Structure and property of AlOOH in CO hydrogenation

LI Lei-lei; TIAN Hui-hui; HAN Yan-mei; LIU Yan; GAO Zhi-hua; HUANG Wei

Volume 44 Issue 7

Jul. 2016

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LI Lei-lei, TIAN Hui-hui, HAN Yan-mei, LIU Yan, GAO Zhi-hua, HUANG Wei. Structure and property of AlOOH in CO hydrogenation[J]. Journal of Fuel Chemistry and Technology, 2016, 44(7): 830-836.

Citation:

LI Lei-lei, TIAN Hui-hui, HAN Yan-mei, LIU Yan, GAO Zhi-hua, HUANG Wei. Structure and property of AlOOH in CO hydrogenation[J]. Journal of Fuel Chemistry and Technology, 2016, 44(7): 830-836.

LI Lei-lei, TIAN Hui-hui, HAN Yan-mei, LIU Yan, GAO Zhi-hua, HUANG Wei. Structure and property of AlOOH in CO hydrogenation[J]. Journal of Fuel Chemistry and Technology, 2016, 44(7): 830-836.

Citation:

LI Lei-lei, TIAN Hui-hui, HAN Yan-mei, LIU Yan, GAO Zhi-hua, HUANG Wei. Structure and property of AlOOH in CO hydrogenation[J]. Journal of Fuel Chemistry and Technology, 2016, 44(7): 830-836.

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Structure and property of AlOOH in CO hydrogenation

Key Laboratory of Coal Science and Technology of Ministry of Education and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, China

Funds:

The project was supported by the National Natural Science Foundation of China 21336006

Natural Science Foundation of Shanxi Province 2012011046-1

More Information

Corresponding author: GAO Zhi-hua, Tel/Fax: 0351-6018466, E-mail: gaozhihua@tyut.edu.cn
Received Date: 2015-12-18
Rev Recd Date: 2016-03-23

Available Online: 2021-01-23

Publish Date: 2016-07-10

Abstract

Abstract

AlOOH were prepared by precipitation-hydrothermal method with different water-to-gel ratios, which were mixed with industrial methanol synthesis catalyst C302 and tested for CO hydrogenation in the fixed-bed reactor. The AlOOH samples were characterized by XRD, FT-IR, BET, NH₃-TPD-MS, TG-DTG and H₂-TPR. The results showed that the ratios of water-to-gel in the hydrothermal process had obvious influence on the preferred orientation, pore structure and surface acidity of AlOOH, leading to the different selectivity of higher alcohols and DME. When the ratio of water-to-gel was 2:1, AlOOH showed in (020) and (120) preferred orientation. Moreover, it had larger pore volume and proper ratio of weak acid sites to strong acid sites, the composite catalyst showed a relatively high selectivity of higher alcohols, which indicated that AlOOH favored the growth of carbon chains. This study provided a new way for synthesis of higher alcohols from syngas.
- AlOOH,
- syngas,
- higher alcohols,
- precipitation hydrothermal method,
- dimethyl ether

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References(37)

