Performance of pentaethylenehexamine modified MIL-101(Cr) metal-organic framework in CO<sub>2</sub> adsorption

WANG Xiao-guang; LIU Dai; CHEN Shao-yun; LIU Yang; ZHANG Yong-chun

Volume 45 Issue 4

Apr. 2017

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Article Navigation > Journal of Fuel Chemistry and Technology > 2017 > 45(4): 484-490

WANG Xiao-guang, LIU Dai, CHEN Shao-yun, LIU Yang, ZHANG Yong-chun. Performance of pentaethylenehexamine modified MIL-101(Cr) metal-organic framework in CO2 adsorption[J]. Journal of Fuel Chemistry and Technology, 2017, 45(4): 484-490.

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WANG Xiao-guang, LIU Dai, CHEN Shao-yun, LIU Yang, ZHANG Yong-chun. Performance of pentaethylenehexamine modified MIL-101(Cr) metal-organic framework in CO₂ adsorption[J]. Journal of Fuel Chemistry and Technology, 2017, 45(4): 484-490.

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Performance of pentaethylenehexamine modified MIL-101(Cr) metal-organic framework in CO₂ adsorption

Dalian University of Technology, Institute of Chemical Engineering, State Key Laboratory of Fine Chemicals, Dalian 116023, China

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Corresponding author: ZHANG Yong-chun, Tel:0411-84986322, Fax:0411-84986322, E-mail:zalidy5518@vip.sina.com
Received Date: 2017-01-06
Rev Recd Date: 2017-03-13

Available Online: 2021-01-23

Publish Date: 2017-04-10

Abstract

Abstract

The metal-organic framework MIL-101(Cr) was synthesized via hydrothermal process and then modified with pentaethylenehexamine (PEHA) through refluxing in ethanol. Various measures such as SEM, XRD, N₂ sorption, Elemental analysis and FT-IR were used to characterize the structure, morphology and properties of PEHA-grafted MIL-101(Cr). Meanwhile, the performance of PEHA-grafted MIL-101(Cr) in CO₂ adsorption was investigated under 25℃. The results illustrate that the loading of PEHA in MIL-101(Cr) can conspicuously enhance the CO₂ adsorption capacity. PEHA-grafted MIL-101(Cr) with a PEHA loading of 0.24 mL exhibits the highest capacity for CO₂ adsorption; the adsorption capacity reaches 58.944 mg/g at 25℃ and atmospheric pressure, which is 33% higher than that of the unmodified MIL-101(Cr) (44.208 mg/g). In addition, the CO₂ adsorption capacities on both MIL-101(Cr) and PEHA-MIL-101(Cr) are greatly enhanced by increasing pressure, reaching 1 147.59 and 1 256.74 mg/g at 1.1 MPa, respectively. These results suggest that PEHA-modified MIL-101(Cr) could be a good candidate adsorbent for CO₂ capture at high pressure.
- metal-organic frameworks,
- MIL-101(Cr),
- pentaethylenehexamine,
- CO₂,
- absorption

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