Experimental study on bio-oil from catalytic pyrolysis on Fe modified HZSM-5

LI Di; LI Pan; WANG Xian-hua; SHAO Jing-ai; YANG Hai-ping; CHEN Han-ping

Volume 44 Issue 5

May 2016

Turn off MathJax

Article Contents

Article Navigation > Journal of Fuel Chemistry and Technology > 2016 > 44(5): 540-547

LI Di, LI Pan, WANG Xian-hua, SHAO Jing-ai, YANG Hai-ping, CHEN Han-ping. Experimental study on bio-oil from catalytic pyrolysis on Fe modified HZSM-5[J]. Journal of Fuel Chemistry and Technology, 2016, 44(5): 540-547.

Citation:

LI Di, LI Pan, WANG Xian-hua, SHAO Jing-ai, YANG Hai-ping, CHEN Han-ping. Experimental study on bio-oil from catalytic pyrolysis on Fe modified HZSM-5[J]. Journal of Fuel Chemistry and Technology, 2016, 44(5): 540-547.

Citation:

PDF( 833 KB)

Experimental study on bio-oil from catalytic pyrolysis on Fe modified HZSM-5

State Key Laboratory of Coal Combustion, China-EU Institute for Clean and Renewable Energy, Huazhong University of Science and Technology, Wuhan 430074, China

Funds:

the National Natural Science Foundation of China 51376075

the Major State Basic Research Development Program of China 973 program

the Major State Basic Research Development Program of China 973 program, 2013CB228102

Special Fund for Agro-Scientific Research in the Public Interest 201303095

Received Date: 2015-11-10
Rev Recd Date: 2016-01-29

Available Online: 2021-01-23

Publish Date: 2016-05-10

Abstract

Abstract

The 2% Fe modified HZSM-5 zeolite catalysts were prepared by ion-exchange and characterized by laser particle size analyzer, specific surface area and pore size analyzer, and X-ray diffraction (XRD) to investigate the pore and surface properties. The catalytic pyrolysis of wood was carried out at 550 ℃ to get the maximum oil yield. After pyrolysis, the bio-oil was separated to the lighter (upper layer) and heavier component (bottom layer). The results indicate that with Fe modified HZSM-5 catalysts, the bio-oil yield increases significantly (maximum 7%) the same as that of the lighter one, while the heavier one is nearly constant. Ketones and furans in the lighter oil decreases, while acids and phenols increase significantly; in the heavier oil, ketones and furans decreased dramatically, phenols and naphthalenes increase significantly. The Fe modified HZSM-5 catalysts play an important role in pyrolysis of wood dusts, and have a critical influence on oil yield because the modified catalysts promote the shape-selective modifying of the initial pyrolysis steam and inhibit the secondary coking reaction of steam. The product tends to much lighter bio-oil component and lower oxygen content.
- Fe modified,
- HZSM-5,
- catalytic pyrolysis,
- bio-oil

FullText(HTML)

References(21)

