Mordenite supported Ni-W self-reducing bifunctional catalyst for cellulose hydrogenolysis into ethylene glycol

XIAO Zhu-qian; SHA Ru-yi; JI Jian-bing; MAO Jian-wei

Volume 44 Issue 10

Oct. 2016

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Article Navigation > Journal of Fuel Chemistry and Technology > 2016 > 44(10): 1225-1232

XIAO Zhu-qian, SHA Ru-yi, JI Jian-bing, MAO Jian-wei. Mordenite supported Ni-W self-reducing bifunctional catalyst for cellulose hydrogenolysis into ethylene glycol[J]. Journal of Fuel Chemistry and Technology, 2016, 44(10): 1225-1232.

Citation:

XIAO Zhu-qian, SHA Ru-yi, JI Jian-bing, MAO Jian-wei. Mordenite supported Ni-W self-reducing bifunctional catalyst for cellulose hydrogenolysis into ethylene glycol[J]. Journal of Fuel Chemistry and Technology, 2016, 44(10): 1225-1232.

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Mordenite supported Ni-W self-reducing bifunctional catalyst for cellulose hydrogenolysis into ethylene glycol

XIAO Zhu-qian^{1, 2, 3, 4},
SHA Ru-yi^{1, 2, 3
,
,},
JI Jian-bing⁴,
MAO Jian-wei^{1, 2, 3}

1.
School of Biological and Chemical Engineering, Zhejiang University of Science & Technology, Hangzhou 310023, China
2.
Zhejiang Provincial Key Laboratory of Chemical and Biological Processing Technology of Farm Products, Hangzhou 310023, China
3.
Collaborative Innovation Center of Agricultural Biological Resources Biochemical Manufacturing of Zhejiang Province, Hangzhou 310023, China
4.
College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China

More Information

Corresponding author: Tel: 0571-85070390, E-mail: zjhzxzq@yeah.net
Received Date: 2016-06-06
Rev Recd Date: 2016-07-10

Available Online: 2021-01-23

Publish Date: 2016-10-10

Abstract

Abstract

Based on the reducing gases (H₂ and CO) generated from biomass-based carbon at high clacination temperature, self-reducing bifunctional catalyst Ni-W/MOR was prepared by incipient impregnation. This series of catalysts were directly applied to cellulose hydrogenolysis to low carbon polyols in aqueous solution, omitting the catalysts reduction step. The effects of catalysts temperature of the catalyst and weight ratio of active components on conversion of cellulose and yield of target products were investigated. The optimal calcination temperature was 773 K through experimental results. XRD analysis showed that the crystallinity and species of metallic alloys were related to different weight ratios of nickel and tungsten. It was intuitively observed that the active metals showed good dispersion on the surface of MOR through TEM characterization, with particles sizes less than 20 nm. The total yield of low carbon polyols was up to 56.92%, including 52.30% of EG under the reaction condition of 5.0 MPa of H₂ for 2 h reaction time and the calcination temperature of catalysts was 773 K.
- mordenite,
- self-reducing catalysts,
- sugar polyols,
- hydrogenolysis,
- ethylene glycol

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References(16)

References

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