Effect of Nd-incorporation and K-modification on catalytic performance of Co3O4 for N2O decomposition

ZHAO Tian-qi; GAO Qiang; LIAO Wei-ping; XU Xiu-feng

Volume 47 Issue 9

Sep. 2019

Turn off MathJax

Article Contents

Article Navigation > Journal of Fuel Chemistry and Technology > 2019 > 47(9): 1120-1128

ZHAO Tian-qi, GAO Qiang, LIAO Wei-ping, XU Xiu-feng. Effect of Nd-incorporation and K-modification on catalytic performance of Co3O4 for N2O decomposition[J]. Journal of Fuel Chemistry and Technology, 2019, 47(9): 1120-1128.

Citation:

ZHAO Tian-qi, GAO Qiang, LIAO Wei-ping, XU Xiu-feng. Effect of Nd-incorporation and K-modification on catalytic performance of Co₃O₄ for N₂O decomposition[J]. Journal of Fuel Chemistry and Technology, 2019, 47(9): 1120-1128.

Citation:

PDF( 4659 KB)

Effect of Nd-incorporation and K-modification on catalytic performance of Co₃O₄ for N₂O decomposition

School of Chemistry and Chemical Engineering, Yantai University, Yantai 264005, China

Funds:

the Shandong Natural Science Foundation ZR2017MB020

Graduate Innovation Foundation of Yantai University YDYB1909

More Information

Corresponding author: XU Xiu-feng, E-mail: xxf@ytu.edu.cn
Received Date: 2019-05-06
Rev Recd Date: 2019-07-10

Available Online: 2021-01-23

Publish Date: 2019-09-10

Abstract

Abstract

Nd-Co₃O₄ catalysts were prepared by hydrothermal and co-precipitation methods to catalyze the decomposition of N₂O. The catalysts prepared by hydrothermal method showed higher activity. Among the hydrothermal Nd-Co₃O₄ catalysts, the catalyst with Nd/Co molar ratio of 0.01 had higher activity. 0.01Nd-Co₃O₄ catalyst was then impregnated by K₂CO₃ solution to prepare K-modified catalyst. The catalysts were characterized by means of X-ray diffraction (XRD), nitrogen physisorption, scanning electrons microscopy (SEM), X-ray photoelectron spectroscopy (XPS), hydrogen temperature-programmed reduction (H₂-TPR), and oxygen temperature-programmed desorption (O₂-TPD). The results show that Nd-Co₃O₄ and K-modified catalysts exhibit spinel structure. In contrast to bare Nd-Co₃O₄, the K-modified catalyst with higher activity is due to its weaker strength of Co-O bond and easier desorption of surface oxygen species. In addition, over 90% conversion of N₂O can be reached over 0.02K/0.01Nd-Co₃O₄ at 350 ℃ for 40 h under the co-presence of oxygen and steam in feed gases.
- catalytic decomposition of N₂O,
- Nd-Co₃O₄ catalysts,
- K-modified catalysts,
- catalytic activity

FullText(HTML)

References(25)

