Effect of calcination temperature on the catalytic performance of the hydrotalcite derived Ce/Cu/Zn-Al catalysts for hydrogen production via methanol steam reforming

YANG Shu-qian; LIU Yu-juan; LIU Jin-bo; FANG Ming-ming; XIAO Guo-peng; ZHANG Lei; CHEN Lin; YUAN Xing-zhou; ZHANG Jian

Volume 46 Issue 12

Dec. 2018

Turn off MathJax

Article Contents

Article Navigation > Journal of Fuel Chemistry and Technology > 2018 > 46(12): 1482-1490

YANG Shu-qian, LIU Yu-juan, LIU Jin-bo, FANG Ming-ming, XIAO Guo-peng, ZHANG Lei, CHEN Lin, YUAN Xing-zhou, ZHANG Jian. Effect of calcination temperature on the catalytic performance of the hydrotalcite derived Ce/Cu/Zn-Al catalysts for hydrogen production via methanol steam reforming[J]. Journal of Fuel Chemistry and Technology, 2018, 46(12): 1482-1490.

Citation:

YANG Shu-qian, LIU Yu-juan, LIU Jin-bo, FANG Ming-ming, XIAO Guo-peng, ZHANG Lei, CHEN Lin, YUAN Xing-zhou, ZHANG Jian. Effect of calcination temperature on the catalytic performance of the hydrotalcite derived Ce/Cu/Zn-Al catalysts for hydrogen production via methanol steam reforming[J]. Journal of Fuel Chemistry and Technology, 2018, 46(12): 1482-1490.

Citation:

YANG Shu-qian, LIU Yu-juan, LIU Jin-bo, FANG Ming-ming, XIAO Guo-peng, ZHANG Lei, CHEN Lin, YUAN Xing-zhou, ZHANG Jian. Effect of calcination temperature on the catalytic performance of the hydrotalcite derived Ce/Cu/Zn-Al catalysts for hydrogen production via methanol steam reforming[J]. Journal of Fuel Chemistry and Technology, 2018, 46(12): 1482-1490.

PDF( 1167 KB)

Effect of calcination temperature on the catalytic performance of the hydrotalcite derived Ce/Cu/Zn-Al catalysts for hydrogen production via methanol steam reforming

1.
College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China
2.
Department of Chemistry and Materials Engineering, Yingkou Institute of Technology, Yingkou 115014, China

Funds:

the National Natural Science Foundation of China 21376237

the Doctoral Scientific Research Foundation of Liaoning Province 201601322

the Science Research General Foundation of Liaoning Education Department L2015296

More Information

Corresponding author: ZHANG Lei, E-mail: lnpuzhanglei@163.com; ZHANG Jian, E-mail: zhangjian_lnpu@163.com
Received Date: 2018-08-20
Rev Recd Date: 2018-11-04

Available Online: 2021-01-23

Publish Date: 2018-12-10

Abstract

Abstract

ZnAl-LDHs was prepared by in-situ synthesis method on the surface of γ-Al₂O₃, and then a series Ce/Cu/Zn-Al catalysts were prepared by ordinal wet impregnation method. All the catalysts were characterized by XRD, BET, H₂-TPR and XPS to investigate the effects of calcination temperature on the surface structure of Ce/Cu/Zn-Al catalyst and its catalytic performance in methanol steam reforming. The results showed that calcination temperature mainly influenced the specific surface area of copper, surface oxygen vacancy content and the interaction between Cu and Ce. When the calcination temperature is 500℃, the specific surface area of Cu is larger, the content of oxygen vacancy is higher and the interaction between Cu and Ce is stronger. Therefore, the catalytic activity of the catalysts for methanol steam reforming is the best. When the calcination temperature rises to 700℃, the Cu species mainly exist in the form of stable CuAl₂O₄ spinel, which is not conducive to the reaction of methanol steam reforming, resulting in lower catalytic activity.
- calcination temperature,
- hydrotalcite,
- Cu-Al spinel,
- methanol steam reforming,
- hydrogen

FullText(HTML)

References(37)