References

[1]	KLASS D L. Biomass for renewable energy, fuels and chemicals[J]. Bio Renew Energy Fuels Chem, 1998, 29(12): 1028-1037.
[2]	马广鹏, 张颖.中国生物质能源发展现状及问题探讨[J].农业科技管理, 2013, 32(1): 20-22. http://www.cnki.com.cn/Article/CJFDTOTAL-NKGL201301006.htm MA Guang-peng, ZHANG Ying. Discussions on current situation and problems of biomass energy development in China[J]. Manage Agri Sci Technol, 2013, 32(1): 20-2. http://www.cnki.com.cn/Article/CJFDTOTAL-NKGL201301006.htm
[3]	田原宇, 乔英云.基于生物固碳的低碳发展模式探讨[J].绿色科技, 2013, (7): 156-158. http://www.cnki.com.cn/Article/CJFDTOTAL-LVKJ201307077.htm TIAN Yuan-yu, QIAO Ying-yun. Discussion of low charbon development model based on biological sequestration[J]. J Green Sci Technol, 2013, (7): 156-158. http://www.cnki.com.cn/Article/CJFDTOTAL-LVKJ201307077.htm
[4]	LU Q, ZHANG Z B, ZHANG C J, SU S H, LI W Y, DONG C Q. Overview of chemical characterization of biomass fast pyrolysis oils[J]. Appl Mech Mater, 2012, 130-134: 422-425. https://www.researchgate.net/publication/253115353_Overview_of_Chemical_Characterization_of_Biomass_Fast_Pyrolysis_Oils
[5]	ZHANG M J, LI W Z, ZU S, HUO W, ZHU X F, WANG Z Y. Catalytic hydrogenation for bio-oil upgrading by a supported nimob amorphous alloy[J]. Chem Eng Technol, 2013, 36(36): 2108-2116. doi: 10.1002/ceat.201300142/full
[6]	ZHANG X L, YANG W H, DONG C Q. Comparison of non-catalytic and catalytic fast pyrolysis of corncob in a fluidized bed reactor[J]. Bioresour Technol, 2009, 100(3): 1428-1434. doi: 10.1016/j.biortech.2008.08.031
[7]	ILIOPOULOU E F, STEFANIDIS S D, KALOGIANNIS K G, DELIMITIS A, LAPPAS A A, TRIANTAFYLLIDIS K S. Catalytic upgrading of biomass pyrolysis vapors using transition metal-modified ZSM-5 zeolite[J]. Appl Catal B: Environ, 2012, 127(17): 281-290. http://www.sciencedirect.com/science/article/pii/S0926337312003888
[8]	FRENCH R, CZERNIK S. Catalytic pyrolysis of biomass for biofuels production[J]. Fuel Process Technol, 2010, 91(1): 25-32. doi: 10.1016/j.fuproc.2009.08.011
[9]	俞宁, 蔡忆昔, 李小华, 樊永胜, 尹云海, 张蓉仙. HZSM-5分子筛催化热裂解油菜秸秆制取精制生物油[J].农业工程学报, 2014, 30(15): 264-271. http://www.cnki.com.cn/Article/CJFDTOTAL-NYGU201415034.htm YU Ning, CAI Yi-xi, LI Xiao-hua, FAN Yong-sheng, YIN Yun-hai, ZHANG Rong-xian. Catalytic pyrolysis of rape straw for upgraded bio-oil production using HZSM-5 zeolite[J]. Trans CSAE, 2014, 30(15): 264-271. http://www.cnki.com.cn/Article/CJFDTOTAL-NYGU201415034.htm
[10]	辛星, 田文栋, 肖云汉.气氛对快速催化热解生物质的影响[J].环境工程, 2012, (S2): 473-476. http://www.cnki.com.cn/Article/CJFDTOTAL-HJGC2012S2131.htm XIN Xing, TIAN Wen-dong, XIAO Yun-han. Influence of different atmospheres on catalystical pyrolysis of biomass[J]. Environ Eng, 2012, (S2): 473-476. http://www.cnki.com.cn/Article/CJFDTOTAL-HJGC2012S2131.htm
[11]	TRANE R, DAHL S, SKJΦTH-RASMUSSEN M S, JENSEN A D. Catalytic steam reforming of bio-oil[J]. Int J Hydro Energy, 2012, 37(8): 6447-6472. doi: 10.1016/j.ijhydene.2012.01.023
[12]	MARTINEZ C, CORMA A. Inorganic molecular sieves: Preparation, modification and industrial application in catalytic processes[J]. Coordin Chem Rev, 2011, 255(13): 1558-1580. http://www.sciencedirect.com/science/article/pii/S0010854511001214
[13]	AL-SABAWI M, CHEN J, NG S. Fluid catalytic cracking of biomass-derived oils and their blends with petroleum feedstocks: A review[J]. Energy Fuels, 2012, 26(9): 5355-5372. doi: 10.1021/ef3006417
[14]	朱锡锋, 陆强, 郑冀鲁, 郭庆祥, 朱清时.生物质热解与生物油的特性研究[J].太阳能学报, 2007, 27(12): 1285-1289. http://www.cnki.com.cn/Article/CJFDTOTAL-TYLX200612017.htm ZHU Xi-Feng, LU Qiang, ZHENG Ji-lu, GUO Qing-xiang, ZHU Qing-shi. Research on biomass pyrolysis and bio-oil characteristics[J]. Acta Energ Sol Sin, 2007, 27(12): 1285-1289. http://www.cnki.com.cn/Article/CJFDTOTAL-TYLX200612017.htm
[15]	王丽红, 柏雪源, 易维明, 孔凡霞, 李永军, 何芳, 李志合.玉米秸秆热解生物油特性的研究[J].农业工程学报, 2006, 22(3): 108-111. http://www.cnki.com.cn/Article/CJFDTOTAL-NYGU200603023.htm WANG Li-hong, BAI Xue-yuan, YI Wei-ming, KONG Fan-xia, LI Yong-jun, HE Fang, LI Zhi-he. Characteristics of bio-oil from plasma heated fluidized bed pyrolysis of corn stalk[J]. Trans CSAE, 2006, 22(3): 108-111. http://www.cnki.com.cn/Article/CJFDTOTAL-NYGU200603023.htm
[16]	HOSOYA T, KAWAMOTO H, SAKA S. Role of methoxyl group in char formation from lignin-related compounds[J]. J Anal Appl Pyrolysis, 2009, 84(1): 79-83. doi: 10.1016/j.jaap.2008.10.024
[17]	ASMADI M, KAWAMOTO H, SAKA S. Pyrolysis and secondary reaction mechanisms of softwood and hardwood lignins at the molecular level[J]. Green Energy Technol, 2010, 66: 129-135. http://www.doc88.com/p-3387766235530.html
[18]	ZHANG H, RUI X, JIN B, SHEN D, RAN C, XIAO G. Catalytic fast pyrolysis of straw biomass in an internally interconnected fluidized bed to produce aromatics and olefins: Effect of different catalysts[J]. Bioresour Technol, 2013, 137(6): 82-87. https://www.researchgate.net/publication/236184448_Catalytic_fast_pyrolysis_of_straw_biomass_in_an_internally_interconnected_fluidized_bed_to_produce_aromatics_and_olefins_Effect_of_different_catalysts
[19]	GAYUBO A G, AGUAYO A T, ATUTXA A, AGUADO R, MARTIN O A, BILBAO J. Transformation of oxygenate components of biomass pyrolysis oil on a HZSM-5 zeolite.Ⅱ. Aldehydes, ketones, and acids[J]. Ind Eng Chem Res, 2004, 43(11): 2619-2626. doi: 10.1021/ie030792g
[20]	DICKERSON T, SORIA J. Catalytic fast pyrolysis: A review[J]. Energies, 2013, 6(1): 514-38. doi: 10.3390/en6010514
[21]	SAMOLADA M, PAPAFOTICA A, VASALOS I. Catalyst evaluation for catalytic biomass pyrolysis[J]. Energy Fuels, 2000, 14(6): 1161-1167. doi: 10.1021/ef000026b