Effect of preparation method on the structure and properties of coal tar model compound cracking catalyst Ni/Al<sub>2</sub>O<sub>3</sub>

ZHAI Jian-rong; ZHANG Yan-min; MO Wen-long; LI Xian; ZHONG Mei; MA Feng-yun

Volume 46 Issue 9

Sep. 2018

Turn off MathJax

Article Contents

Article Navigation > Journal of Fuel Chemistry and Technology > 2018 > 46(9): 1063-1073

ZHAI Jian-rong, ZHANG Yan-min, MO Wen-long, LI Xian, ZHONG Mei, MA Feng-yun. Effect of preparation method on the structure and properties of coal tar model compound cracking catalyst Ni/Al2O3[J]. Journal of Fuel Chemistry and Technology, 2018, 46(9): 1063-1073.

Citation:

ZHAI Jian-rong, ZHANG Yan-min, MO Wen-long, LI Xian, ZHONG Mei, MA Feng-yun. Effect of preparation method on the structure and properties of coal tar model compound cracking catalyst Ni/Al₂O₃[J]. Journal of Fuel Chemistry and Technology, 2018, 46(9): 1063-1073.

Citation:

ZHAI Jian-rong, ZHANG Yan-min, MO Wen-long, LI Xian, ZHONG Mei, MA Feng-yun. Effect of preparation method on the structure and properties of coal tar model compound cracking catalyst Ni/Al₂O₃[J]. Journal of Fuel Chemistry and Technology, 2018, 46(9): 1063-1073.

PDF( 1831 KB)

Effect of preparation method on the structure and properties of coal tar model compound cracking catalyst Ni/Al₂O₃

ZHAI Jian-rong¹,
ZHANG Yan-min¹,
MO Wen-long¹,
LI Xian^{1, 2},
ZHONG Mei^{1
,
,},
MA Feng-yun^{1
,
,}

1.
Key Laboratory of Coal Clean Conversion & Chemical Engineering Process(Xinjiang Uyghur Autonomous Region), College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China
2.
State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China

Funds:

the Key Laboratory of Xinjiang Uygur Autonomous Region 2016D03009

National Natural Science Foundation of China 21606187

National Key Research and Development Program 2016YFF0102602

Youth Science and technology innovation personnel training project in Xinjiang Uygur Autonomous Region QN2016BS0152

More Information

Corresponding author: ZHONG Mei, E-mail:zhongmei0504@126.com; MA Feng-yun, E-mail:ma_fy@126.com
Received Date: 2018-03-05
Rev Recd Date: 2018-07-03

Available Online: 2021-01-23

Publish Date: 2018-09-10

Abstract

Abstract

Cat-1, Cat-2, Cat-3 and Cat-4 catalysts were synthesized via different preparation methods that are incipient wetness, impregnation-precipitation and mechanochemical method (carriers from market and homemade for comparison), and then characterized by BET, H₂-TPR, XRD, XPS and NH₃-TPD. The cracking behavior of toluene and pyrene (3%, mass fraction) (coal tar model compounds) were investigated to evaluate the catalytic performance of the stated catalysts. The catalyst characterization showed that the pore size of all the catalysts belonged to mesoporous range, and Cat-4 catalyst exhibited higher ordered mesoporous and larger surface area than others, up to 235 m²/g. Besides, the peak area of NiAl₂O₄ spinel reached up to the highest value of 85.2%. The dispersion of Ni in the reduced Cat-4 was the highest and its particle size was the lowest value, about 10.0 nm. Which means that there are more active sites. The catalytic performance results showed that the cracking rate of pyrene varied little for other catalysts, except for Cat-1, but the lowest carbon deposition of 10.84% was obtained under the action of Cat-4, while the carbon deposition of Cat-1, Cat-2 and Cat-3 increased by 35.0%, 74.7% and 45.7% respectively compared with that of Cat-4. Thus, Cat-4 prepared by mechanochemical method is more suitable for the cracking of toluene and pyrene system because of highest BET surface area, which is favorable for the dispersion of active component, and at the same time, the highest content of NiAl₂O₄ can inhibit the formation of carbon.
- preparation method,
- Ni/Al₂O₃ catalyst,
- model compound,
- cracking performance

FullText(HTML)

References(38)