References

[1]	REILLY J, PRINN R, HARNISCH J, FITZMAURICE J, JACOBY H, KICKLIGHTER D, MELILLO J, STONE P, SOKOLOV A, WANG C. Multi-gas assessment of the Kyoto Protocol[J]. Nature, 1999, 401:549-555. doi: 10.1038/44069
[2]	SHEN Q, LI L D, LI J J, TIAN H, HAO Z P. A study on N₂O catalytic decomposition over Co/MgO catalysts[J]. J Hazard Mater, 2009, 163:1332-1337. doi: 10.1016/j.jhazmat.2008.07.104
[3]	YAN L, REN T, WANG X L, JI D, SUO J S. Catalytic decomposition of N₂O over M_xCo_1-xCo₂O₄(M=Ni, Mg) spinel oxides[J]. Appl Catal B:Environ, 2003, 45(2):85-90. doi: 10.1016/S0926-3373(03)00174-7
[4]	IVANOVA Y A, SUTORMINA E F, ISUPOVA L A, ROGOV V A. Effect of the composition of Ni_xCo_3-xO₄(x=0-0.9) oxides on their catalytic activity in the low-temperature reaction of N₂O decomposition[J]. Kinet Catal, 2018, 59(3):365-370. doi: 10.1134%2FS0023158418030072
[5]	DOU Z, ZHANG H J, PAN Y F, XU X F. Catalytic decomposition of N₂O over potassium-modified Cu-Co spinel oxides[J]. J Fuel Chem Technol, 2014, 42(2):238-245. doi: 10.1016/S1872-5813(14)60016-5
[6]	FRANKEN T, PALKOVITS R. Investigation of potassium doped mixed spinels Cu_xCo_3-x O₄ as catalysts for an efficient N₂O decomposition in real reaction conditions[J]. Appl Catal B:Environ, 2015, 176/177:298-305. doi: 10.1016/j.apcatb.2015.04.002
[7]	WANG Y Z, HUO X B, ZHANG K, WEI X H, ZHAO Y X. Effect of SnO₂ on the structure and catalytic performance of Co₃O₄ for N₂O decomposition[J]. Catal Commun, 2018, 111:70-74. doi: 10.1016/j.catcom.2018.04.004
[8]	TURSUN M, WANG X P, ZHANG F, YU H B. Bi-Co₃O₄ catalyzing N₂O decomposition with strong resistance to CO₂[J]. Catal Commun, 2015, 65:1-5. doi: 10.1016/j.catcom.2015.02.013
[9]	YU H B, TURSUN M, WANG X P, WU X X. Pb_0.04Co catalyst for N₂O decomposition in presence of impurity gases[J]. Appl Catal B:Environ, 2016, 185:110-118. doi: 10.1016/j.apcatb.2015.12.011
[10]	YU H B, WANG X P, WU X X, CHEN Y. Promotion of Ag for Co₃O₄ catalyzing N₂O decomposition under simulated real reaction conditions[J]. Chem Eng J, 2018, 334:800-806. doi: 10.1016/j.cej.2017.10.079
[11]	KIM M J, LEE S J, RYU I S, JEON M W, MOON S H, ROH H S, JEON S G. Catalytic decomposition of N₂O over cobalt based spinel oxides:The role of additives[J]. Mol Catal, 2017, 422:202-207. https://www.sciencedirect.com/science/article/pii/S2468823117303048
[12]	XUE L, HE H, LIU C, ZHANG C B, ZHANG B. Promotion effects and mechanism of alkali metals and alkaline earth metals on cobalt-cerium composite oxide catalysts for N₂O decomposition[J]. Environ Sci Technol, 2009, 43(3):890-895. doi: 10.1021/es801867y
[13]	YOU Y, CHANG H, MA L, GUO L, QIN X, LI J Y, LI J H. Enhancement of N₂O decomposition performance by N₂O pretreatment over Ce-Co-O catalyst[J]. Chem Eng J, 2018, 347:184-192. doi: 10.1016/j.cej.2018.04.081
[14]	ABUZIED B M, BAWAKED S M, KOSA S A, SCHWIEGER W. Effect of Pr, Sm, and Tb doping on the morphology, crystallite size, and N₂O decomposition activity of Co₃O₄ nanorods[J]. J Nanomater, 2015, 56(12):1417-1423. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=Doaj000004122728
