Preparation of highly dispersed silicon spheres supported cobalt-based catalysts and their catalytic performance for Fischer-Tropsch synthesis

ZHANG Meng; LIU Jia; ZHANG Yu-hua; WANG Li; LI Jin-lin; HONG Jing-ping

doi:10.1016/S1872-5813(22)60078-1

Volume 51 Issue 5

May 2023

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Article Navigation > Journal of Fuel Chemistry and Technology > 2023 > 51(5): 608-615

ZHANG Meng, LIU Jia, ZHANG Yu-hua, WANG Li, LI Jin-lin, HONG Jing-ping. Preparation of highly dispersed silicon spheres supported cobalt-based catalysts and their catalytic performance for Fischer-Tropsch synthesis[J]. Journal of Fuel Chemistry and Technology, 2023, 51(5): 608-615. doi: 10.1016/S1872-5813(22)60078-1

Citation:

ZHANG Meng, LIU Jia, ZHANG Yu-hua, WANG Li, LI Jin-lin, HONG Jing-ping. Preparation of highly dispersed silicon spheres supported cobalt-based catalysts and their catalytic performance for Fischer-Tropsch synthesis[J]. Journal of Fuel Chemistry and Technology, 2023, 51(5): 608-615. doi: 10.1016/S1872-5813(22)60078-1

Citation:

ZHANG Meng, LIU Jia, ZHANG Yu-hua, WANG Li, LI Jin-lin, HONG Jing-ping. Preparation of highly dispersed silicon spheres supported cobalt-based catalysts and their catalytic performance for Fischer-Tropsch synthesis[J]. Journal of Fuel Chemistry and Technology, 2023, 51(5): 608-615. doi: 10.1016/S1872-5813(22)60078-1

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Preparation of highly dispersed silicon spheres supported cobalt-based catalysts and their catalytic performance for Fischer-Tropsch synthesis

doi: 10.1016/S1872-5813(22)60078-1

Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education & Hubei Key Laboratory of Catalysis and Materials Science, South-Central Minzu University, Wuhan 430074, China

Received Date: 2022-09-30
Accepted Date: 2022-11-18
Rev Recd Date: 2022-11-15

Available Online: 2022-12-26

Publish Date: 2023-05-15

Abstract

Abstract

A series of silicon spheres supported cobalt catalysts were prepared by incipient wetness impregnation followed by decomposition under treatment of glow discharge plasma with different intensities. The catalysts were characterized by X-ray powder diffraction, N₂physical adsorption-desorption, H₂ temperature-programmed reduction, transmission electron microscope and Fourier-Transform Infrared spectroscopy. The Fischer-Tropsch synthesis performance were tested on a fixed bed reactor. The influence of plasma treatment on cobalt dispersion, reducibility and cobalt-support interaction were analyzed and discussed. The results showed that the plasma-treated catalysts had better catalytic performance than the calcined sample. The Co/SP-P650W catalyst showed the highest reaction activity due to the proper cobalt dispersion and higher cobalt reducibility.
- Fischer-Tropsch synthesis,
- cobalt-based catalyst,
- glow discharge plasma,
- structure-activity relationship

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References(25)

References

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