References

[1]	KAN T, WANG H Y, HE H X, LI C S, ZHANG S J. Experimental study on two-stage catalytic hydroprocessing of middle-temperature coal tar to clean liquid fuels[J]. Fuel, 2011, 90(11):3404-3409. doi: 10.1016/j.fuel.2011.06.012
[2]	高晋生.煤的热解、炼焦和煤焦油加工[M].北京:化学工业出版社, 2010. GAO Jin-sheng. The Coal Pyrolysis, Coke and Coal Tar Processing[M]. Beijing:Chemical Industry Press, 2010.
[3]	王向辉, 门卓武, 许明, 翁丽, 刘科.低阶煤粉煤热解提质技术研究现状及发展建议[J].洁净煤技术, 2014, 20(6):36-41. http://d.old.wanfangdata.com.cn/Periodical/jjmjs201406010 WANG Xiang-hui, MEN Zhuo-wu, XU Ming, WENG Li, LIU Ke. Research status and development proposals on pyrolysis techniques of low rank pulverized coal[J]. Clean Coal Technol, 2014, 20(6):36-41. http://d.old.wanfangdata.com.cn/Periodical/jjmjs201406010
[4]	侯斌, 吕子安, 李晓辉, 李定凯.生物质热解产物中焦油的催化裂解[J].燃料化学学报, 2001, 29(1):70-75. doi: 10.3969/j.issn.0253-2409.2001.01.014 HOU Bin, LÜ Zi-an, LI Xiao-hui, LI Ding-kai. Catalytic cracking of tar derived from biomass pyrolysis[J]. J Fuel Chem Technol, 2001, 29(1):70-75. doi: 10.3969/j.issn.0253-2409.2001.01.014
[5]	杨修春, 韦亚南, 李伟捷.焦油裂解用催化剂的研究进展[J].化工进展, 2007, 26(3):326-330. doi: 10.3321/j.issn:1000-6613.2007.03.006 YANG Xiu-chun, Wei Ya-nan, LI Wei-jie. Research progress of catalysts for tar cracking[J]. Chem Ind Eng Progress, 2007, 26(3):326-330. doi: 10.3321/j.issn:1000-6613.2007.03.006
[6]	余长林, 胡久彪, 杨凯, 周晓春.制备方法对Ni/CeO₂-Al₂O₃催化剂甲烷部分氧化催化性能的影响[J].燃料化学学报, 2013, 41(6):722-728. doi: 10.3969/j.issn.0253-2409.2013.06.013 YU Chang-lin, HU Jiu-biao, YANG Kai, ZHOU Xiao-chun. Effects of preparation methods on the catalytic performance of Ni/CeO₂-Al₂O₃ catalyst in methane partial oxidation[J]. J Fuel Chem Technol, 2013, 41(6):722-728. doi: 10.3969/j.issn.0253-2409.2013.06.013
[7]	徐军科, 任克威, 周伟, 王晓蕾, 李兆静, 潘相敏, 马建新.制备方法对甲烷干重整催化剂Ni/La₂O₃/Al₂O₃结构及性能的影响[J].燃料化学学报, 2009, 37(4):473-479. doi: 10.3969/j.issn.0253-2409.2009.04.017 XU Jun-ke, REN Ke-wei, ZHOU Wei, WANG Xiao-lei, LI Zhao-jing, PAN Xiang-min, MA Jian-xin. Influence of preparation method on the properties and catalytic performance of Ni/La₂O₃/Al₂O₃ catalyst for dry reforming of methane[J]. J Fuel Chem Technol, 2009, 37(4):473-479. doi: 10.3969/j.issn.0253-2409.2009.04.017
[8]	罗来涛, 黄红冈.镍基海泡石催化剂制备方法与表面性质的研究[J].工业催化, 2000, 8(3):60-64. doi: 10.3969/j.issn.1008-1143.2000.03.012 LUO Lai-tao, HUANG Hong-gang. Study on preparation and surface behavior of nickel sepiolite catalyst[J]. Ind Catal, 2000, 8(3):60-64. doi: 10.3969/j.issn.1008-1143.2000.03.012
[9]	柴永明, 相春娥, 孔会清, 柳云骐, 刘晨光.馏分油浆态床加氢处理研究Ⅰ催化剂制备方法[J].燃料化学学报, 2008, 36(6):720-725. doi: 10.3969/j.issn.0253-2409.2008.06.014 CHAI Yong-ming, XIANG Chun-e, KONG Hui-qing, LIU Yun-qi, LIU Chen-guang. A study on slurry-bed hydrotreating process of distillate oil:ⅠCatalyst preparation[J]. J Fuel Chem Technol, 2008, 36(6):720-725. doi: 10.3969/j.issn.0253-2409.2008.06.014