References

[1]	GALLEGO G S, BATIOT-DUPEYRAT C, BARRAULT J, FLOREZ E, MONDRAGÓN F. Dry reforming of methane over LaNi_1-yB_yO_3±δ (B=Mg, Co) perovskites used as catalyst precursor[J]. Appl Catal A: Gen, 2008, 334(1/2): 251-258.
[2]	SAN-JOSÉ-ALONSO D, JUAN-JUAN J, ILLÁN-GÓMEZ M J, ROMÁN-MARTÍNEZ M C. Ni, Co and bimetallic Ni-Co catalysts for the dry reforming of methane[J]. Appl Catal A: Gen, 2009, 371(1/2): 54-59. https://www.researchgate.net/publication/257373495_Ni_Co_and_bimetallic_Ni-Co_catalysts_for_the_dry_reforming_of_methane
[3]	JAKOBSEN J G, JAKOBSEN M, CHORKENDORFF I, SEHESTED J. Methane steam reforming kinetics for a rhodium-based catalyst[J]. Catal Lett, 2010, 140(3): 90-97. doi: 10.1007/s10562-010-0436-7?view=classic
[4]	XU J H, YEUNG C M Y, NI J, MEUNIER F, ACERBI N, FOWLES M, TSANG S C. Methane steam reforming for hydrogen production using low water-ratios without carbon formation over ceria coated Ni catalysts[J]. Appl Catal A: Gen, 2008, 345(2): 119-127. doi: 10.1016/j.apcata.2008.02.044
[5]	CHRISTIAN ENGER B, LØDENG R, HOLMEN A. A review of catalytic partial oxidation of methane to synthesis gas with emphasis on reaction mechanisms over transition metal catalysts[J]. Appl Catal A: Gen, 2008, 346(1/2): 1-27. https://www.researchgate.net/publication/234842361_A_review_of_catalytic_partial_oxidation_of_methane_to_synthesis_gas_with_emphasis_on_reaction_mechanisms_over_transition_metal_catalysts
[6]	SILÜA C R B, DA CONCEIÇÃO L, RIBEIRO N F P, SOUZA M M V M. Partial oxidation of methane over Ni-Co perovskite catalysts[J].Catal Commun, 2011, 12(7): 665-668. doi: 10.1016/j.catcom.2010.12.025
[7]	MAESTRI M, VLACHOS D G, BERETTA A, GROPPI G, TRONCONI E. Steam and dry reforming of methane on Rh: Microkinetic analysis and hierarchy of kinetic models[J]. J Catal, 2008, 259(2): 211-222. doi: 10.1016/j.jcat.2008.08.008
[8]	MORTOLA V B, DAMYANOVA S, ZANCHET D, BUENO J M C. Surface and structural features of Pt/CeO₂-La₂O₃-Al₂O₃ catalysts for partial oxidation and steam reforming of methane[J]. Appl Catal B: Environ, 2011, 107(3/4): 221-236.
[9]	BAEK S C, BAE J W, CHEON J Y, JUN K W, LEE K Y. Combined steam and carbon dioxide reforming of methane on Ni/MgAl₂O₄: Effect of CeO₂ promoter to catalytic performance[J]. Catal Lett, 2011, 141(2): 224-234. doi: 10.1007/s10562-010-0483-0
[10]	李德宝, 马玉刚, 齐会杰, 李文怀, 孙予罕, 钟炳. CO加氢合成低碳混合醇催化体系研究新进展[J].化学进展, 2004, 16(4): 584-592. http://www.cnki.com.cn/Article/CJFDTOTAL-HXJZ200404013.htm LI De-bao, MA Yu-gang, QI Hui-Jie, LI Wen-huai, SUN Yu-han, ZHONG Bing. Progress in synthesis of mixed alcohols from CO hydrogenation[J]. Prog Chem, 2004, 16(4): 584-592. http://www.cnki.com.cn/Article/CJFDTOTAL-HXJZ200404013.htm
[11]	葛庆杰, 徐恒泳, 李文钊.煤层气经合成气制液体燃料的关键技术[J].化工进展, 2009, 28(6): 917-921. http://www.cnki.com.cn/Article/CJFDTOTAL-HGJZ200906003.htm GE Qing-jie, XU Heng-yong, LI Wen-zhao. Key techniques of liquid fuel synthesis from coal-bed methane[J]. Chem Ind Eng Prog, 2009, 28(6): 917-921. http://www.cnki.com.cn/Article/CJFDTOTAL-HGJZ200906003.htm
[12]	SURISETTY V R, DALAI A K, KOZINSKI J. Influence of porous characteristics of the carbon support on alkali-modified trimetallic Co-Rh-Mo sulfided catalysts for higher alcohols synthesis from synthesis gas[J]. Appl Catal A: Gen, 2011, 393(1/2): 50-58. http://linkinghub.elsevier.com/retrieve/pii/S0926860X10007805
