Effect of calcination temperature on MgAlO<sub><i>x</i></sub> mixed oxides for converting formaldehyde and acetaldehyde to propanal

CHENG Fu-long; GUO He-qin; CUI Jing-lei; HOU Bo; LI De-bao

Volume 46 Issue 7

Jul. 2018

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Article Navigation > Journal of Fuel Chemistry and Technology > 2018 > 46(7): 841-847

CHENG Fu-long, GUO He-qin, CUI Jing-lei, HOU Bo, LI De-bao. Effect of calcination temperature on MgAlOx mixed oxides for converting formaldehyde and acetaldehyde to propanal[J]. Journal of Fuel Chemistry and Technology, 2018, 46(7): 841-847.

Citation:

CHENG Fu-long, GUO He-qin, CUI Jing-lei, HOU Bo, LI De-bao. Effect of calcination temperature on MgAlO_x mixed oxides for converting formaldehyde and acetaldehyde to propanal[J]. Journal of Fuel Chemistry and Technology, 2018, 46(7): 841-847.

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Effect of calcination temperature on MgAlO_x mixed oxides for converting formaldehyde and acetaldehyde to propanal

CHENG Fu-long^{1, 2},
GUO He-qin^{1
,
,},
CUI Jing-lei³,
HOU Bo¹,
LI De-bao^{1
,
,}

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China
3.
Institute of Resources and Environment Engineering, Shanxi University, Taiyuan 030006, China

Funds:

the National Natural Science Foundation of China 21736007

the National Natural Science Foundation of China 21303241

More Information

Corresponding author: GUO He-qin, Tel:0351-4040499, E-mail:heqinguo@sxicc.ac.cn; LI De-bao, E-mail:dbli@sxicc.ac.cn
Received Date: 2018-01-15
Rev Recd Date: 2018-05-11

Available Online: 2021-01-23

Publish Date: 2018-07-10

Abstract

Abstract

A series of MgAlO_x mixed oxides were prepared by calcination of hydrotalcite materials at various temperatures ranging from 400 to 700℃. The physical and chemical properties of the catalysts were characterized by XRD, TG, N₂ adsorption/desorption, NH₃-TPD, and CO₂-TPD techniques. The catalytic activity was evaluated by the condensation of formaldehyde and acetaldehyde. The results show that as the calcination temperatures increase, both the conversion of acetaldehyde and the space time yield of propanal first increase and then decrease, which shows the same trend with the amount of moderate basic sites, and the C-550 catalyst has the maximum of 39.22% and 103.86 g/(kg·h), respectively. Moreover, the yields of by-products including methanol and CO₂ are also significantly related to the moderate and strong basic sites.
- formaldehyde and acetaldehyde,
- propanal,
- MgAlO_x mixed oxides,
- calcination temperature

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References(22)

