Effect of calcination temperature on catalytic performance of Pt-FeOx/γ-Al2O3 catalysts for HCHO oxidation

CUI Wei-yi; WANG Xi-yue; TAN Nai-di

Volume 47 Issue 8

Aug. 2019

Turn off MathJax

Article Contents

Article Navigation > Journal of Fuel Chemistry and Technology > 2019 > 47(8): 964-972

CUI Wei-yi, WANG Xi-yue, TAN Nai-di. Effect of calcination temperature on catalytic performance of Pt-FeOx/γ-Al2O3 catalysts for HCHO oxidation[J]. Journal of Fuel Chemistry and Technology, 2019, 47(8): 964-972.

Citation:

CUI Wei-yi, WANG Xi-yue, TAN Nai-di. Effect of calcination temperature on catalytic performance of Pt-FeO_x/γ-Al₂O₃ catalysts for HCHO oxidation[J]. Journal of Fuel Chemistry and Technology, 2019, 47(8): 964-972.

Citation:

PDF( 7038 KB)

Effect of calcination temperature on catalytic performance of Pt-FeO_x/γ-Al₂O₃ catalysts for HCHO oxidation

CUI Wei-yi^{1, 2},
WANG Xi-yue²,
TAN Nai-di^{2
,
,}

1.
The Key Laboratory of Chemical Cleaner Production Technology of Jilin Province, Jilin Institute of Chemical Technology, Jilin 132022, China;
2.
College of Chemical and Pharmaceutical Engineering, Jilin Institute of Chemical Technology, Jilin 132022, China

Funds:

the National Science Foundation of China 51805207

13th Five-Year Science and Technology Research and Planning Project of Education Department of Jilin province JJKA20180559KJ

Science and Technology Innovation Development Plan Project of Jilin 201750211

More Information

Corresponding author: TAN Nai-di, E-mail: tannd0119@163.com
Received Date: 2019-03-28
Rev Recd Date: 2019-05-20

Available Online: 2021-01-23

Publish Date: 2019-08-10

Abstract

Abstract

A series of Pt-FeO_x/γ-Al₂O₃ catalysts were prepared by colloid-deposition method and characterized by XRD, TEM, BET, XPS, H₂-TPR and FT-IR to investigate the effects of calcination temperature on the surface structure of Pt-FeO_x/γ-Al₂O₃ catalyst and its catalytic performance in catalytic HCHO oxidation. The characterization results showed that the applied calcination temperature greatly influenced the redox properties and chemical states of the Pt species, as well as the amount of surface hydroxyl groups. All resultant Pt-FeO_x/γ-Al₂O₃ catalysts demonstrated activity in HCHO oxidation. The sample with calcination at 200 ℃ exhibited the best performance, which afforded 100% conversion of HCHO into CO₂ and H₂O at room temperature. The catalysts with lower calcination temperature should be beneficial to have a better valence distribution of Pt species and produce more accessible interface active sites like Pt-O-Fe species, thus endowing Pt-FeO_x/γ-Al₂O₃ catalyst with relatively high activity for the oxidation of formaldehyde under mild conditions.
- formaldehyde,
- catalytic oxidation,
- reactivity,
- calcination temperature,
- Pt nanoparticles

FullText(HTML)

References(30)