References

[1]	RYAN J G, KHALID A A, WILLIAM H G. Thermochemical production of hydrogen from hydrogen sulfide with iodine thermochemical cycles[J]. Int J Hydrogen Energy, 2018, 43(29):12939-12947. doi: 10.1016/j.ijhydene.2018.04.217
[2]	CLAUDE L. From hydrogen production by water electrolysis to its utilization in a PEM fuel cell or in a SO fuel cell:Some considerations on the energy efficiencies[J]. Int J Hydrogen Energy, 2016, 41(34):15415-15425. doi: 10.1016/j.ijhydene.2016.04.173
[3]	HOSSAIN M A, JEWARATNAM J, GANESAN P. Prospect of hydrogen production from oil palm biomass by thermochemical processe-A review[J]. Int J Hydrogen Energy, 2016, 41(38):16637-16655. doi: 10.1016/j.ijhydene.2016.07.104
[4]	SANDRA S, HUGO S, LUCIA B, SOUSA J M, MENDES A. Catalysts for methanol steam reforming-A review[J]. Appl Catal B:Environ, 2010, 99(1/2):43-57. http://www.sciencedirect.com/science/article/pii/S0926337310002584
[5]	苏石龙, 张磊, 张艳, 雷俊腾, 桂建州, 刘丹, 刘道胜, 潘立卫.千瓦级PEMFC甲醇水蒸气重整制氢过程热力学模拟[J].石油化工高等学校学报, 2015, 28(2):19-25. doi: 10.3969/j.issn.1006-396X.2015.02.004 SU Shi-long, ZHANG Lei, ZHANG Yan, LEI Jun-teng, GUI Jian-zhou, LIU Dan, LIU Dao-sheng, PAN Li-wei. Thermodynamic Simulation for Hydrogen Production in the Methanol Steam Reforming System of Kilowatt PEMFC[J]. J Petrochem Univ, 2015, 28(2):19-25. doi: 10.3969/j.issn.1006-396X.2015.02.004
[6]	SANCHES S G, FLORES J H, PAIS DA SILVA M I. Cu/ZnO and Cu/ZnO/ZrO₂ catalysts used for methanol steam reforming[J]. Mol Catal, 2018, 454:55-62. doi: 10.1016/j.mcat.2018.05.012
[7]	XU T K, ZOU J, TAO W T, ZHANG S Y, CUI L, ZENG F L, WANG D Z, CAI W J. Co-nanocasting synthesis of Cu based composite oxide and itspromoted catalytic activity for methanol steam reforming[J]. Fuel, 2018, 183:238-244. http://www.sciencedirect.com/science/article/pii/S0016236116305403
[8]	LI J, ZHANG Q J, LONG X, QI P, LIU Z T, LIU Z W. Hydrogen production for fuel cells via steam reforming of dimethyl ether over commercial Cu/ZnO/Al₂O₃ and zeolite[J]. Chem Eng J, 2012, 187:299-305. doi: 10.1016/j.cej.2012.01.126
[9]	CHOI Y, FUTAGAMI K, FUTAGAMI K, FUJITANI T, NAKAMURA J. The role of ZnO in Cu/ZnO methanol synthesis catalysts-morphology effect or active site model[J]. Appl Catal A:Gen, 2001, 208(1/2):163-167. http://www.sciencedirect.com/science/article/pii/S0926860X00007122
[10]	XIAO S, ZHANG Y F, GAO P, ZHONG L S, LI X P, ZHANG Z Z, WANG H, WEI W, SUN Y H. Highly efficient Cu-based catalysts via hydrotalcite-like precursors for CO₂ hydrogenation to methanol[J]. Catal Today, 2017, 281:327-336. doi: 10.1016/j.cattod.2016.02.004
[11]	HAMMOUD D, GENNEQUIN C, ABOUKAIS A, AAD E A. Steam reforming of methanol over x% Cu/Zn-Al 400500 based catalysts for production of hydrogen:Preparation by adopting memory effect of hydrotalcite and behavior evaluation[J]. Int J Hydrogen Energy, 2015, 40(2):1283-1297. doi: 10.1016/j.ijhydene.2014.09.080
