Steam reforming of phenol for producing hydrogen over nickel support on MgO prepared by different methods

JI Ting-ting; YANG Xiao-xuan; WANG Ya-jing; WANG Yu-he

Volume 44 Issue 9

Sep. 2016

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Article Navigation > Journal of Fuel Chemistry and Technology > 2016 > 44(9): 1131-1137

JI Ting-ting, YANG Xiao-xuan, WANG Ya-jing, WANG Yu-he. Steam reforming of phenol for producing hydrogen over nickel support on MgO prepared by different methods[J]. Journal of Fuel Chemistry and Technology, 2016, 44(9): 1131-1137.

Citation:

JI Ting-ting, YANG Xiao-xuan, WANG Ya-jing, WANG Yu-he. Steam reforming of phenol for producing hydrogen over nickel support on MgO prepared by different methods[J]. Journal of Fuel Chemistry and Technology, 2016, 44(9): 1131-1137.

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Steam reforming of phenol for producing hydrogen over nickel support on MgO prepared by different methods

College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025, China

Funds:

Overseas Scholars Program of Department of Education, Heilongjiang Province 1155h019

Program for Scientific and Technological Innovation Team Construction in University of Heilongjiang Province 2011TD010

Received Date: 2016-05-09
Rev Recd Date: 2016-06-29

Available Online: 2021-01-23

Publish Date: 2016-09-10

Abstract

Abstract

MgO-supported nickel catalysts were prepared by impregnation and hydrothermal coprecipitation methods; they were characterized by XRD, N₂ sorption, H₂-TPR, TEM and TG and used in the steam reforming of biomass oil model compound-phenol for hydrogen production. The results indicated that the NiO/MgO solid solution prepared by the impregnation method displays higher surface area (60.6 m²/g) and larger pore diameter (10.1 nm), in comparison with that prepared by hydrothermal coprecipitation. After reduction, the mesoporous Ni/MgO catalyst obtained from impregnation exhibits small and uniform Ni nanoparticles (5.0-6.0 nm) with high dispersion (19.44%). As high surface area is favorable for the dispersion of Ni nanoparticles and mesoporous structure can promote the mass transfer of reactants and products, the Ni/MgO catalyst exhibits high activity as well as excellent coke resistance ability and long-term stability in the steam reforming of phenol.
- mesoporous MgO,
- Ni/MgO catalyst,
- steam reforming,
- phenol,
- hydrogen

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References(22)

References

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