CO<sub>2</sub> adsorption and separation on phloroglucinol-melamine -formaldehyde polymeric nanofibers

ZHOU Zhi-hui; JIN Can; ZHANG Hao-yi; LIANG Xiao-lei; ZHANG Fu-min; XIAO Qiang

Volume 47 Issue 2

Feb. 2019

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Article Navigation > Journal of Fuel Chemistry and Technology > 2019 > 47(2): 242-248

ZHOU Zhi-hui, JIN Can, ZHANG Hao-yi, LIANG Xiao-lei, ZHANG Fu-min, XIAO Qiang. CO2 adsorption and separation on phloroglucinol-melamine -formaldehyde polymeric nanofibers[J]. Journal of Fuel Chemistry and Technology, 2019, 47(2): 242-248.

Citation:

ZHOU Zhi-hui, JIN Can, ZHANG Hao-yi, LIANG Xiao-lei, ZHANG Fu-min, XIAO Qiang. CO₂ adsorption and separation on phloroglucinol-melamine -formaldehyde polymeric nanofibers[J]. Journal of Fuel Chemistry and Technology, 2019, 47(2): 242-248.

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CO₂ adsorption and separation on phloroglucinol-melamine -formaldehyde polymeric nanofibers

Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Zhejiang Normal University, Jinhua 321004, China

Funds:

the National Natural Science Foundation of China 21471131

College Students Technology Innovation Plan of Zhejiang Province(XinMiao Talent Plan) 2017R404017

More Information

Corresponding author: XIAO Qiang, E-mail: xiaoq@zjnu.cn
Received Date: 2018-09-18
Rev Recd Date: 2018-11-28

Available Online: 2021-01-23

Publish Date: 2019-02-10

Abstract

Abstract

Phloroglucinol-melamine-formaldehyde polymeric nanofibers (PMF) were hydrothermally synthesized by a polycondensation method using melamine, phloroglucinol and formaldehyde as starting materials. The effect of temperature on the PMF synthesis was investigated. The morphology and structure of the as-synthesized PMF were characterized by the scanning electron microscope (SEM), transmission electron microscope (TEM), N₂ adsorption-desorption and Fourier-transform infrared spectrometer (FT-IR) etc. Pure gas adsorption equilibrium isotherms of CO₂ and N₂ were determined by the volumetric method. The PMF sample synthesized at 393 K presented a higher specific surface area (64 m²/g) and a higher adsorption capacity of CO₂ (1.83 mmol/g@118 kPa, 298 K). Breakthrough column experiments indicated that efficient separation of CO₂-N₂ mixtures could be achieved on the PMF at 298 K and various pressures ranging from 200 to 600 kPa. After the PMF was thermally treated at 873 K in various atmospheres such as N₂, H₂, water vapor, etc., it was found that the specific surface area and micropore volume were greatly increased. Among the posttreated PMF samples, the one treated in 15% H₂O stream showed an improved CO₂ adsorption amount up to 2.83 mmol/g at 298 K and 118 kPa.
- melamine,
- nanofiber,
- CO₂ adsorption,
- breakthrough column,
- nitrogen-rich carbon nanofiber

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References(29)

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