Preparation and properties of dibenzothiophene molecularly imprinted functionalized MOF199 adsorbent

CHEN Ying; ZHANG Qi; LIANG Hong-bao; TIAN Gong-wei; LI Jing

Volume 46 Issue 9

Sep. 2018

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Article Navigation > Journal of Fuel Chemistry and Technology > 2018 > 46(9): 1130-1136

CHEN Ying, ZHANG Qi, LIANG Hong-bao, TIAN Gong-wei, LI Jing. Preparation and properties of dibenzothiophene molecularly imprinted functionalized MOF199 adsorbent[J]. Journal of Fuel Chemistry and Technology, 2018, 46(9): 1130-1136.

Citation:

CHEN Ying, ZHANG Qi, LIANG Hong-bao, TIAN Gong-wei, LI Jing. Preparation and properties of dibenzothiophene molecularly imprinted functionalized MOF199 adsorbent[J]. Journal of Fuel Chemistry and Technology, 2018, 46(9): 1130-1136.

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Preparation and properties of dibenzothiophene molecularly imprinted functionalized MOF199 adsorbent

Provincial Key Laboratory of Oil and Gas Chemical Technology, College of Chemistry and Chemical Engineering, Northeast Petroleum University, Daqing 163318, China

Funds:

the National Natural Science Foundation of China 21463006

More Information

Corresponding author: CHEN Ying, Tel：0459-6503786, E-mail: chenying648617@163.com
Received Date: 2018-05-04
Rev Recd Date: 2018-07-13

Available Online: 2021-01-23

Publish Date: 2018-09-10

Abstract

Abstract

Combined with molecular imprinting technology, a novel surface molecularly imprinted polymer material MOF@SMIP was prepared, using MOF199 used as matrix, dibenzothiophene (DBT) as template molecule and methacrylic acid (MAA) as functional monomer. The structure and morphology were characterized by SEM, BET, FT-IR, etc. The adsorption behavior was evaluated using a simulated oil sample. The adsorption equilibrium time was 1.5 h. The MOF@SMIP adsorption capacity for DBT (130.73 mg/g) was higher than that for the MOF199 (37.79 mg/g), while the MOF@SMIP adsorption capacity (57.13 mg/g) was comparable to the MOF@NIP adsorption capacity. The obvious advantage is that the imprint factor f_imp is 2.29. Adsorption behavior follows the pseudo-first-order kinetic model, indicating that the adsorption is primarily a physical process. The selective adsorption experiments showed that the MOF@SMIP exhibited a higher affinity for the target molecule DBT than the structural analog benzothiophene (BT) and biphenyl. The relative selection coefficient k' of the adsorbed DBT to the interferent BT and biphenyl was 2.55 and 2.14, respectively.
- MOFs,
- molecular imprinting,
- dibenzothiophene,
- functional monomer

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References(31)

References

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