[13]	SHU L, KALIAGUINE S. WELL-DISPERSED perovskite-type oxidation catalysts[J]. Appl Catal B: Environ, 1998, 16(4): L303-L308. doi: 10.1016/S0926-3373(97)00097-0
[14]	MAHDAVI V, PEYROVI M H, ISLAMI M, YEGANE M J. Synthesis of higher alcohols from syngas over Cu-Co₂O₃/ZnO, Al₂O₃ catalyst[J]. Appl Catal A: Gen, 2005, 281(1/2): 259-265.
[15]	杨成, 李建青, 蔡飞鹏, 孙立, 吴晋沪.一种用于合成气制低碳醇的催化剂及制法和应用:中国, CN101653729[P]. 2010-02-24. YANG Cheng, LI Jian-qing, CAI Fei-peng, SUN Li, WU Jing-hu. Preparation and application of catalysts for higher alcohols synthesis from syngas: CN, 101653729[P]. 2010-02-24.
[16]	SUBRAMANI V, GANGWAL S K. A review of recent literature to search for an efficient catalytic process for the conversion of syngas to ethanol[J]. Energy Fuels, 2008, 22(2): 814-839. doi: 10.1021/ef700411x
[17]	朱秋峰, 张荣俊, 贺德华. CaO改性对CuZnAlZr催化剂在合成气制低碳醇中性能的影响[J].物理化学学报, 2012, 28(6): 1461-1466. http://www.cnki.com.cn/Article/CJFDTOTAL-WLHX201206027.htm ZHU Qiu-feng, ZHANG Rong-jun, HE De-hua. Effect of CaO modification on performance of CuZnAlZr catalyst in synthesis of higher alcohols from synthesis gas[J]. Acta Phys-Chim Sin, 2012, 28(6): 1461-1466. http://www.cnki.com.cn/Article/CJFDTOTAL-WLHX201206027.htm
[18]	SUBRAMANIAN N D, BALAJI G, KUMAR CHALLA S S R, SPIVERY JAMES J. Development of cobalt-copper nanoparticles as catalysts for higher alcohol synthesis from syngas[J]. Catal Today, 2009, 147(2): 100-106. doi: 10.1016/j.cattod.2009.02.027
[19]	LIN M G, FANG K G, LI D B, SUN Y H. CO hydrogenation to mixed alcohols over co-precipitated Cu-Fe catalysts[J]. Catal Commun, 2008, 9(9): 1869-1873. doi: 10.1016/j.catcom.2008.03.004
[20]	SURISETTY V R, TAVASOLI A, DALAI A K. Synthesis of higher alcohols from syngas over alkali promoted MoS₂ catalysts supported on multi-walled carbon nanotubes[J]. Appl Catal A: Gen, 2009, 365(2): 243-251. doi: 10.1016/j.apcata.2009.06.017
[21]	刘雷, 黄伟, 高志华.一种甲醇脱水制二甲醚的催化剂及其制备法:CN, 200710139633.0[P].2008-04-09. LIU Lei, HUANG Wei, GAO Zhi-hua. The preparation method of catalyst for DME synthesis from methanol dehydration: CN, 200710139633.0[P]. 2008-04-09.
[22]	樊金串, 吴慧, 黄伟, 谢克昌.表面活性剂对完全液相法制Cu-Zn-Al浆状催化剂结构和性能的影响[J].高等学校化学学报, 2008, 29(5): 993-999. http://www.cnki.com.cn/Article/CJFDTOTAL-GDXH200805026.htm FAN Jin-chuan, WU Hui, HUANG Wei, XIE Ke-chang. Effect of surfactants on structure and performance of Cu-Zn-Al catalyst prepared by complete liquid-phase technology[J]. Chem J Chin Univ, 2008, 29(5): 993-999. http://www.cnki.com.cn/Article/CJFDTOTAL-GDXH200805026.htm
[23]	BOKHIMI X, SANCHEZ VALENTE J, PEDRAZA F. Crystallization of sol-gel boehmite via hydrothermal annealing[J]. Solid State Chem, 2002, 166(1): 182-190. doi: 10.1006/jssc.2002.9579
[24]	CHEN X Y, ZHANG Z J, LI X L, LEE S W. Controlled hydrothermal synthesis of colloidal boehmite (γ-AlOOH) nanorods and nanoflakes and their conversion into γ-Al₂O₃ nanocrystals[J]. Solid State Commun, 2008, 145(7/8): 368-373.
[25]	LI G C, LIU Y Q, LIU D, LIU L H, LIU C G. Synthesis of flower-like Boehmite (AlOOH) via a simple solvothermal process without surfactant[J]. Mater Res Bull, 2010, 45(10): 1487-1491. doi: 10.1016/j.materresbull.2010.06.013
[26]	XU Z H, YU J G, LOW J X, JARONIEC M. Microemulsion-assisted synthesis of mesoporous aluminum oxyhydroxide nanoflakes for efficient removal of gaseous formaldehyde[J]. ACS Appl Mater Interfaces, 2014, 6(3): 2111-2117. doi: 10.1021/am405224u