[12]	HE J P, YANG Z X, ZHANG L, LI Y, PAN L W. Cu supported on ZnAl-LDHs precursor prepared by in-situ synthesis method on γ-Al₂O₃ as catalytic material with high catalytic activity for methanol steam reforming[J]. Int J Hydrogen Energy, 2017, 42(15):9930-9937. doi: 10.1016/j.ijhydene.2017.01.229
[13]	贺建平, 张磊, 陈琳, 杨占旭, 佟宇飞. CeO₂改性Cu/Zn-Al水滑石衍生催化剂对甲醇水蒸气重整制氢性能的影响[J].高等学校化学学报, 2017, 38:1822-1828. doi: 10.7503/cjcu20170158 HE Jian-ping, ZHANG Lei, CHEN Lin, YANG Zhan-xu, TONG Yu-fei. Effect of CeO₂ on Cu/Zn-Al catalysts derived from hydrotalcite precursor for methanol steam reforming[J]. Chem J Chin Univ, 2017, 38:1822-1828. doi: 10.7503/cjcu20170158
[14]	杨淑倩, 贺建平, 张娜, 隋晓伟, 张磊, 杨占旭.稀土掺杂改性对Cu/ZnAl水滑石衍生催化剂甲醇水蒸气重整制氢性能的影响[J].燃料化学学报, 2018, 46(2):179-188. doi: 10.3969/j.issn.0253-2409.2018.02.007 YANG Shu-qian, HE Jian-ping, ZHANG Na, SUI Xiao-wei, ZHANG Lei, YANG Zhan-xu. Effect of rare-earth element modification on the performance of Cu/ZnAl catalysts derived from hydrotalcite precursor in methanol steam reforming[J]. J Fuel Chem Technol, 2018, 46(2):179-188. doi: 10.3969/j.issn.0253-2409.2018.02.007
[15]	杨淑倩, 张娜, 贺建平, 张磊, 王宏浩, 白金, 张健, 刘道胜, 杨占旭. Ce的浸渍顺序对Cu/Zn-Al水滑石衍生催化剂用于甲醇水蒸气重整制氢性能的影响[J].燃料化学学报, 2018, 46(4):479-488. doi: 10.3969/j.issn.0253-2409.2018.04.014 YANG Shu-qian, ZHANG Na, HE Jian-ping, ZHANG Lei, WANG Hong-hao, BAI Jin, ZHANG Jian, LIU Dao-sheng, YANG Zhan-xu. Effect of impregnation sequence of Ce on the performance of Cu/Zn-Al catalysts derived from hydrotalcite precursor in methanol steam reforming[J]. J Fuel Chem Technol, 2018, 46(4):479-488. doi: 10.3969/j.issn.0253-2409.2018.04.014
[16]	刘玉娟, 许骥, 佟宇飞, 张娜, 张磊, 刘道胜, 韩蛟, 张财顺.氧化铈纳米材料合成方法的研究进展[J].辽宁石油化工大学学报, 2017, 37(5):8-12. doi: 10.3969/j.issn.1672-6952.2017.05.002 LIU Yu-Juan, XU Ji, TONG Yu-fei, ZHANG Na, ZHANG Lei, LIU Dao-sheng, HAN Jiao, ZHANG Cai-shun. Progress in research of the synthesis methods of nanometer ceria[J]. J Liaoning Univ Pet Chem Technol, 2017, 37(5):8-12. doi: 10.3969/j.issn.1672-6952.2017.05.002
[17]	张秋林, 徐海迪, 李伟, 林涛, 龚茂初, 陈耀强.焙烧温度对MnO₂-CeO₂/Zr_0.25Ti_0.25Al_0.5O_1.75整体式催化剂NH₃低温选择性催化还原NO性能的影响[J].催化学报, 2010, 31(2):229-235. http://d.wanfangdata.com.cn/Periodical/cuihuaxb201002017 ZHANG Qiu-lin, XU Hai-di, LI Wei, LIN Tao, GONG Mao-chun, CHEN Yao-qiang. Influence of calcination temperature on performance of monolith catalyst MnO₂-CeO₂/Zr_0.25Ti_0.25Al_0.5O_1.75 for selective catalytic reduction of NO by NH₃ at low temperature[J]. Chin J Catal, 2010, 31(2):229-235. http://d.wanfangdata.com.cn/Periodical/cuihuaxb201002017
[18]	BIALAS A, KUSTROWSKI P, DUDEK B, PIWOWARSKA Z, WACH A, MICHALIK M, KOZAK M. Copper-aluminum oxide catalysts for total oxidation of toluene synthesized by thermal decomposition of co-precipitated precursors[J]. Thermochim Acta, 2014, 590:191-197. doi: 10.1016/j.tca.2014.06.027
