Preparation of Co<sub>0.5</sub>Cu<sub>0.5</sub>/CNR catalyst and its performance in hydrogen production by hydrolysis of ammonia borane

ZUO Youhua; LI Rong; HUA Junfeng; HAO Siyu; XIE Jing; XU Lixin; YE Mingfu; WAN Chao

doi:10.1016/S1872-5813(24)60442-1

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ZUO Youhua, LI Rong, HUA Junfeng, HAO Siyu, XIE Jing, XU Lixin, YE Mingfu, WAN Chao. Preparation of Co0.5Cu0.5/CNR catalyst and its performance in hydrogen production by hydrolysis of ammonia borane[J]. Journal of Fuel Chemistry and Technology. doi: 10.1016/S1872-5813(24)60442-1

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ZUO Youhua, LI Rong, HUA Junfeng, HAO Siyu, XIE Jing, XU Lixin, YE Mingfu, WAN Chao. Preparation of Co_0.5Cu_0.5/CNR catalyst and its performance in hydrogen production by hydrolysis of ammonia borane[J]. Journal of Fuel Chemistry and Technology. doi: 10.1016/S1872-5813(24)60442-1

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Preparation of Co_0.5Cu_0.5/CNR catalyst and its performance in hydrogen production by hydrolysis of ammonia borane

doi: 10.1016/S1872-5813(24)60442-1

ZUO Youhua^1
,,
LI Rong^1
,,
HUA Junfeng^2
,,
HAO Siyu^1
,,
XIE Jing^1
,,
XU Lixin^{1
,
,},
YE Mingfu^{1, 3, 4, 5
,},
WAN Chao^{1, 4, 6, 7
,
,}

1.
School of Chemistry and Chemical Engineering, Anhui University of Technology, Ma’anshan 243032, China
2.
Zhejiang Environment Technology Co., Ltd, Hangzhou 310027, China
3.
Engineering Research Center of Biofilm Water Purification and Utilization Technology, Ministry of Education, Anhui University of Technology, Ma’anshan 243032, China
4.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China
5.
Key Laboratory of Green Energy and Environment Catalysis, Ningde Normal University, Ningde, 352100, China
6.
Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Changzhou University, Changzhou 213164, China
7.
College of Chemical Engineering and Biological Engineering, Zhejiang University, Hangzhou 310058, China

Funds: The project was supported by the National Natural Science Foundation of China (22108238, U22A20408), Anhui Provincial Natural Science Foundation (1908085QB68), China Postdoctoral Science Foundation (2019M662060, PC2022046, 2020T130580), Open Research Funds of Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology(BM2012110), Open Research Funds of Key Laboratory of Green En-ergy and Environment Catalysis(FJ-GEEC202204)and 2022, 2023 National Undergraduate Innovation and entrepreneurship training program (202210360037, S202310260212), Supported by the Open Project of Engineering Research Center of Biofilm Water Purification and Utiliza-tion Technology of Ministry of Education (BWPU2023KF06).

Received Date: 2024-01-04
Accepted Date: 2024-02-26
Rev Recd Date: 2024-02-07

Available Online: 2024-04-23

Abstract

Abstract

Solution A was prepared with cobalt nitrate and copper nitrate, and solution B was prepared with phenyldicarboxylic acid(PTA) and N,N-dimethylformamide(DMF), and the two solutions were used to prepare Co/Cu Lavashield skeleton series materials(Co/Cu-MIL precursors) by solvothermal method, and the further direct carbonization of the precursor system prepared the MOFs derivatives, i.e., bimetallic carbon nanorods(Co_xCu_1−x/CNR) catalyst. The morphology and composition were explored by SEM, TEM, XRD, XPS and other characterization means. The results showed that Co_xCu_1−x/CNR was successfully obtained after Co/Cu-MIL was roasted at high temperature, and the catalytic activity of the catalyst obtained was optimal when x=0.5, the solvent heat temperature was 120°C, and the roasting temperature was 650 ℃. The TOF value of the Co_0.5Cu_0.5/CNR catalyst catalyzed the hydrolysis of ammonia borane (AB) for the production of hydrogen was 2718.21 h⁻¹, and the reaction The activation energy was 51.64 kJ/mol, and the catalyst had good cycling stability, and the catalytic activity decreased after 10 cycles, but still maintained 100% conversion of AB.
- lavashield skeleton series materials,
- MOFs derivatives,
- bimetallic carbon nanorod catalysts,
- ammonia borane,
- hydrogen hydrolysis

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References(46)

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