[10]	王广建, 邴连成, 郭娜娜, 杨志坚, 张健康.浸渍沉淀法制备活性炭负载Co-Mo双金属脱硫催化剂[J].燃料化学学报, 2012, 40(10):1252-1257. doi: 10.3969/j.issn.0253-2409.2012.10.015 WANG Guang-jian, BING Lian-cheng, GUO Na-na, YANG Zhi-jian, ZHANG Jian-kang. Preparation of activated carbon-supported Co-Mo bimetallic catalyst by impregnation-precipitation method[J]. J Fuel Chem Technol, 2012, 40(10):1252-1257. doi: 10.3969/j.issn.0253-2409.2012.10.015
[11]	AMIN M N, LI Y, RAZZAQ R, LU X M, LI C S, ZHANG S J. Pyrolysis of low rank coal by nickel based zeolite catalysts in the two-staged bed reactor[J]. J Anal Appl Pyrolysis, 2016, 118(MAR):54-62. http://cn.bing.com/academic/profile?id=5d3ec09d9c1ab1a40dd4c9144039e9e1&encoded=0&v=paper_preview&mkt=zh-cn
[12]	HAN J Z, LIU X X, YUE J R, XI B F, GAO S Q, XU G W. Catalytic upgrading of in situ coal pyrolysis tar over Ni-Char catalyst with different additives[J]. Energy Fuels, 2014, 28(8):4934-4941. doi: 10.1021/ef500927d
[13]	HU F X, YANG G H, DING G Z, LI Z, DU K S, HU Z F, TIAN S R. Experimental study on catalytic cracking of model tar compounds in a dual layer granular bed filter[J]. Appl Energy, 2016, 170:47-57. doi: 10.1016/j.apenergy.2016.02.080
[14]	邹梦, 马凤云, 莫文龙, 孔令涛, 刘景梅, 钟梅, 肖艳.机械化学法制备甲烷化Ni/Al₂O₃催化剂性能研究[J].应用化工, 2017, 46(12):2314-2319. doi: 10.3969/j.issn.1671-3206.2017.12.008 ZOU Meng, MA Feng-yun, MO Wen-long, KONG Ling-tao, LIU Jing-mei, ZHONG Mei, XIAO Yan. Mechanochemical prepared Ni/Al₂O₃ catalysts and their catalytic performance for methanation[J]. Appl Chem Ind, 2017, 46(12):2314-2319. doi: 10.3969/j.issn.1671-3206.2017.12.008
[15]	张艳敏, 邹达, 赵渊, 钟梅, 马凤云.双金属催化剂对煤焦油模型化合物催化裂解行为的影响[J].化工学报, 2017, 68(10):3805-3815. http://d.old.wanfangdata.com.cn/Periodical/hgxb201710018 ZHANG Yan-min, ZOU Da, ZHAO Yuan, ZHONG Mei, MA Feng-yun. Effect of bimetallic catalysts on cracking behavior of coal tar model compounds[J]. CIESC J, 2017, 68(10):3805-3815. http://d.old.wanfangdata.com.cn/Periodical/hgxb201710018
[16]	CAO T T, SONG Z G, WANG S B, CAO X X, LI Y, XIA J. Characterizing the pore structure in the silurian and permian shales of the sichuan basin, China[J]. Mar Petrol Geol, 2015, 61:140-150. doi: 10.1016/j.marpetgeo.2014.12.007
[17]	杨华明, 欧阳静, 张科, 史蓉蓉, 张向超.机械化学合成纳米材料的研究进展[J].化工进展, 2005, 24(3):239-244. doi: 10.3321/j.issn:1000-6613.2005.03.004 YANG Hua-ming, OUYANG Jin, ZHANG Ke, SHI Rong-rong, ZHANG Xiang-chao. Research progress of mechano-chemical preparation of nanomaterials[J]. Chem Ind Eng Progress, 2005, 24(3):239-244. doi: 10.3321/j.issn:1000-6613.2005.03.004
[18]	杨圣品, 施雨湘.高能球磨法制备金属微粉的研究[J].焊接技术, 2002, 31(3):43-44. doi: 10.3969/j.issn.1002-025X.2002.03.021 YANG Sheng-pin, SHI Yu-xiang. Research of metal powder preparation by high energy ball milling[J]. Welding Technol, 2002, 31(3):43-44. doi: 10.3969/j.issn.1002-025X.2002.03.021