References

[1]	SALTHAMMER T, MENTESE S, MARUTZKY R. Formaldehyde in the indoor environment[J]. Chem Rev, 2010, 110(4):2536-2572. doi: 10.1021/cr800399g
[2]	CHI C C, CHEN W D, GUO M, WENG M L, YAN G, SHEN X Y. Law and features of TVOC and formaldehyde pollution in urban indoor air[J]. Atmos Environ, 2016, 132(5):85-90. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=1521901c1510a13ac0d0c9c6162c34fb
[3]	TANG X J, BAI Y, DUONG A, SMITH M T, LI L Y, ZHANG L P. Formaldehyde in China:Production, consumption, exposure levels, and health effects[J]. Environ Int, 2009, 35(8):1210-1224. doi: 10.1016/j.envint.2009.06.002
[4]	MARSH G M, YOUK A O. Reevaluation of mortality risks from nasopharyngeal cancer in the formaldehyde cohort study of the national cancer institute[J]. Regul Toxicol Pharmacol, 2004, 40(11):113-124. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=7a3fdf4cc193217c05653b2e7b70f81d
[5]	HUANG H B, XU Y, FENG Q Y, LEUNG D Y C. Low temperature catalytic oxidation of volatile organic compounds:A review[J]. Catal Sci Technol, 2015, 5(2):2649-2669. http://www.mendeley.com/research/low-temperature-catalytic-oxidation-volatile-organic-compounds-review/
[6]	NIE L H, YU J G, JARONIEC M, TAO F. Room-temperature catalytic oxidation of formaldehyde on catalysts[J]. Catal Sci Technol, 2016, 6(11):3649-3669. doi: 10.1039/C6CY00062B
[7]	拜冰阳, 乔琦, 李俊华, 郝吉明.甲醛催化氧化催化剂的研究进展[J].催化学报, 2016, 37(1):102-122. http://d.old.wanfangdata.com.cn/Periodical/cuihuaxb201601013 BAI Bing-yang, QIAO Qi, LI Jun-hua, HAO Ji-ming. Progress in research on catalysts for catalytic oxidation of formaldehyde[J]. Chin J Catal, 2016, 37(1):102-122. http://d.old.wanfangdata.com.cn/Periodical/cuihuaxb201601013
[8]	ZHANG C B, LIU F D, ZHAI Y P, ARIGA H, YI N, LIU Y C, ASAKURA K, FLYTZANI-STEPHANOPOULOS M, HE H. Alkali-metal-promoted Pt/TiO₂ opens a more efficient pathway to formaldehyde oxidation at ambient temperatures[J]. Angew Chem Int Ed, 2012, 51(38):9628-9632. doi: 10.1002/anie.v51.38
[9]	XU Q L, LEI W Y, LI X Y, QI X Y, YU J G, LIU G, WANG J L, ZHANG P Y. Efficient removal of formaldehyde by nanosized gold on well-defined CeO₂ nanorods at room temperature[J]. Environ Sci Technol, 2014, 48(16):9702-9708. doi: 10.1021/es5019477
[10]	LI Y B, ZHANG C B, HE H, ZHANG J H, CHEN M. Influence of alkali metals on Pd/TiO₂ catalysts for catalytic oxidation of formaldehyde at room temperature[J]. Catal Sci Technol, 2016, 6(7):2289-2295. doi: 10.1039/C5CY01521A
[11]	MA L, WANG D S, LI J H, BAI B Y, FU L X, LI Y D. Ag/CeO₂ nanospheres:Efficient catalysts for formaldehyde oxidation[J]. Appl Catal B:Environ, 2014, 148/149(7):36-43. http://www.sciencedirect.com/science/article/pii/S0926337313006644
[12]	WANG J L, LI J G, JIANG C J, ZHOU P, ZHANG P Y, YU J G. The effect of manganese vacancy in birnessite-type MnO₂ on room-temperature oxidation of formaldehyde in air[J]. Appl Catal B:Environ, 2017, 204(5):147-155. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=fb70db68f2265617d095cbbae17d7b14
[13]	XIA Y S, DAI H X, ZHANG L, DENG J G, HE H, AU C T. Ultrasound-assisted nanocasting fabrication and excellent catalytic performance of three-dimensionally ordered mesoporous chromia for the combustion of formaldehyde, acetone, and methanol[J]. Appl Catal B:Environ, 2010, 100(10):229-237. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=5314897f591d3c6b2316eedcef2668cf
[14]	WANG Z, WANG W Z, ZHANG L, JIANG D. Surface oxygen vacancies on Co₃O₄ mediated catalytic formaldehyde oxidation at room temperature[J]. Catal Sci Technol, 2016, 6:3845-3853. doi: 10.1039/C5CY01709B
[15]	HUANG Y C, FAN W J, LONG B, LI H B. Alkali-modified non-precious metal 3D-NiCo₂O₄ nanosheets for efficient formaldehyde oxidation at low temperature[J]. J Mater Chem A, 2016, 4(10):3648-3654. doi: 10.1039/C5TA09370H