[19]	方书农, 姜明, 伏义路, 林培琰, 乔山, 谢亚宁.不同焙烧温度对Cu/γ-Al₂O₃催化剂铜物种结构的影响[J].物理化学学报, 1994, 10(7):623-627. doi: 10.3866/PKU.WHXB19940709 FANG Shu-nong, JIANG Ming, FU Yi-lu, LIN Pei-yan, QIAO Shan, XIE Ya-ning. The effect of different calcination temperature on the structure of Cu/γ-Al₂O₃ catalysts[J]. Acta Phys Chim Sin, 1994, 10(7):623-627. doi: 10.3866/PKU.WHXB19940709
[20]	孙蛟, 任国卿, 黄玉辉, 陈晓蓉, 梅华.焙烧温度对CuMgAl催化剂催化糠醛气相加氢制糠醇性能的影响[J].燃料化学学报, 2017, 45(1):43-47. doi: 10.3969/j.issn.0253-2409.2017.01.007 SUN Jiao, REN Guo-qing, HUANG Yu-hui, CHEN Xiao-rong, MEI Hua. Effect of calcination temperature on the catalytic performance of CuMgAl catalysts for furfural gas phase selective hydrogenation to furfuryl alcohol[J]. J Fuel Chem Technol, 2017, 45(1):43-47. doi: 10.3969/j.issn.0253-2409.2017.01.007
[21]	BASAG S, PIWOWARSKA Z, KOWALCZYK A, WEGRZYN A, BARAN R, GIL B, MICHALIK M, CHMIELARZ L. Cu-Mg-Al hydrotalcite-like materials as precursors of effective catalysts for selective oxidation of ammonia to dinitrogen-The influence of Mg/Al ratio and calcination temperature[J]. Appl Clay Sci, 2016, 129:122-130. doi: 10.1016/j.clay.2016.05.019
[22]	ZHANG L, PAN L W, NI C J, SUN T J, ZHAO S S, WANG S D, WANG A J, HU Y K. CeO₂-ZrO₂-promoted CuO/ZnO catalyst for methanol steam reforming[J]. Int J Hydrogen Energy, 2013, 38(11):4397-4406. doi: 10.1016/j.ijhydene.2013.01.053
[23]	GUO X M, MAO D S, LU G Z, WANG S, WU G S. CO₂ hydrogenation to methanol over Cu/ZnO/ZrO₂ catalysts prepared via a route of solid-state reaction[J].Catal Commun, 2011, 12(12):1095-1098. doi: 10.1016/j.catcom.2011.03.033
[24]	SHIM J O, NA H S, JHA A, JANG W J, JEONG D W, NAH I W, JEON B H, ROH H S. Effect of preparation method on the oxygen vacancy concentration of CeO₂-promoted Cu/γ-Al₂O₃ catalysts for HTS reactions[J]. Chem Eng J, 2016, 306:908-915. doi: 10.1016/j.cej.2016.08.030
[25]	BYOUNG K K, DAE S P, YANG S Y, JONGHEOP Y. Preparation and characterization of nanocrystalline CuAl₂O₄ spinel catalysts by sol-gel method for the hydrogenolysis of glycerol[J]. Catal Commun, 2012, 24:90-95. doi: 10.1016/j.catcom.2012.03.029
[26]	覃发玠, 刘雅杰, 庆绍军, 侯晓宁, 高志贤.甲醇制氢铜铝尖晶石缓释催化剂的研究-不同铜源合成的影响[J].燃料化学学报, 2017, 45(12):1481-1488. doi: 10.3969/j.issn.0253-2409.2017.12.010 QIN Fa-jie, LIU Ya-jie, QING Shao-jun, HOU Xiao-ning, GAO Zhi-xian. Cu-Al spinel as a sustained release catalyst for H₂ production from methanol steam reforming:Effects of different copper sources[J]. J Fuel Chem Technol, 2017, 45(12):1481-1488. doi: 10.3969/j.issn.0253-2409.2017.12.010
[27]	WANG J, ZHONG L P, LU J C, CHEN R, LEI Y Q, CHEN K Z, HAN C H, HE S F, WAN G P, LUO Y M. A solvent-free method to rapidly synthesize CuO-CeO₂ catalysts to enhance their CO preferential oxidation:Effects of Cu loading and calcination temperature[J]. Mol Catal, 2017, 443:241-252. doi: 10.1016/j.mcat.2017.10.012