[19]	GROEN J C, PEFFER L A A, PEREZ-RAMIREZ J. Pore size determination in modified micro-and mesoporous materials. Pitfalls and limitations in gas adsorption data analysis[J]. Microporous Mesoporous Mater, 2003, 60(1/3):1-17. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=JJ0213448779
[20]	SING K S W. Reporting physisorption data for gas/solid systems-with special reference to the determination of surface area and porosity[J]. Pure Appl Chem, 1985, 57(4):603-619. doi: 10.1351/pac198557040603
[21]	ZHANG J, XU H Y, JIN X L, GE Q J, LI W Z. Characterizations and activities of the nano-sized Ni/Al₂O₃ and Ni/La-Al₂O₃catalysts for NH₃ decomposition[J]. Appl Catal A:Gen, 2005, 290(1/2):87-96. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=JJ024426858
[22]	BOUKHA Z, JIMENEZ-GONZALEZ C, RIVAS B D, GONZALEZ-VELASCO J R, GUTIERREZ-ORTIZ J I, LOPEZ-FONSECA R. Synthesis, characterisation and performance evaluation of spinel-derived Ni/Al₂O₃ catalysts for various methane reforming reactions[J]. Appl Catal B:Environ, 2014, 158/159(1):190-201. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=JJ0232793414
[23]	HU D C, GAO J J, PING Y, JIA L H, GUNAWAN P, ZHONG Z Y, XU G W, GU F N, SU F B. Enhanced investigation of CO methanation over Ni/Al₂O₃ catalysts for synthetic natural gas production[J]. Ind Eng Chem Res, 2012, 51(13):4875-4886. doi: 10.1021/ie300049f
[24]	SUN N N, WEN X, WANG F, PENG W C, XIAO F K, WEI W, SUN Y H. Influence of Ni content on catalytic performance of Ni-CaOZrO₂ catalysts in CH₄-CO₂ reforming[J]. Fine Chem, 2010, 27(10):1004-1008.
[25]	莫文龙, 马凤云, 刘月娥, 刘景梅, 钟梅, 艾沙·努拉洪.溶液燃烧法制备Ni-Al₂O₃催化剂用于CO₂-CH₄重整研究[J].无机材料学报, 2016, 31(5):485-491. http://d.old.wanfangdata.com.cn/Periodical/wjclxb201605007 MO Wen-long, MA Feng-yun, LIU Yue-e, LIU Jing-mei, ZHONG Mei, AISHA·nulahong. Preparation of Ni-Al₂O₃ catalysts by solution combustion method for CO₂ reforming of CH₄[J]. J Inorg Mater, 2016, 31(5):485-491. http://d.old.wanfangdata.com.cn/Periodical/wjclxb201605007
[26]	ZHANG J F, BAI Y X, ZHANG Q D, WANG X X, ZHANG T, TIAN Y S, HAN Y Z. Low-temperature methanation of syngas in slurry phase over Zr-doped Ni/γ-Al₂O₃ catalysts prepared using different methods[J]. Fuel, 2014, 132(15):211-218.
[27]	CZEKAJ I, LOVIAT F, RAIMONDI F, WAMBACH J, BIOLLAZ S, WOKAUN A. Characterization of surface processes at the Ni-based catalyst during the methanation of biomass-derived synthesis gas:X-ray photoelectron spectroscopy (XPS)[J]. Appl Catal A:Gen, 2007, 329(10):68-78. http://cn.bing.com/academic/profile?id=c5edfa5a6841bfa104c17fdc4073d836&encoded=0&v=paper_preview&mkt=zh-cn
[28]	SALLEH N F M, JALIL A A, TRIWAHYONO S, EFENDI J, MUKTI R R, HAMEED B H. New insight into electrochemical-induced synthesis of NiAl₂O₄/Al₂O₃:Synergistic effect of surface hydroxyl groups and magnetism for enhanced adsorptivity of Pd(Ⅱ)[J]. Appl Surf Sci, 2015, 349(15):485-495.
