Effect of Ni2P loading on the structure and naphthalene hydrogenation performance of Ni2P/Ce-Al2O3 catalyst

QIE Zhi-qiang; ZHANG Zi-yi; JING Jie-ying; YANG Zhi-fen; FENG Jie; LI Wen-ying

Volume 47 Issue 6

Jun. 2019

Turn off MathJax

Article Contents

Article Navigation > Journal of Fuel Chemistry and Technology > 2019 > 47(6): 718-724

QIE Zhi-qiang, ZHANG Zi-yi, JING Jie-ying, YANG Zhi-fen, FENG Jie, LI Wen-ying. Effect of Ni2P loading on the structure and naphthalene hydrogenation performance of Ni2P/Ce-Al2O3 catalyst[J]. Journal of Fuel Chemistry and Technology, 2019, 47(6): 718-724.

Citation:

QIE Zhi-qiang, ZHANG Zi-yi, JING Jie-ying, YANG Zhi-fen, FENG Jie, LI Wen-ying. Effect of Ni₂P loading on the structure and naphthalene hydrogenation performance of Ni₂P/Ce-Al₂O₃ catalyst[J]. Journal of Fuel Chemistry and Technology, 2019, 47(6): 718-724.

Citation:

PDF( 4828 KB)

Effect of Ni₂P loading on the structure and naphthalene hydrogenation performance of Ni₂P/Ce-Al₂O₃ catalyst

Training Base of State Key Laboratory of Coal Science and Technology, Taiyuan University of Technology, Taiyuan 030024, China

Funds:

the National Natural Science Foundation of China U1610221

Natural Science Foundation of Shanxi Province 201701D221237

Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi 164010121-S

More Information

Corresponding author: JING Jie-ying, Tel/Fax: 86-351-6018453, E-mail: jingjieying@tyut.edu.cn
Received Date: 2019-01-30
Rev Recd Date: 2019-04-16

Available Online: 2021-01-23

Publish Date: 2019-06-10

Abstract

Abstract

A series of Ni₂P/Ce-Al₂O₃ catalysts were prepared by temperature-programmed reduction method, and the influence of Ni₂P loading on the catalyst structure and naphthalene hydrogenation saturation performance was investigated. The results show that the specific surface area, the Ni₂P particle size and the active site number of the as-synthesized catalysts are greatly affected by Ni₂P loading, which is derived from the variable interaction between active component Ni₂P and the support Ce-Al₂O₃. When the Ni₂P loading is 17% (mass ratio), the catalyst possesses a large specific surface area (40 m²/g), a small Ni₂P particle size (26.3 nm), and the maximum number of active sites (26.7 μmol/g). Meanwhile, the conversion rate of naphthalene and the selectivity of decalin reach to 95% and 76%, respectively, and the activity stability of the catalyst is good, which is mainly attributed to the large specific surface area and high number of active sites of the catalyst providing more sites for the reaction.
- naphthalene hydrogenation,
- Ni₂P/Ce-Al₂O₃,
- Ni₂P loading,
- temperature-programmed reduction method

FullText(HTML)

References(18)

