Effect of Ni-Cu on the one-step mild pressure hydrogenation of 1, 4-butynediol

FANG Jie; LI Na; CHENG Lang; LU Jiang-yin

Volume 47 Issue 6

Jun. 2019

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FANG Jie, LI Na, CHENG Lang, LU Jiang-yin. Effect of Ni-Cu on the one-step mild pressure hydrogenation of 1, 4-butynediol[J]. Journal of Fuel Chemistry and Technology, 2019, 47(6): 725-736.

Citation:

FANG Jie, LI Na, CHENG Lang, LU Jiang-yin. Effect of Ni-Cu on the one-step mild pressure hydrogenation of 1, 4-butynediol[J]. Journal of Fuel Chemistry and Technology, 2019, 47(6): 725-736.

FANG Jie, LI Na, CHENG Lang, LU Jiang-yin. Effect of Ni-Cu on the one-step mild pressure hydrogenation of 1, 4-butynediol[J]. Journal of Fuel Chemistry and Technology, 2019, 47(6): 725-736.

Citation:

FANG Jie, LI Na, CHENG Lang, LU Jiang-yin. Effect of Ni-Cu on the one-step mild pressure hydrogenation of 1, 4-butynediol[J]. Journal of Fuel Chemistry and Technology, 2019, 47(6): 725-736.

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Effect of Ni-Cu on the one-step mild pressure hydrogenation of 1, 4-butynediol

Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education, Xinjiang University, Urumqi 830046, China

Funds:

National Natural Science Foundation of China 21366030

More Information

Corresponding author: LU Jiang-yin, E-mail: jiangyinlu6410@163.com
Received Date: 2018-12-11
Rev Recd Date: 2019-03-05

Available Online: 2021-01-23

Publish Date: 2019-06-10

Abstract

Abstract

The deposition-precipitation method was employed for the purpose of bringing in metallic promoters into Ni/Al₂O₃ catalysts. The effects of various metallic promoters on the catalytic performance in 1, 4-butynediol (BYD) hydrogenation were investigated. Besides, the contents of the suitable promoter were further studied, which were combined with BET, XRD, H₂-TPR, EDX-MAPPING, TEM, XPS, and NH₃-TPD techniques, aimed at exploring physico-chemical characteristics in catalysts. As the findings suggested, the addition of different promoters substantially impacted the interaction between Ni²⁺ and support, acting as the key factor impacting the catalytic performance. The introduction of Cu and Fe had the potential to prominently lower the strong interaction between Ni²⁺ and support for the improvement of the BYD conversion of 95%. Furthermore, different contents of Cu were further studied and discovered that it was the phenomenon of hydrogen spillover arisen on Cu surfaces, efficiently lowering the interaction between Ni²⁺ and support. Nevertheless, the aggregation in Ni particles cannot be evitable, but for the existence of Ni-Cu alloying in Cu-added catalysts. As the Cu content reached up to 5%, the catalyst manifested the excellent catalytic performance in hydrogenation owing to the abundant amount of Ni⁰ active sites in the form of the high dispersion and the fitting acidity.
- Ni/Al₂O₃ catalysts,
- Ni-Cu,
- modification,
- BYD,
- BED

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References(49)

References

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