[27]	JEFFERY A G, DAVID B H, MARGARET E O. Alcohol and thiol adsorption on (oxy) hydroxide and carbon surfaces: Molecular dynamics simulation and desorption experiments[J]. J Phys Chem C, 2012, 116(51): 26756-26764. doi: 10.1021/jp305275q
[28]	HUANG J, WANG Y, ZHENG J M, DAI W L, FAN K N. Influence of support surface basicity and gold particle size on catalytic activity of Au/γ-AlOOH and Au/γ-Al₂O₃ catalyst in aerobic oxidation of α, ω-diols to lactones[J]. Appl Catal B: Environ, 2011, 103(3): 343-350.
[29]	栾春晖, 吕经纬, 阴丽华, 黄伟.完全液相法AlOOH催化甲醇脱水行为研究[J].太原理工大学学报, 2014, 45(1): 92-96. http://www.cnki.com.cn/Article/CJFDTOTAL-TYGY201401020.htm LUAN Chun-hui, LÜ Jing-wei, YIN Li-hua, HUANG Wei. Catalysis performance of AlOOH catalysts prepared by complete liquid-phase method for methanol dehydration to dimethyl ether in a fixed bed[J]. J Taiyuan Univ Technol, 2014, 45(1): 92-96. http://www.cnki.com.cn/Article/CJFDTOTAL-TYGY201401020.htm
[30]	肖康, 鲍正洪, 齐行振, 王新星, 钟良枢, 房克功, 林明桂, 孙予罕.合成气制混合醇双功能催化研究进展[J].催化学报, 2013, 34(1): 116-129. doi: 10.1016/S1872-2067(11)60496-8 XIAO Kang, BAO Zheng-hong, QI Xing-zhen, WANG Xin-xing, ZHONG Liang-shu, FANG Ke-gong, LIN Ming-gui, SUN Yu-han. Advances in bifunctional catalysis for higher alcohol synthesis from syngas[J]. Chin J Catal, 2013, 34(1): 116-129. doi: 10.1016/S1872-2067(11)60496-8
[31]	宋宪根, 丁云杰, 陈维茵, 董文达, 裴彦鹏, 臧娟, 严丽, 吕元.铁镍磷化物催化剂在CO加氢制低碳醇反应的应用[J].催化学报, 2012, 33(11/12): 1938-1944. http://www.cnki.com.cn/Article/CJFDTOTAL-CHUA201212013.htm SONG Xian-gen, DING Yun-jie, CHEN Wei-yin, DONG Wen-dong, PEI Yan-peng, ZANG Juan, YAN Li, LÜ yuan. Synthesis of mixed alcohols from CO hydrogenation over Iron and nickel metal phosphide catalysts[J]. Chin J Catal, 2012, 33(11/12): 1938-1944. http://www.cnki.com.cn/Article/CJFDTOTAL-CHUA201212013.htm
[32]	PETROVIC R, MILONJIC S, JOKANOVIC V, KOSTIC-GVOZDENOVIC L, PETROVIC-PRELEVIC I, JANACKOVIC D. Influence of synthesis parameters on the structure of boehmite sol particles[J]. Powder Technol, 2003, 133(1/3): 185-189. https://www.researchgate.net/publication/223502010_Influence_of_Synthesis_Parameters_on_the_Structure_of_Bohmite_Sol_Particles
[33]	罗玉长.拟薄水铝石结构的演化[J].无机盐工业, 1998, 30(2): 3-5. http://www.cnki.com.cn/Article/CJFDTOTAL-QJSS200102003.htm LUO Yu-chang. The structure evolution of pseudo-boehmite[J]. Inorg Chem Ind, 1998, 30(2): 3-5. http://www.cnki.com.cn/Article/CJFDTOTAL-QJSS200102003.htm
[34]	刘建国, 定明月, 王铁军, 马隆龙. Cu-Fe基双孔载体催化剂结构和低碳醇合成反应性能[J].物理化学学报, 2012, 28(8): 1964-1970. http://www.cnki.com.cn/Article/CJFDTOTAL-WLHX201208026.htm LIU Jian-guo, DING Ming-yue, WANG Tie-jun, MA Long-long. Structure and performance of Cu-Fe bimodal support for higher alcohol syntheses[J]. Acta Phys-Chim Sin, 2012, 28(8): 1964-1970. http://www.cnki.com.cn/Article/CJFDTOTAL-WLHX201208026.htm
[35]	XU M T, LUNSFORD J H, GOODMAN D W, BHATTACHARYYA A. Synthesis of dimethyl ether (DME) from methanol over solid-acid catalysts[J]. Appl Catal A: Gen, 1997, 149(2): 289-301. doi: 10.1016/S0926-860X(96)00275-X
[36]	JOO O S, JUNG K D, HAN S H. Modification of H-ZSM-5 and γ-alumina with formaldehyde and its application to the synthesis of dimethyl ether from syn-gas[J]. Bull Korean Chem Soc, 2002, 23(8): 1103-1105. doi: 10.5012/bkcs.2002.23.8.1103
[37]	解峰, 黎汉生, 赵学良, 任飞, 王德峥, 王金福, 刘敬利.甲醇在活性Al₂O₃催化剂表面的吸附与脱水反应[J].催化学报, 2004, 25(5): 403-408. XIE Feng, LI Han-sheng, ZHAO Xue-Liang, REN Fei, WANG De-zheng, Wang Jin-fu, LIU Jing-li. Adsorption and dehydration of methanol on Al₂O₃ Catalyst[J]. Chin J Catal, 2004, 25(5): 403-408.