[15]	ZHAO T Q, GAO Q, LI H J, XU X F. Catalytic decomposition of N₂O over Y-Co₃O₄ composite oxides prepared by one-step hydrothermal method[J]. J Fuel Chem Technol, 2019, 47(4):446-454. doi: 10.1016/S1872-5813(19)30021-0
[16]	李岩, 邹晓玲, 张舒恒, 张相俊, 王虹, 李翠清, 宋永吉. M_0.5Co_2.5O₄(M=La, Ce, Pr, Nd)尖晶石型复合氧化物催化剂催化分解N₂O性能[J].工业催化, 2017, 25(4):28-33. doi: 10.3969/j.issn.1008-1143.2017.04.005 LI Yan, ZOU Xiao-ling, ZHANG Shu-heng, ZHANG Xiang-jun, WANG Hong, LI Cui-qing, SONG Yong-ji. Catalytic decomposition of N₂O on M_0.5Co_2.5O₄(M=La, Ce, Pr, Nd) spinel oxides catalysts[J]. Ind Catal, 2017, 25(4):28-33. doi: 10.3969/j.issn.1008-1143.2017.04.005
[17]	王焘, 王虹, 李翠清, 宋永吉, 丁福臣.稀土修饰的Co/Hβ催化剂催化分解N₂O[J].环境化学, 2012, 31(2):157-161. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hjhx201202004 WANG Tao, WANG Hong, LI Cui-qing, SONG Yong-ji, DING Fu-chen. N₂O decomposition over Co/Hβ catalysts doped with rare-earth metals[J]. Environ Chem, 2012, 31(2):157-161. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=hjhx201202004
[18]	ABU-ZIED B M, BAWAKED S M, KOSA S A, ALI T T, SCHWIEGER W, AQLAN F M. Effects of Nd-, Pr-, Tb-and Y-doping on the structural, textural, electrical and N₂O decomposition activity of mesoporous NiO nanoparticles[J]. Appl Surf Sci, 2017, 419:399-408. doi: 10.1016/j.apsusc.2017.05.040
[19]	ABU-ZIED B M, BAWAKED S M, KOSA S A, SCHWIEGER W. Impact of Gd-, La-, Nd-and Y-doping on the textural, electrical conductivity and N₂O decomposition activity of CuO catalyst[J]. Int J Electrochem Sci, 2016, 11:2230-2246.
[20]	XUE Z W, SHEN Y S, SHEN S B, LI C L, ZHU S M. Promotional effects of Ce⁴⁺, La³⁺ and Nd³⁺ incorporations on catalytic performance of Cu-Fe-O_x for decomposition of N₂O[J]. J Ind Eng Chem, 2015, 30:98-105. doi: 10.1016/j.jiec.2015.05.008
[21]	LI H J, ZHENG L, ZHAO T Q, XU X F. Effect of preparation parameters on the catalytic performance of hydrothermally synthesized Co₃O₄ in the decomposition of N₂O[J]. J Fuel Chem Technol, 2018, 46(6):717-724. doi: 10.1016/S1872-5813(18)30031-8
[22]	PAN Y F, FENG M, CUI X, XU X F. Catalytic activity of alkali metal doped Cu-Al mixed oxides for N₂O decomposition in the presence of oxygen[J]. J Fuel Chem Technol, 2012, 40(5):601-607. doi: 10.1016/S1872-5813(12)60024-3
[23]	STELMACHOWSKI P, MANIAK G, KOTARBA A, SOJKA Z. Strong electronic promotion of Co₃O₄ towards N₂O decomposition by surface alkali dopants[J]. Catal Commun, 2009, 10(7):1062-1065. doi: 10.1016/j.catcom.2008.12.057
[24]	郑珂, 王永钊, 胡晓波, 武瑞芳, 刘晓丽, 赵永祥.还原-氧化预处理对Co₃O₄催化分解N₂O性能的影响[J].燃料化学学报, 2019, 47(4):455-463. http://d.old.wanfangdata.com.cn/Periodical/rlhxxb201904009 ZHENG Ke, WANG Yong-zhao, HU Xu-bo, WU Rui-fang, LIU Xiao-li, ZHAO Yong-xiang. Effect of reduction-oxidation pretreatment on the catalytic performance of Co₃O₄ catalyst in N₂O decomposition[J]. J Fuel Chem Technol, 2019, 47(4):455-463. http://d.old.wanfangdata.com.cn/Periodical/rlhxxb201904009
[25]	YAO X J, CAO J, CHEN L, KANG K K, CHEN Y, TIAN M, YANG F M. Doping effect of cations (Zr⁴⁺, Al³⁺, and Si⁴⁺) on MnO_x/CeO₂ nano-rod catalyst for NH₃-SCR reaction at low temperature[J]. Chin J Catal, 2019, 40(5):733-743. doi: 10.1016/S1872-2067(18)63204-8