CO<sub>2</sub> hydrogenation to C<sub>5+</sub> isoalkanes on ZnZr/HZSM-5 composite catalyst

MA Xiao-ling; WANG Xiao-xing; SONG Fa-en; MA Zi-xuan; TAN Yi-sheng

doi:10.19906/j.cnki.JFCT.2022085

Volume 51 Issue 6

Jun. 2023

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Article Navigation > Journal of Fuel Chemistry and Technology > 2023 > 51(6): 757-767

MA Xiao-ling, WANG Xiao-xing, SONG Fa-en, MA Zi-xuan, TAN Yi-sheng. CO2 hydrogenation to C5+ isoalkanes on ZnZr/HZSM-5 composite catalyst[J]. Journal of Fuel Chemistry and Technology, 2023, 51(6): 757-767. doi: 10.19906/j.cnki.JFCT.2022085

Citation:

MA Xiao-ling, WANG Xiao-xing, SONG Fa-en, MA Zi-xuan, TAN Yi-sheng. CO₂ hydrogenation to C₅₊ isoalkanes on ZnZr/HZSM-5 composite catalyst[J]. Journal of Fuel Chemistry and Technology, 2023, 51(6): 757-767. doi: 10.19906/j.cnki.JFCT.2022085

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CO₂ hydrogenation to C₅₊ isoalkanes on ZnZr/HZSM-5 composite catalyst

doi: 10.19906/j.cnki.JFCT.2022085

MA Xiao-ling^{1, 2
,},
WANG Xiao-xing^{1
,
,},
SONG Fa-en^1
,,
MA Zi-xuan^{1, 2
,},
TAN Yi-sheng^{1
,
,}

1.
State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China
2.
University of Chinese Academy of Sciences, Beijing 100049, China

Funds: The project was supported by the National Natural Science Foundation of China (22172182) and the Natural Science Foundation of Shanxi Province (202103021224441)

Received Date: 2022-10-12
Accepted Date: 2022-11-09
Rev Recd Date: 2022-11-09

Available Online: 2022-11-16

Publish Date: 2023-06-15

Abstract

Abstract

Zinc-zirconium oxide (ZnZr) was effectively coupled with HZSM-5 zeolite in this report. The effects of SiO₂/Al₂O₃ ratio of HZSM-5 zeolite and Zn/Zr ratio on the performance of CO₂ hydrogenation to C₅₊ isoalkanes over the composite catalyst were investigated, respectively. The results show that ZnZr-4/HZSM-5 prepared by SiO₂/Al₂O₃ = 130 and Zn/Zr = 1∶5 manifests the optimal performance of CO₂ hydrogenation to C₅₊ isoalkanes, with CO₂ conversion of 17% and CO selectivity of 25%, as well as the selectivity of C₅₊ hydrocarbons and isoalkanes in C₅₊ hydrocarbons up to 60% and 89%. Moreover, ZnZr/HZSM-5 composite catalyst shows excellent stability with time on stream for 120 h without losing activity. A suitable coupling between ZnZr and HZSM-5 zeolite is critical for highly selective synthesis of C₅₊ isoalkanes by CO₂ hydrogenation.
- CO₂ hydrogenation,
- C₅₊ isoalkanes,
- ZnZr oxides,
- HZSM-5 zeolite,
- Zn/Zr ratio

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References(54)

References

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