References

[1]	崔小明.丙醛的生产应用及市场前景[J].杭州化工, 2003, 33(3):17-20. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=schgyfskz200304004 CUI Xiao-ming. Production, application, and market prospect pf propaldehyde[J]. Hangzhou Chem Ind, 2003, 33(3):17-20. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=schgyfskz200304004
[2]	李明.丙醛的生产应用及市场前景[J].精细化工原料及中间体, 2005, 23(6):23-29. http://www.cnki.com.cn/Article/CJFDTOTAL-ZJTY2003Z2003.htm LI Ming. Production, application, and market prospect pf propaldehyde[J]. Fine Chem Ind Raw Mater Intermed, 2005, 23(6):23-29. http://www.cnki.com.cn/Article/CJFDTOTAL-ZJTY2003Z2003.htm
[3]	ZHU X, LOBBAN L L, MALLINSON R G, RESASCO D E. Tailoring the mesopore structure of HZSM-5 to control product distribution in the conversion of propanal[J]. J Catal, 2010, 271(1):88-98. doi: 10.1016/j.jcat.2010.02.004
[4]	张福生.丙醛生产及其应用[J].江苏化工, 1996, 24(4):35-37. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=jshg604.010&dbname=CJFD&dbcode=CJFQ ZHANG Fu-sheng. Preparation and application of propanal[J]. Jiangsu Chem Ind, 1996, 24(4):35-37. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=jshg604.010&dbname=CJFD&dbcode=CJFQ
[5]	KAINULAINEN T A, NIEMELA M K, KRAUSE A O I. Ethene hydroformylation on Co/SiO₂ catalysts[J]. Catal Lett, 1998, 53(1/2):97-101. doi: 10.1023/A:1019053805618
[6]	TRICAS H, DIEBOLT O, VAN LEEUWEN P W N M. Bulky monophosphite ligands for ethene hydroformylation[J]. J Catal, 2013, 298:198-205. doi: 10.1016/j.jcat.2012.11.031
[7]	AI M. Formation of acrylaldehyde by vapor-phase aldol condensation 2. Phosphate catalysts[J]. Bull Chem Soc Jpn, 1991, 64(4):1346-1350. doi: 10.1246/bcsj.64.1346
[8]	AI M. Formation of acrylaldehyde by vapor-phase aldol condensation 1. Basic oxide catalysts[J]. Bull Chem Soc Jpn, 1991, 64(4):1342-1345. doi: 10.1246/bcsj.64.1342
[9]	AZZOUZ A, MESSAD D, NISTOR D, CATRINESCU C, ZVOLINSCHI A, ASAFTEI S. Vapor phase aldol condensation over fully ion-exchanged montmorillonite-rich catalysts[J]. Appl Catal A:Gen, 2003, 241(1/2):1-13. http://www.sciencedirect.com/science/article/pii/S0926860X02005240
[10]	DUMITRIU E, HULEA V, CHELARU C, CATRINESCU C, TICHIT D, DURAND R. Influence of the acid-base properties of solid catalysts derived from hydrotalcite-like compounds on the condensation of formaldehyde and acetaldehyde[J]. Appl Catal A:Gen, 1999, 178(2):145-157. doi: 10.1016/S0926-860X(98)00282-8
[11]	CAVANI F, TRIFIRO F, VACCARI A. Hydrotalcite-type anionic clays:Preparation, properties and applications[J]. Catal Today, 1991, 11(2):173-301. doi: 10.1016/0920-5861(91)80068-K
[12]	RAMASAMY K K, GRAY M, JOB H, SANTOSA D, LI X S, DEVARAJ A, KARKAMKAR A, WANG Y. Role of calcination temperature on the hydrotalcite derived MgO-Al₂O₃ in converting ethanol to butanol[J]. Top Catal, 2016, 59(1):46-54. doi: 10.1007/s11244-015-0504-8
[13]	STOSIC D, HOSOGLU F, BENNICI S, TRAVERT A, CAPRON M, DUMEIGNIL F, COUTURIER J L, DUBOIS J L, AUROUX A. Methanol and ethanol reactivity in the presence of hydrotalcites with Mg/Al ratios varying from 2 to 7[J]. Catal Commun, 2017, 89:8-14. http://www.sciencedirect.com/science/article/pii/S1566736716303788
[14]	GAO P, LI F, ZHAO N, XIAO F K, WEI W, ZHONG L S, SUN Y H. Influence of modifier (Mn, La, Ce, Zr and Y) on the performance of Cu/Zn/Al catalysts via hydrotalcite-like precursors for CO₂ hydrogenation to methanol[J]. Appl Catal A:Gen, 2013, 468:442-452. doi: 10.1016/j.apcata.2013.09.026
[15]	雒京, 李洪广, 赵宁, 王峰, 肖福魁.磺化Salen金属配合物插层水滑石选择性催化氧化甘油制备二羟基丙酮的研究[J].燃料化学学报, 2015, 43(6):677-683. http://manu60.magtech.com.cn/rlhxxb/CN/abstract/abstract18640.shtml LUO Jing, LI Hong-guang, ZHAO Ning, WANG Feng, XIAO Fu-kui. Selective oxidation of glycerol to dihydroxyacetone over layer double hydroxide intercalated with sulfonato-salen metal complexes[J]. J Fuel Chem Technol, 2015, 43(6):677-683. http://manu60.magtech.com.cn/rlhxxb/CN/abstract/abstract18640.shtml
[16]	CANTRELL D G, GILLIE L J, LEE A F, WILSON K. Structure-reactivity correlations in MgAl hydrotalcite catalysts for biodiesel synthesis[J]. App Catal A:Gen, 2005, 287(2):183-190. doi: 10.1016/j.apcata.2005.03.027
[17]	GAO P, LI F, ZHAN H J, ZHAO N, XIAO F K, WEI W, ZHONG L S, WANG H, SUN Y H. Influence of Zr on the performance of Cu/Zn/Al/Zr catalysts via hydrotalcite-like precursors for CO₂ hydrogenation to methanol[J]. J Catal, 2013, 298:51-60. doi: 10.1016/j.jcat.2012.10.030
[18]	杜亚丽, 谢鲜梅, 吴旭, 胡秋霞, 王志忠. TG-DTA技术在类水滑石化合物热分解研究中的应用[J].应用化工, 2005, 34(9):5-12. http://www.cnki.com.cn/Article/CJFDTOTAL-WJHX200208017.htm DU Ya-li, XIE Xian-mei, WU xu, HU Qiu-xia, WANG Zhi-zhong. TG-DTA technology used in thermal decomposition of hydrotalcite-like compounds[J]. App Chem Ind, 2005, 34(9):5-12. http://www.cnki.com.cn/Article/CJFDTOTAL-WJHX200208017.htm
[19]	SHEN J Y, TU M, HU C. Structural and surface acid/base properties of hydrotalcite-derived MgAlO oxides calcined at varying temperatures[J]. J Solid State Chem, 1998, 137(2):295-301. doi: 10.1006/jssc.1997.7739
[20]	DI COSIMO J I, DIEZ V K, XU M, IGLESIA E, APESTEGUIA C R. Structure and surface and catalytic properties of Mg-Al basic oxides[J]. J Catal, 1998, 178(2):499-510. doi: 10.1006/jcat.1998.2161
[21]	张军, 王秀芝, 赵宁, 肖福魁, 魏伟, 孙予罕.氟修饰的含Ni类水滑石在甲烷部分氧化制合成气中的应用研究[J].燃料化学学报, 2012, 40(4):424-429. http://manu60.magtech.com.cn/rlhxxb/CN/abstract/abstract17921.shtml ZHANG Jun, WANG Xiu-zhi, ZAHO Ning, XIAO Fu-kui, WEI wei, SUN Yu-han. Application of fluorine-modified Ni-Mg-Al hydrotalcite catalyst in the partial oxidation of methane to syngas[J]. J Fuel Chem Technol, 2012, 40(4):424-429. http://manu60.magtech.com.cn/rlhxxb/CN/abstract/abstract17921.shtml
[22]	LIU Y X, SUN K P, MA H W, XU X L, WANG X L. Zr-incorporated hydrotalcites and their application in the synthesis of isophorone[J]. Catal Commun, 2010, 11(10):880-883. doi: 10.1016/j.catcom.2010.03.014