temperature of 35℃ and the reaction time of 20 min. Under the optimum condition, the extraction rate of guaiacols in the three fractions of low temperature water, low temperature oil and high temperature are 34.1%, 33.8% and 33.5%, respectively.
- bio-oil,
- bio-oil fraction,
- phenol,
- barium ion precipitation method,
- recycling

FullText(HTML)

References(19)

References

[1]	ŽILNIK L F, JAZBINŠEK A. Recovery of renewable phenolic fraction from pyrolysis oil[J]. Sep Purif Technol, 2012, 86(8):157-170. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=4e26ff3fcaa0d1a7b1ad371c2aaca00d
[2]	QIANG L, LI W Z, ZHU X F. Overview of fuel properties of biomass fast pyrolysis oils[J].Energy Convers Manage, 2009, 50(5):1376-1383. doi: 10.1016/j.enconman.2009.01.001
[3]	XIU S, SHAHBAZI A. Bio-oil production and upgrading research:A review[J]. Renewable Sustainable Energy Rev, 2012, 16(7):4406-4414. doi: 10.1016/j.rser.2012.04.028
[4]	邹勇, 尉芹, 郑冀鲁, 李宏伟, 马希汉.生物油中酚类物质的富集工艺优化研究[J].西北林学院学报, 2016, 31(1):226-230. doi: 10.3969/j.issn.1001-7461.2016.01.39 ZOU Yong, WEI Qin, ZHENG Ji-lu, LI Hong-wei, MA Xi-han. Optimization of the technology of enriching phenolic components from bio-oil[J]. J NW For Univ, 2016, 31(1):226-230. doi: 10.3969/j.issn.1001-7461.2016.01.39
[5]	赵欣, 李凯, 李明, 马善为, 朱锡锋.沉淀法回收生物油高温馏分中的酚类物质[J].燃料化学学报, 2016, 44(2):201-208. doi: 10.3969/j.issn.0253-2409.2016.02.010 ZHAO Xin, LI Kai, LI Ming, MA Shan-wei, ZHU Xi-feng.Separating phenols from high-temperature fraction of bio-oil by precipitation[J]. J Fuel Chem Technol, 2016, 44(2):201-208. doi: 10.3969/j.issn.0253-2409.2016.02.010
[6]	吕东灿, 刘运权, 王夺, 叶跃元.生物油的分离及其产品应用[J].林产化学与工业, 2013, 33(4):137-143. doi: 10.3969/j.issn.0253-2417.2013.04.026 LU Dong-can, LIU Yun-quan, WANG Duo, YE Yue-yuan.Separation of chemicals from bio-oil and their application prospects[J].Chem Ind For Prod, 2013, 33(4):137-143. doi: 10.3969/j.issn.0253-2417.2013.04.026
[7]	KANG S, LI X, FAN J. Classified separation of lignin hydrothermal liquefied products[J]. Ind Eng Chem Res, 2011, 50(19):11288-11296. doi: 10.1021/ie2011356
[8]	KIM J S. Production, separation and applications of phenolic-rich bio-oil-A review.[J]. Bioresource Technol, 2015, 178:90-98. doi: 10.1016/j.biortech.2014.08.121
[9]	REVERCHON E, MARCO I D. Supercritical fluid extraction and fractionation of natural matter[J]. J Supercrit Fluid, 2006, 38(2):146-166. doi: 10.1016/j.supflu.2006.03.020
[10]	AMEN-CHEN C, PAKDEL H, ROY C. Separation of phenols from eucalyptus, wood tar[J]. Biomass Bioenergy, 1997, 13(1):25-37. doi: 10.1016-j.jtcvs.2009.06.017/
[11]	LI J H, CHAO W, YANG Z Y. Production and separation of phenols from biomass-derived bio-petroleum.[J]. J Anal Appl Pyrolysis, 2010, 89(2):218-224. doi: 10.1016/j.jaap.2010.08.004
[12]	WANG D, LI D, LIU Y. Study of a new complex method for extraction of phenolic compounds from bio-oils[J]. Sep Purif Technol, 2014, 134(5):132-138. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=fc8188145ffd8c0321547e71414b65ed
[13]	FU D, FARAG S, CHAOUKI J. Extraction of phenols from lignin microwave-pyrolysis oil using a switchable hydrophilicity solvent[J]. Bioresource Technol, 2014, 154(2):101-108. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=156bafac8f83eedef5d70d6642384ad2
[14]	葛宜掌, 金红, 李斌. Ba~(2+)离子沉淀法回收酚类化学过程的研究[J].燃料化学学报, 1996, 24(3):266-270. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199600430536 GE Yi-zhang, JIN Hong, LI Bin. Study on the chemical process of recovering phenols by Ba~(2+) ion precipitation[J].J Fuel Chem Technol, 1996, 24(3):266-270. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=QK199600430536
[15]	杨续来, 陆强, 朱锡锋.生物油的蒸馏特性及其应用[C].中国生物质能科学技术论坛, 2007. http://www.wanfangdata.com.cn/details/detail.do?_type=conference&id=6589754 YANG Xu-lai, LU Qiang, ZHU Xi-feng.Distillation characteristics and applications of biological oils[C]. Forum Biomass Energy Science and Technology in China, 2007. http://www.wanfangdata.com.cn/details/detail.do?_type=conference&id=6589754
[16]	GE Y, JIN H. Recovery process for phenolic compounds from coal-derived oils by ions of soluble metal salts[J]. Fuel, 1996, 75(14):1681-1683. doi: 10.1016/0016-2361(95)00276-6
[17]	GROENEWOLD G S, JOHNSON K M, FOX S C. Pyrolysis two-dimensional GC-MS of miscanthus biomass:Quantitative measurement using an internal standard method[J]. Energy Fuels, 2017, 31(2):1620-1630. doi: 10.1021/acs.energyfuels.6b02645
[18]	LEE J, CHO S, RODRIGUEZ J P. Determination of fatty acids from perilla cultivars and edible oils by GC-FID[J]. Planta Med, 2016, 81(S 01):S1-S381. http://www.ncbi.nlm.nih.gov/pubmed/27976251
[19]	明珠, 吴云海, 阿依妮尕尔·艾尔肯.茶汤与金属离子络合反应的研究[J].环境科技, 2015, (4):5-11. doi: 10.3969/j.issn.1674-4829.2015.04.002 MING Zhu, WU Yun-hai, ARKEN Ayinigar.Study on complexation reaction of tea infusion with metal ions[J]. Environ Sci Technol, 2015, (4):5-11. doi: 10.3969/j.issn.1674-4829.2015.04.002