[29]	HERACLEOUS E, LEE A F, WILSON K, LEMONIDOU A A. Investigation of Ni-based alumina-supported catalysts for the oxidative dehydrogenation of ethane to ethylene:Structural characterization and reactivity studies[J]. J Catal, 2005, 231(1):159-171. doi: 10.1016/j.jcat.2005.01.015
[30]	宫立倩, 陈吉祥, 邱业君, 张继炎.焙烧温度对甲烷催化部分氧化Ni/MgO-Al₂O₃催化剂结构和性能的影响[J].燃料化学学报, 2005, 33(2):224-228. doi: 10.3969/j.issn.0253-2409.2005.02.019 GONG Li-qian CHEN Ji-xiang QIU Ye-jun ZHANG Ji-yan. Effects of calcinations temperature on structure and catalytic performance of Ni/MgO-Al₂O₃ catalysts for partial oxidation of methane[J]. J Fuel Chem Technol, 2005, 33(2):224-228. doi: 10.3969/j.issn.0253-2409.2005.02.019
[31]	CHEN Y G, REN J. Conversion of methane and carbon dioxide into synthesis gas over alumina-supported nickel catalysts. Effect of Ni-Al₂O₃, interactions[J]. Catal Lett, 1994, 29(1/2):39-48.
[32]	BHATTACHARYYA A, CHANG V W. CO₂ reforming of methane to syngas:Deactivation behavior of nickel aluminate spinel catalysts[J]. Stud Surface Sci Catal, 1994, 88:207-213. doi: 10.1016/S0167-2991(08)62742-1
[33]	MO W L, MA F Y, LIU Y E, LIU J M, ZHONG M, AISHA·N L H. Preparation of porous Al₂O₃ by template method and its application in Ni-based catalyst for CH₄/CO₂ reforming to produce syngas[J]. Int J Hydrogen Energy, 2015, 40(46):16147-16158. doi: 10.1016/j.ijhydene.2015.09.149
[34]	GUO J J, LOU H, ZHENG X M. The deposition of coke from methane on a Ni/MgAl₂O₄ catalyst[J]. Carbon, 2007, 45(6):1314-1321. doi: 10.1016/j.carbon.2007.01.011
[35]	XU J K, ZHOU W, WANG J H, LI Z J, MA J X. Characterization and analysis of carbon deposited during the dry reforming of methane over Ni/La₂O₃/Al₂O₃ Catalysts[J]. Chin J Catal, 2009, 30(11):1076-1084. doi: 10.1016/S1872-2067(08)60139-4
[36]	FRUSTERI F, SPADARO L, ARENA F, CHUVILIN A. TEM evidence for factors affecting the genesis of carbon species on bare and K-promoted Ni/MgO catalysts during the dry reforming of methane[J]. Carbon, 2002, 40(7):1063-1070. doi: 10.1016/S0008-6223(01)00243-3
[37]	张兆斌, 余长春, 沈师孔.甲烷部分氧化制合成气的La₂O₃助Ni/MgAl₂O₄催化剂[J].催化学报, 2000, 21(1):14-18. doi: 10.3321/j.issn:0253-9837.2000.01.006 ZHANG Zhao-bin, YU Chang-chun, SHEN Shi-kong. Partial oxidation of CH₄ to syngas on La₂O₃-promoted Ni/MgAl₂O₄[J]. Chin J Catal, 2000, 21(1):14-18. doi: 10.3321/j.issn:0253-9837.2000.01.006
[38]	杨帆, 周志杰, 王辅臣, 刘海峰, 龚欣, 于遵宏.氢气存在下的煤焦水蒸气气化:Ⅰ反应特性研究[J].燃料化学学报, 2009, 37(1):36-41. doi: 10.3969/j.issn.0253-2409.2009.01.007 YANG Fan, ZHOU Zhi-jie, WANG Fu-chen, LIU Hai-feng, GONG Xin, YU Zun-hong. Coal char gasification with steam and H₂:I The gasification reaction characteristics[J]. J Fuel Chem Technol, 2009, 37(1):36-41. doi: 10.3969/j.issn.0253-2409.2009.01.007