[16]	崔维怡, 惠继星, 谭乃迪.负载型铂催化剂催化氧化甲醛的研究进展[J].化工进展, 2017, 36(10):3711-3719. http://d.old.wanfangdata.com.cn/Periodical/hgjz201710025 CUI Wei-yi, HUI Ji-xing, TAN Nai-di. Research progress on catalytic oxidation of formaldehyde over supported platinum catalysts[J]. Chem Ind Eng Prog, 2017, 36(10):3711-3719. http://d.old.wanfangdata.com.cn/Periodical/hgjz201710025
[17]	GUO J H, LIN C X, JIANG C J, ZHANG P Y. Review on noble metal-based catalysts for formaldehyde oxidation at room temperature[J].Appl Surf Sci, 2019, 475:237-255. doi: 10.1016/j.apsusc.2018.12.238
[18]	AN N H, YU Q S, LIU G, LI S Y, JIA M J, ZHANG W X. Complete oxidation of formaldehyde at ambient temperature over supported Pt/Fe₂O₃ catalysts prepared by colloid-deposition method[J]. J Hazard Mater, 2011, 186(10):1392-1397. http://www.sciencedirect.com/science/article/pii/S0304389410015980
[19]	XU Z H, YU J G, JARONIEC M. Efficient catalytic removal of formaldehyde at room temperature using AlOOH nanoflakes with deposited Pt[J]. Appl Catal B:Environ, 2015, 163(2):306-312. http://d.old.wanfangdata.com.cn/Conference/9171952
[20]	YAN Z X, XU Z H, YU J G, JARONIEC M. Highly active mesoporous ferrihydrite supported Pt catalyst for formaldehyde removal at room temperature[J]. Environ Sci Technol, 2015, 49(11):6637-6644. doi: 10.1021/acs.est.5b00532
[21]	CUI W Y, YUAN X L, WU P, ZHENG B, ZHANG W X, JIA M J. Catalytic properties of Al₂O₃ supported Pt-FeO_x catalysts for complete oxidation of formaldehyde at ambient temperature[J]. RSC Adv, 2015, 5(126):104330-104336. doi: 10.1039/C5RA19151C
[22]	郑彬, 甘涛, 吴淑杰, 刘钢, 张文祥等. Pt-FeO_x催化剂微结构对催化CO氧化性能的影响[J].无机化学学报, 2018, 34(6):1065-1070. http://d.old.wanfangdata.com.cn/Periodical/wjhxxb201806008 ZHENG Bin, GAN Tao, WU Shu-jie, LIU Gang, ZHANG Wen-xiang. Influence of microstructure of Pt-FeO_x catalyst on the catalytic CO oxidation[J]. Chin J Inorg Chem, 2018, 34(6):1065-1070. http://d.old.wanfangdata.com.cn/Periodical/wjhxxb201806008
[23]	QI L F, CHENG B, YU J G, HO W K. High-surface area mesoporous Pt/TiO₂ hollow chains for efficient formaldehyde decomposition at ambient temperature[J]. J Hazard Mater, 2016, 301:522-530. doi: 10.1016/j.jhazmat.2015.09.026
[24]	CHEN G X, ZHAO Y, FU G, DUCHESNE P N, GU L, ZHENG Y P, WENG X F, CHEN M S, ZHANG P, PAO C W, LEE J F, ZHENG N F. Interfacial effects in iron-nickel hydroxide-platinum nanoparticles enhance catalytic oxidation[J]. Science, 2014, 344:495-499. doi: 10.1126/science.1252553
[25]	XU L S, ZHANG W H, ZHANG Y L, WU Z F, CHEN B H, JIANG Z Q, MA Y S, YANG J L, HUANG W X. Oxygen vacancy-controlled reactivity of hydroxyls on an FeO(111) monolayer film[J]. J Phys Chem C, 2011, 115(14):6815-6824. doi: 10.1021/jp200423j
[26]	ZHENG B, LIU G, GENG L L, CUI J Y, WU S J, WU P, JIA M J, YAN W F, ZHANG W X. Role of the FeO_x support in constructing high-performance Pt/FeO_x catalysts for low-temperature CO oxidation[J]. Catal Sci Technol, 2016, 6(5):1546-1554. doi: 10.1039/C5CY00840A
[27]	CHEN B B, ZHU X B, CROCKER M, WANG Y, SHI C. FeO_x-supported gold catalysts for catalytic removal of formaldehyde at room temperature[J]. Appl Catal B:Environ, 2014, 154-155:73-81. doi: 10.1016/j.apcatb.2014.02.009
[28]	JIA J F, SHEN J Y, LIN L W, XU Z S, ZHANG T, LIANG D B. A study on reduction behaviors of the supported platinum-iron catalysts[J]. J Mol Catal A:Chem, 1999, 138:177-184. doi: 10.1016/S1381-1169(98)00147-2
[29]	AN N H, DUCHESNE P N, LI S Y, WU P, ZHANG W L, LEE J F, CHENG S, ZHANG P, JIA M J, ZHANG W X. Size effects of platinum colloid particles on the structure and CO oxidation properties of supported Pt/Fe₂O₃ catalysts[J]. J Phys Chem C, 2013, 117:21254-21262. doi: 10.1021/jp404266p
[30]	AN N H, YUAN X L, PAN B, LI Q L, LI S Y, ZHANG W X. Design of a highly active Pt/Al₂O₃ catalyst for low-temperature CO oxidation[J]. RSC Adv, 2014, 4(72):38250-38257. doi: 10.1039/C4RA05646A