References

[1]	COOPER B H, DONNIS B. Aromatic saturation of distillates:An overview[J]. Appl Catal A:Gen, 1996, 137(2):203-223. doi: 10.1016/0926-860X(95)00258-8
[2]	焦燕, 冯利利, 朱岳麟, 熊常健.美国军用喷气燃料发展综述[J].火箭推进, 2008, 34(1):30-35. doi: 10.3969/j.issn.1672-9374.2008.01.007 JIAO Yan, FENG Li-li, ZHU Yue-lin, XIONG Chang-jian. Review of American military jet fuels development[J]. J Rocket Propul, 2008, 34(1):30-35). doi: 10.3969/j.issn.1672-9374.2008.01.007
[3]	佟瑞利, 王永刚, 张旭, 张海永, 戴谨泽, 林雄超, 许德平. P改性NiW/Al₂O₃的低温焦油芳烃组分加氢性能研究[J].燃料化学学报, 2015, 43(12):1461-1469. doi: 10.3969/j.issn.0253-2409.2015.12.009 TONG Rui-li, WANG Yong-gang, ZHANG Xu, ZHANG Hai-yong, DAI Jin-ze, LIN Xiong-chao, XU De-ping. Effect of phosphorus modification on the catalytic properties of NiW/Al₂O₃ in the hydrogenation of aromatics from coal tar[J].J Fuel Chem Technol, 2015, 43(12):1461-1469. doi: 10.3969/j.issn.0253-2409.2015.12.009
[4]	HE T, WANG Y, MIAO P, LI J, WU J, FANG Y. Hydrogenation of naphthalene over noble metal supported onmesoporous zeolite in the absence and presence of sulfur[J]. Fuel, 2013, 106:365-371. doi: 10.1016/j.fuel.2012.12.025
[5]	李贺, 殷长龙, 赵雪萍, 李秀峥, 柳云骐, 刘晨光.萘、四氢萘和十氢萘的加氢或脱氢反应与催化剂的研究进展[J].石油化工, 2014, 43(8):971-979. doi: 10.3969/j.issn.1000-8144.2014.08.020 LI He, YIN Chang-long, ZHAO Xue-ping, LI Xiu-zheng, LIU Yun-qi, LIU Chen-guang. Progresses in hydrogenation orhehydrogenation of naphthalene, tetralin and decalin, and the catalysts[J]. Petrochem Technol, 2014, 43(8):971-979. doi: 10.3969/j.issn.1000-8144.2014.08.020
[6]	LI R, GUAN Q, WEI R, YANG S, SHU Z, DONG Y, CHEN J, LI W. A potential regularity for enhancing the hydrogenation properties of Ni₂P[J]. J Phy Chem C, 2015, 119(5):2557-2565. doi: 10.1021/jp511191e
[7]	LIU D, WANG A, LIU C, PRINS R. Bulk and Al₂O₃-supported Ni₂P HDS catalysts prepared by separating the nickel and hypophosphite sources[J]. Catal Commun, 2016, 77:13-17. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=412aa624e55137137db3b75efb902e64
[8]	YUN G, GUAN Q, LI W. The synthesis and mechanistic studies of a highly active nickel phosphide catalyst for naphthalene hydrodearomatization[J]. RSC Adv, 2017, 7(14):8677-8687. doi: 10.1039/C7RA00250E
[9]	YANG Y, LI J, LV G, ZHANG L. Novel method to synthesize Ni₂P/SBA-15 adsorbents for the adsorptive desulfurization of model diesel fuel[J]. J Alloy Compd, 2018, 745:467-476. doi: 10.1016/j.jallcom.2018.02.156
[10]	SONG H, WANG J, WANG Z, SONG H, LI F, JIN Z. Effect of titanium content on dibenzothiophene HDS performance over Ni₂P/Ti-MCM-41 catalyst[J]. J Catal, 2014, 311:257-265. doi: 10.1016/j.jcat.2013.11.021
[11]	D'AQUINO A I, DANFORTH S J, CLINKINGBEARD T R, ILIC B, PULLAN L, REYNOLDS M A, MURRAY B D, BUSSELL M E. Highly-active nickel phosphide hydrotreating catalysts prepared in situ using nickel hypophosphite precursors[J]. J Catal, 2016, 335:204-214. doi: 10.1016/j.jcat.2015.12.006
[12]	宋华, 姜楠, 宋华林, 李锋, 代敏, 万霞, 徐晓伟.镍磷物质的量比对负载型Ni₂P/MCM-41催化剂结构及加氢脱硫性能的影响[J].燃料化学学报, 2015, 43(3):338-343. doi: 10.3969/j.issn.0253-2409.2015.03.012 SONG Hua, JIANG Nan, SONG Hua-lin, LI Feng, DAI Min, WAN Xia, XU Xiao-wei. Effect of Ni/P mol ratio on structure and performance of hydrodesulfurization of Ni₂P/MCM-41 catalyst[J].J Fuel Chem Technol, 2015, 43(3):338-343. doi: 10.3969/j.issn.0253-2409.2015.03.012
[13]	米星, 何广湘, 郭晓燕, 杨索和, 罗国华, 徐新, 靳海波. Ni/γ-Al₂O₃催化剂上萘加氢生成十氢萘的催化反应研究[J].燃料化学学报, 2018, 46(7):879-885. doi: 10.3969/j.issn.0253-2409.2018.07.015 MI Xing, HE Guang-xiang, GUO Xiao-yan, YANG Suo-he, LUO Guo-hua, XU Xin, JIN Hai-bo. Effect of reaction conditions on the hydrogenation of naphthalene to decalin over Ni/Al₂O₃ catalyst[J]. J Fuel Chem Technol, 2018, 46(7):879-885. doi: 10.3969/j.issn.0253-2409.2018.07.015
[14]	LI X, FENG J, GUO J, WANG A, PRINS R, DUAN X, CHEN Y. Preparation of Ni ₂P/Al₂O₃ by temperature-programmed reduction of a phosphate precursor with a low P/Ni ratio[J]. J Catal, 2016, 334:116-119. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=739a7343455ae38b51c8703efca97ae9
[15]	ZHANG X, ZHANG Q, ZHAO A, GUAN J, HE D, HU H, LIANG C. Naphthalene hydrogenation over silica supported nickel phosphide in the absence and presence of N-containing compounds[J]. Energy Fuels, 2010, 24(7):3796-3803. doi: 10.1021/ef100342z
[16]	OYAMA S T, GOTT T, ZHAO H, LEE Y K. Transition metal phosphide hydroprocessing catalysts:A review[J]. Catal Today, 2009, 143(1/2):94-107. http://d.old.wanfangdata.com.cn/NSTLQK/NSTL_QKJJ0226572816/
[17]	姚程程.负载量对Ni₂P/SiO₂催化剂结构及氯苯加氢脱氯性能的影响[D].天津: 天津大学, 2010. http://cdmd.cnki.com.cn/Article/CDMD-10056-1011262518.htm YAO Cheng-cheng. Effect of loading on Ni₂P/SiO₂ catalyst structure and hydrodechlorination performance of chlorobenzene[D]. Tianjin: Tianjin University, 2010. http://cdmd.cnki.com.cn/Article/CDMD-10056-1011262518.htm
[18]	SONG H, DAI M, SONG H, WAN X, XU X. A novel synthesis of Ni₂P/MCM-41 catalysts by reducing a precursor of ammonium hypophosphite and nickel chloride at low temperature[J]. Appl Catal A:Gen, 2013, 462:247-255. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=52ccf707bd8757a5597297c77cd9c953