[28]	LUO M F, FANG P, HE M, XIE Y L. In situ XRD, Raman, and TPR studies of CuO/Al₂O₃ catalysts for CO oxidation[J]. J Mol Catal A:Chem, 2005, 239(1/2):243-248. http://www.sciencedirect.com/science/article/pii/S1381116905004164
[29]	张磊, 雷俊腾, 田园, 胡鑫, 白金, 刘丹, 杨义, 潘立卫.前驱体和沉淀剂浓度对CuO/ZnO/CeO₂-ZrO₂甲醇水蒸气重整制氢催化剂性能的影响[J].燃料化学学报, 2015, 43(11):1366-1374. doi: 10.3969/j.issn.0253-2409.2015.11.012 ZHANG Lei, LEI Jun-teng, TIAN Yuan, HU Xin, BAI Jin, LIU Dan, YANG Yi, PAN Li-wei. Effect of precursor and precipitant concentration on the performance of CuO/ZnO/CeO₂-ZrO₂ catalyst for methanol steam reforming[J]. J Fuel Chem Technol, 2015, 43(11):1366-1374. doi: 10.3969/j.issn.0253-2409.2015.11.012
[30]	TANG D M, LIU G, LI F, TAN J, LIU C, LU G Q, CHENG H M. Synthesis and photoelectrochemical property of Urchin-like Zn/ZnO core-shell structures[J]. J Phys Chem C, 2009, 113(25):11035-11040. doi: 10.1021/jp8107254
[31]	SEO Y S, CHOI T Y, HA J, JEONG D Y, LEE S Y, KIM D. Enhancement of stability of aqueous suspension of alumina nanoparticles by femtosecond laser irradiation[J]. J Appl Phys, 2015, 118:114906. doi: 10.1063/1.4931373
[32]	WANG C, CHENG Q P, WANG X L, MA K, BAI X Q, TAN S R, TIAN Y, TONG D, ZHENG L R, ZHANG J, LI X G. Enhanced catalytic performance for CO preferential oxidation over CuO catalysts supported on highly defective CeO₂ nanocrystals[J]. Appl Surf Sci, 2017, 422:932-943. doi: 10.1016/j.apsusc.2017.06.017
[33]	张国强, 郭天玉, 郑华艳, 李忠.焙烧温度对CuCe/Ac催化剂甲醇氧化羰基化性能的影响[J].燃料化学学报, 2016, 44(6):674-679. http://manu60.magtech.com.cn/rlhxxb/CN/abstract/abstract18844.shtml ZHANG Guo-qiang, GUO Tian-yu, LI Zhong. Effect of calcination temperature on catalytic performance of CuCe/Ac catalysts for oxidative carbonylation of methanol[J]. J Fuel Chem Technol, 2016, 44(6):674-679. http://manu60.magtech.com.cn/rlhxxb/CN/abstract/abstract18844.shtml
[34]	FAN J, WU X D, WU X D, LIANG Q, RAN R, WENG D. Thermal ageing of Pt on low-surface-area CeO₂-ZrO₂-La₂O₃ mixed oxides:Effect on the OSC performance[J]. Appl Catal B:Environ, 2008, 81(1/2):38-48. http://www.sciencedirect.com/science/article/pii/S0926337307004183
[35]	LIOTTA L F, CARLO G D, PANTALEO G, VENEZIA A M, DEGANELLO G. Co₃O₄/CeO₂ composite oxides for methane emissions abatement:Relationship between Co₃O₄-CeO₂ interaction and catalytic activity[J]. Appl Catal B:Environ, 2006, 66(3/4):217-227.
[36]	LIANG F L, YU Y, ZHOU W, XU X Y, ZHU Z H. Highly defective CeO₂ as a promoter for efficient and stable water oxidation[J]. J Mater Chem A, 2015, 3(2):634-640. doi: 10.1039/C4TA05770H
[37]	LIN S S, CHEN C L, CHANG D J, CHEN C C. Catalytic wet air oxidation of phenol by various CeO₂ catalysts[J]. Water Res, 2002, 36(12):3009-3014. doi: 10.1016/S0043-1354(01)00539-5